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Metal-free syntheses of new azocines via addition reactions of enaminones with acenaphthoquinone followed by oxidative cleavages of the corresponding vicinal diols. [PDF]

open access: yesRSC Adv, 2020
A one-pot, clean and green procedure is described for the syntheses of new azocine derivatives via addition reactions of enaminones with acenaphthoquinone followed by periodic acid-mediated oxidative cleavages of the corresponding vicinal diols.
Mousavi SH   +5 more
europepmc   +2 more sources

Helically Chiral π-Expanded Azocines Through Regioselective Beckmann Rearrangement and Their Charged States.

open access: yesAngewandte Chemie, Volume 136, Issue 29, July 15, 2024.
We report a synthetic approach to p-expanded [6]helicenes incorporating tropone and azocine units in combination with a 5-membered ring, which exhibit intriguing structural, electronic, and chiroptical properties.
Jan Borstelmann   +4 more
semanticscholar   +3 more sources

Synthesis of 1-(para-methoxyphenyl)tetrazolyl-Substituted 1,2,3,4-Tetrahydroisoquinolines and Their Transformations Involving Activated Alkynes [PDF]

open access: yesMolecules, 2018
1-(p-Methoxyphenyl)tetrazolyl-substituted 6,7-dimethoxy(6,7-methylenedioxy)-1,2,3,4-tetrahydroisoquinolines formed tetrazolyl-substituted azocines in high yields by using activated alkynes.
Alexander A. Titov   +9 more
doaj   +2 more sources

Friedel-Crafts chemistry. Part 40. An expedient novel synthesis of some dibenz-azepines, -azocines, 11H-benzo[f]pyrido[2,3-b]azepines and 6H-benzo[g]pyrido[2,3-c]azocines

open access: yesARKIVOC, 2013
A new synthetic approach for the synthesis of novel 5 H-dibenz( b,f )azepine, 5 H-dibenz( b,f )- azocine, 11 H-benzo( f)pyrido(2,3-b)azepine and 6 H-benzo( g)pyrido(2,3-c)azocine derivatives is reported.
Hassan A. K. Abd El-Aal, Ali A. Khalaf
doaj   +2 more sources

Synthesis of benz[d]azocines (microreview)

open access: yesChemistry of Heterocyclic Compounds, 2016
[Figure not available: see fulltext.][Figure not available: see fulltext.] This review is concerned with two types of efficient methods for the synthesis of benz[d]-azocines: the ring expansion reactions and intramolecular cyclizations.[Figure not available: see fulltext.] © 2016 Springer Science+Business Media New ...
Nevskaya A.A., Voskressensky L.G.
openaire   +4 more sources

Recent Advances in the Synthesis of Hydrogenated Azocine-Containing­ Molecules [PDF]

open access: yesSynthesis (Stuttg), 2017
This review covers recent advances in synthesis of azocine-containing systems. The most approaches towards azocines are discussed.1 Introduction2 Ring-Expansion Reaction2.1 Ring-Expansion Reaction of Cyclopentane Containing the 1,4-Diketone Moiety with Primary Amines (from 5 to 8)2.2 Ring-Expansion Reaction of Annulated Tetrahydropyridines under ...
Listratova A, Voskressensky L.
europepmc   +5 more sources

Two highly efficient syntheses of scalemic azocines

open access: yesTetrahedron Letters, 1996
Abstract Two approaches to the synthesis of disubstituted azocines in scalemic form, via intramolecular alkylation and olefin metathesis, respectively, are described.
Jeffrey D. Winkler   +2 more
openaire   +2 more sources

The first example of tetrahydrothieno[3,2-d]azocines synthesis

open access: yesTetrahedron, 2008
A novel and efficient one-pot synthesis of thieno[3,2-d]azocines based on tamden transformation of tetrahydropyridine ring was elaborated. © 2008 Elsevier Ltd. All rights reserved.
Voskressensky L.G.   +5 more
openaire   +4 more sources

Correction: Diastereoselective synthesis of tetrahydrobenzo[b]azocines by Lu(OTf)3-catalyzed [4+4] cycloaddition of donor-acceptor cyclobutanes with anthranils.

open access: yesChemical Communications, 2022
Correction for 'Diastereoselective synthesis of tetrahydrobenzo[b]azocines by Lu(OTf)3-catalyzed [4+4] cycloaddition of donor-acceptor cyclobutanes with anthranils' by Meifeng Hou et al., Chem.
Meifeng Hou   +4 more
semanticscholar   +1 more source

An access to some functionalized azocine derivatives [PDF]

open access: yesTetrahedron Letters, 2000
The syntheses, from readily accessible 3-alkyl-4-methoxy-1,3,4,5-tetrahydropyridine 1, of functionalized 1,6,7,8-tetrahydroazocine 7 and 1,2,7,8-tetrahydroazocine 9 are reported.
Laurent Gil   +3 more
openaire   +1 more source

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