[3 + 2] Cycloaddition with photogenerated azomethine ylides in β-cyclodextrin [PDF]
Stability constants for the inclusion complexes of cyclohexylphthalimide 2 and adamantylphthalimide 3 with β-cyclodextrin (β-CD) were determined by 1H NMR titration, K = 190 ± 50 M−1, and K = 2600 ± 600 M−1, respectively.
Margareta Sohora +2 more
doaj +2 more sources
Synthesis of Stable Betaines Based on 1H-Pyrrole-2,3-diones and Pyridinium Ylides and Their Thermal Conversion to Cyclopropane-Fused Pyrroles [PDF]
Pyridinium ylides, along with related azaheterocyclic ylides, are widely used in synthetic organic chemistry. However, reactions that yield stable zwitterionic adducts from these ylides remain underexplored. In this work, we demonstrate that the reaction
Maria M. Muranova +4 more
doaj +2 more sources
A Novel One-Pot Green Synthesis of Dispirooxindolo-pyrrolidines via 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides [PDF]
A facile synthesis of dispirooxindolopyrrolidines has been accomplished via a one-pot three component 1,3-dipolar cycloaddition reaction. The reaction of azomethine ylides generated in situ from L-phenylalanine and substituted isatins with a series of ...
Abdulrahman I. Almansour +5 more
doaj +2 more sources
Additive-assisted regioselective 1,3-dipolar cycloaddition of azomethine ylides with benzylideneacetone [PDF]
1,3-Dipolar cycloadditions of isatins, benzylamine and benzylideneacetones were studied to prepare a series of novel spiropyrrolidine-oxindoles – 4′-acetyl-3′,5′-diarylspiro[indoline-3,2′-pyrrolidin]-2-ones and 3′-acetyl-4′,5′-diarylspiro[indoline-3,2 ...
Chuqin Peng +5 more
doaj +2 more sources
Recent Developments in Azomethine Ylide-Initiated Double Cycloadditions [PDF]
Azomethine ylides (AMYs) have a nitrogen–carbon double bond and an electron lone pair on the nitrogen atom. They are essential 1,3-dipoles for [3+2] cycloadditions in the synthesis of pyrrolidine-containing heterocycles.
Tieli Zhou +4 more
doaj +2 more sources
The Chemistry of Azomethine Ylides Developed in the Institute
The research on azomethine ylide 1,3-dipoles, developed in the last five years in the Institute of Advanced Material Study, Kyushu University, is briefly reviewed. New generation methods of unprecedented azomethine ylides, reactivities in their cycloadditions with olefinic dipolarophiles, and stereochemical as well as regiochemical selectivities in the
カネマサ, シュウジ +2 more
openaire +1 more source
Asymmetric metal-catalyzed [3+2] cycloadditions of azomethine ylides [PDF]
Cycloadditions of azomethine ylides with olefins provide a short, attractive route to pyrrolidine units with the potential to control the relative and absolute configuration by means of a chiral catalyst.
Stohler, Remo
core +1 more source
Substituted proline derivatives as organocatalysts in Michael reaction [PDF]
Chiral, polysubstituted proline esters, obtained via cycloaddition reactions of azomethine ylides, have been studied as organocatalysts in Michael reaction of aldehydes/ketones and vinylsulphones. Under optimised reaction conditions employing 10
Jovanović Predrag +5 more
doaj +1 more source
Intramolecular Cycloaddition of Imines of Cysteine Derivatives
Azomethine ylides were generated from Schiffs bases of S-allylcysteine methyl ester and their intramolecular 1,3-dipolar cycloadditions were studied. These reactions led to the synthesis of thieno[3,4-b]pyrrole derivatives in good yield.
Teresa M. V. D. Pinho e Melo +2 more
doaj +1 more source
An Azomethine Ylide Approach to Complex Alkaloid-like Heterocycles [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
William V, Murray +3 more
openaire +2 more sources

