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Direct Decarboxylation of Trifluoroacetates Enabled by Iron Photocatalysis. [PDF]
Angewandte Chemie, 2023 Trifluoroacetates are the most abundant and accessible sources of trifluoromethyl groups, which are key components in pharmaceuticals and agrochemicals.
S. Fernández-García +2 more
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Decarboxylation in Natural Products Biosynthesis
Jacs AuDecarboxylation reactions are frequently found in the biosynthesis of primary and secondary metabolites. Decarboxylase enzymes responsible for these transformations operate via diverse mechanisms and act on a large variety of substrates, making them ...
John McIntosh +2 more
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Light‐Driven Enzymatic Decarboxylation of Fatty Acids
Angewandte Chemie - International Edition, 2018 The photoenzymatic decarboxylation of fatty acids to alkanes is proposed as an alternative approach for the synthesis of biodiesel. By using a recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) we demonstrate the irreversible ...
Wuyuan Zhang +2 more
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Acidic Cannabinoid Decarboxylation
Cannabis & Cannabinoid Research, 2022 Introduction: Cannabis is a valuable plant, cultivated by humans for millennia. However, it has only been in the past several decades that biologists have begun to clarify the interesting Cannabis biosynthesis details ...
C. N. Filer
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Cannabis and Cannabinoid Research, 2016 Introduction: Decarboxylation is an important step for efficient production of the major active components in cannabis, for example, Δ9-tetrahydrocannabinol (Δ9-THC), cannabidiol (CBD), and cannabigerol (CBG).
Ikhlas Khan +2 more
exaly +2 more sources
bioRxiv, 2023 Coenzyme Q (CoQ) is a redox lipid that fulfills critical functions in cellular bioenergetics and homeostasis. CoQ is synthesized by a multi-step pathway that involves several COQ proteins.
L. Pelosi +23 more
semanticscholar +1 more source
Carboxylations and decarboxylations [PDF]
Journal of Cellular and Comparative Physiology, 1959 A brief survey of decarboxylation reactions and carboxylation reactions that are known or presumed in biological systems will be presented. While a considerable number of amino acid decarboxylations are known, their mechanisms will not be included in the present discussion but will be reserved for a later paper in the symposium.
Calvin, Melvin, Pon, Ning G
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Decarboxylation‐Initiated Intermolecular Carbon‐Heteroatom Bond Formation
Advanced Synthesis and Catalysis, 2021 Carboxylic acids are among the most used feedstock chemicals due to their great structural diversity and easy handling. The use of carboxylic acids and their derivatives in decarboxylative couplings has proven to be a valuable tool for the construction ...
Zhong-Yi Zeng +3 more
semanticscholar +1 more source
Membranes, 2023 The 6FDA-based network PI has attracted significant attention for gas separation. A facile strategy to tailor the micropore structure within the network PI membrane prepared by the in situ crosslinking method is extremely significant for achieving an ...
Yuxuan Zhao +5 more
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Decarboxylative alkenylation [PDF]
Nature, 2017 Olefin chemistry, through pericyclic reactions, polymerizations, oxidations, or reductions, has an essential role in the manipulation of organic matter. Despite its importance, olefin synthesis still relies largely on chemistry introduced more than three decades ago, with metathesis being the most recent addition.
Edwards, Jacob T. +12 more
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