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Azobenzene photoswitches in bulk materials
Physical Review E, 2008A nonadiabatic two-scale quantum-classical dynamics method is developed to allow for dynamical simulation of photoinduced processes and reactions in chemically complex condensed-matter systems such as photosensitive liquid crystals. A first application to photoswitching of azobenzene in the bulk reveals not only valuable insights into the excited-state
Boeckmann, Marcus +2 more
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Rotational Barriers in Azobenzene and Azonaphthalene
The Journal of Physical Chemistry A, 2010Theoretical predictions of rotational barriers for pi-conjugated substituents of aromatic rings sometimes significantly overestimate the corresponding experimental values. In this work, the rotational barriers in benzaldehyde, azobenzene, and azonaphthalene are studied by DFT calculations employing a variety of exchange-correlation functionals and ...
Rebecca L, Klug, Rudolf, Burcl
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Direct ortho-mercuration reactions of azobenzene and ortho-substituted azobenzenes
Journal of Organometallic Chemistry, 1976Abstract The mercuration of azobenzene occurred exclusively in the ortho -position to yield 2-chloromercuriazobenzene and a mixture which on iodination gave 2,2'and 2,6-diiodoazobenzene. Ten other ortho -substituted azobenzenes were mercurated and mercuration was found to occur predominately in an ortho -position.
Paul V. Roling +4 more
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Photoisomerization in different classes of azobenzene
Chem. Soc. Rev., 2012Azobenzene undergoes trans→cis isomerization when irradiated with light tuned to an appropriate wavelength. The reverse cis→trans isomerization can be driven by light or occurs thermally in the dark. Azobenzene's photochromatic properties make it an ideal component of numerous molecular devices and functional materials.
H M Dhammika, Bandara, Shawn C, Burdette
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Synthesis and isomerization of azobenzene dendrimers
Photochemical & Photobiological Sciences, 20033,3',5,5'-Tetramethoxyazobenzene and related meta-substituted azobenzene dendrimers show the first evidence of the dendritic effect on trans-to-cis photoisomerization; the thermodynamic parameters for cis-to-trans isomerization have been determined.
Mayuko, Uda +2 more
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Photoresponsive Dendritic Azobenzene Peptides
ChemBioChem, 2001Two dendritic peptides containing a branched lysine core and up to eight azobenzene moieties in the periphery were synthesized on solid support employing the omega-amino acid 4-(aminomethyl)phenylazobenzoic acid. With an additional peptidic tail consisting of an oligolysine portion, water solubility was achieved for the dendrimers, which allowed for ...
A, Cattani-Scholz +3 more
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Photoisomerization of Azobenzenes
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
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Laterally Mounted Azobenzenes on Platforms
The Journal of Organic Chemistry, 2015Triazatriangulenium ions have previously been used as platforms to prepare self-assembled monolayers of functional molecules such as azobenzenes with vertical orientation and that are free-standing on gold surfaces. We have now prepared azobenzenes that are spanned between two posts which are attached on two platforms.
Melanie, Hammerich, Rainer, Herges
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Comparative Studies of thetrans−cisPhotoisomerizations of Azobenzene and a Bridged Azobenzene
The Journal of Physical Chemistry A, 2010Using density-functional-based molecular dynamics simulations, we have performed comparative studies of the trans-cis isomerizations of azobenzene and bridged azobenzene (B-Ab) 5,6-dihydrodibenzo[c,g][1,2]diazocine induced by nπ* electronic excitation.
Chen-Wei, Jiang +3 more
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Perchlorates of Conjugate Acids of Azobenzene and Substituted Azobenzenes
The Journal of Organic Chemistry, 1959Si-Jung Yeh, H Jaffe
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