Results 21 to 30 of about 861 (190)

REACTIONS OF 5-ARYLOXAZOLIDINES AND THEIR DERIVATIVES WITH NUCLEOPHILES [PDF]

open access: yes, 2022
Compounds 5‒7 were obtained with financial support from the Russian Science Foundation (grant no. 22-73-10008)
Buev, E. M.   +3 more
core  

Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

open access: yesAngewandte Chemie, Volume 136, Issue 42, October 14, 2024.
Progress in the development of non‐alternant nanographenes containing N‐doped non‐hexagonal pairs, including N‐doped pentagon‐heptagon (5–7) pairs, N‐doped pentagon‐octagon (5–8) pairs and N‐doped heptagon‐heptagon (7–7) pairs, is comprehensively covered in this review.
Huan Luo, Junzhi Liu
wiley   +2 more sources

Tert-Amino effect: The Meth-Cohn and Reinhoudt reactions (Review) [PDF]

open access: yes, 2013
The data published over the last 15-20 years on reactions taking place by the tert-amino effect mechanism have been reviewed.
Glukhareva, T. V.   +3 more
core   +2 more sources

When indoles meet allene and its derivatives [PDF]

open access: yes, 2020
The allene functional group and the indole ring have emerged as recurring building blocks in organic chemistry due to their diverse reactivity and straightforward preparation. In addition, the biological properties and natural occurrence of indole give a
Alonso Gomez, José M.   +1 more
core   +1 more source

Synthesis of Benzo[b]azocin‐2‐ones by Aryl Amination and Ring‐Expansion of α‐(Iodophenyl)‐β‐oxoesters

open access: yesChemistry – A European Journal, Volume 25, Issue 65, Page 14912-14920, November 22, 2019., 2019
Expanding rings: A sequence of aryl amination of α‐(iodophenyl)‐β‐oxoesters followed by ring transformation is the key to accessing hexahydrobenzo[b]azocin‐2‐on‐6‐carboxylic esters. Abstract Transformation of β‐oxoesters with PhI(OCOCF3)2 leads to α‐(ortho‐iodophenyl)‐β‐oxoesters.
Anna Dierks   +3 more
wiley   +1 more source

Design of new anti-Alzheimer drugs: ring-expansion synthesis and synchrotron X-ray diffraction study of dimethyl 4-ethyl-11-fluoro-1,4,5,6,7,8-hexahydroazonino[5,6-b]indole-2,3-dicarboxylate [PDF]

open access: yes, 2018
The title compound, C20H23FN2O4, is the product of a ring-expansion reaction from a seven-membered fluorinated hexahydroazepine to a nine-membered azonine. The nine-membered azonine ring of the molecule adopts achair–boatconformation.
Alexey N. Bilyachenko   +6 more
core   +2 more sources

18F‐Labeling Using Click Cycloadditions

open access: yesBioMed Research International, Volume 2014, Issue 1, 2014., 2014
Due to expanding applications of positron emission tomography (PET) there is a demand for developing new techniques to introduce fluorine‐18 (t1/2 = 109.8 min). Considering that most novel PET tracers are sensitive biomolecules and that direct introduction of fluorine‐18 often needs harsh conditions, the insertion of 18F in those molecules poses an ...
Kathrin Kettenbach   +3 more
wiley   +1 more source

Four-membered ring systems [PDF]

open access: yes, 2010
Capítulo 4, pp 85-107The search in the field of four-membered heterocycles, where a non-carbon atom is part of the ring, has been actively pursued in 2009 within Organic Chemistry, Inorganic Chemistry, Medicinal Chemistry, and Material Science.
Alcaide, Benito, Almendros, Pedro
core   +1 more source

Modifications of Prenyl Side Chains in Natural Product Biosynthesis

open access: yesAngewandte Chemie International Edition, Volume 63, Issue 52, December 20, 2024.
This review summarizes the unique modifications of prenyl side chains involved in natural product biosynthesis, including epoxidation, dehydrogenation, oxidation of methyl groups to carboxyl groups, C−C bond cleavage and oxidative cyclization. Abstract In recent years, there has been a growing interest in understanding the enzymatic machinery ...
Huibin Wang, Yi Yang, Ikuro Abe
wiley   +1 more source

A terc-amino effektus vizsgálata és kiterjesztése: új típusú, biológiailag aktív policiklusos vegyületek előállítása = The study and the extension of the tert-amino effect: Synthesis of new types of polycyclic compounds with biological activities [PDF]

open access: yes, 2013
1. Vizsgáltuk a terc-amino effektus 2. típusának kiterjesztését a reakcióban résztvevő vinil és terc-amino csoportot két külön gyűrűn tartalmazó (kondenzált) bi- és triaril - bifenil/fenilpiridazin, trifenil/difenilpiridazin, naftalin illetve ...
Balogh, Balázs   +8 more
core  

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