Results 11 to 20 of about 2,363 (206)

[3 + 2] Cycloaddition with photogenerated azomethine ylides in β-cyclodextrin [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2020
Stability constants for the inclusion complexes of cyclohexylphthalimide 2 and adamantylphthalimide 3 with β-cyclodextrin (β-CD) were determined by 1H NMR titration, K = 190 ± 50 M−1, and K = 2600 ± 600 M−1, respectively.
Margareta Sohora   +2 more
doaj   +2 more sources

Synthesis of Stable Betaines Based on 1H-Pyrrole-2,3-diones and Pyridinium Ylides and Their Thermal Conversion to Cyclopropane-Fused Pyrroles [PDF]

open access: yesMolecules
Pyridinium ylides, along with related azaheterocyclic ylides, are widely used in synthetic organic chemistry. However, reactions that yield stable zwitterionic adducts from these ylides remain underexplored. In this work, we demonstrate that the reaction
Maria M. Muranova   +4 more
doaj   +2 more sources

A Novel One-Pot Green Synthesis of Dispirooxindolo-pyrrolidines via 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides [PDF]

open access: yesMolecules, 2015
A facile synthesis of dispirooxindolopyrrolidines has been accomplished via a one-pot three component 1,3-dipolar cycloaddition reaction. The reaction of azomethine ylides generated in situ from L-phenylalanine and substituted isatins with a series of ...
Abdulrahman I. Almansour   +5 more
doaj   +2 more sources

Additive-assisted regioselective 1,3-dipolar cycloaddition of azomethine ylides with benzylideneacetone [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2014
1,3-Dipolar cycloadditions of isatins, benzylamine and benzylideneacetones were studied to prepare a series of novel spiropyrrolidine-oxindoles – 4′-acetyl-3′,5′-diarylspiro[indoline-3,2′-pyrrolidin]-2-ones and 3′-acetyl-4′,5′-diarylspiro[indoline-3,2 ...
Chuqin Peng   +5 more
doaj   +2 more sources

Recent Developments in Azomethine Ylide-Initiated Double Cycloadditions [PDF]

open access: yesMolecules
Azomethine ylides (AMYs) have a nitrogen–carbon double bond and an electron lone pair on the nitrogen atom. They are essential 1,3-dipoles for [3+2] cycloadditions in the synthesis of pyrrolidine-containing heterocycles.
Tieli Zhou   +4 more
doaj   +2 more sources

The Chemistry of Azomethine Ylides Developed in the Institute

open access: yesThe Chemistry of Azomethine Ylides Developed in the Institute
The research on azomethine ylide 1,3-dipoles, developed in the last five years in the Institute of Advanced Material Study, Kyushu University, is briefly reviewed. New generation methods of unprecedented azomethine ylides, reactivities in their cycloadditions with olefinic dipolarophiles, and stereochemical as well as regiochemical selectivities in the
カネマサ, シュウジ   +2 more
openaire   +1 more source

Asymmetric metal-catalyzed [3+2] cycloadditions of azomethine ylides [PDF]

open access: yes, 2006
Cycloadditions of azomethine ylides with olefins provide a short, attractive route to pyrrolidine units with the potential to control the relative and absolute configuration by means of a chiral catalyst.
Stohler, Remo
core   +1 more source

Substituted proline derivatives as organocatalysts in Michael reaction [PDF]

open access: yesJournal of the Serbian Chemical Society, 2014
Chiral, polysubstituted proline esters, obtained via cycloaddition reactions of azomethine ylides, have been studied as organocatalysts in Michael reaction of aldehydes/ketones and vinylsulphones. Under optimised reaction conditions employing 10
Jovanović Predrag   +5 more
doaj   +1 more source

Intramolecular Cycloaddition of Imines of Cysteine Derivatives

open access: yesMolecules, 1998
Azomethine ylides were generated from Schiffs bases of S-allylcysteine methyl ester and their intramolecular 1,3-dipolar cycloadditions were studied. These reactions led to the synthesis of thieno[3,4-b]pyrrole derivatives in good yield.
Teresa M. V. D. Pinho e Melo   +2 more
doaj   +1 more source

An Azomethine Ylide Approach to Complex Alkaloid-like Heterocycles [PDF]

open access: yesThe Journal of Organic Chemistry, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
William V, Murray   +3 more
openaire   +2 more sources

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