Results 11 to 20 of about 81,314 (317)

Catalytic Plasticity of the Aspartate/Glutamate Racemase Superfamily [PDF]

open access: yes, 2009
The bacterial and archaeal Asp/Glu racemase enzyme superfamily contains a variety of catalytic functions that have great potential for use in industrial biocatalysis.
Fisch, Florian A
core   +7 more sources

Continuous Flow Synthesis of Propofol

open access: yesMolecules, 2021
Herein, we report a continuous flow process for the synthesis of 2,6-diisopropylphenol—also known as Propofol—a short-acting intravenous anesthesia, widely used in intensive care medicine to provide sedation and hypnosis.
Romain Mougeot   +3 more
doaj   +1 more source

New Insights on Hemp Oil Enriched in Cannabidiol: Decarboxylation, Antioxidant Properties and In Vitro Anticancer Effect

open access: yesAntioxidants, 2021
This study aimed to obtain and characterize extracted hemp oil enriched in cannabidiol (CBD) by decarboxylation of cannabidiolic acid (CBDA) and to give new insights into its antioxidant and anticancer effects.
A. Petrovici   +5 more
semanticscholar   +1 more source

Trichloroacetic acid fueled practical amine purifications

open access: yesBeilstein Journal of Organic Chemistry, 2022
Amine purification have for long been dominated by tedious stepwise processes involving the generation of large amounts of undesired waste. Inspired by recent work on out of equilibrium molecular machinery, using trichloroacetic acid (TCA), we disclose a
Aleena Thomas   +3 more
doaj   +1 more source

Decarboxylative borylation [PDF]

open access: yesScience, 2017
Swapping boron acids for carbon acids Carbon-bound boronic acids and their esters are widely used as coupling partners to make carbon-carbon bonds. More recently, these chemicals have garnered pharmaceutical interest in their own right. Li et al.
Chao Li   +11 more
openaire   +2 more sources

The Decarboxylation and Protonation Enigma in the H85Q Mutant of Cytochrome P450OleT [PDF]

open access: yes, 2023
Cytochrome P450OleT (CYP450OleT), a member of CYP450 Peroxygenases, catalyzes unusual decarboxylation activity. Unlike other members of the peroxygenases family, CYP450OleT possesses a Histidine at the 85th position, which was supposed to be the root ...
Kshatresh, Dubey   +2 more
core   +2 more sources

Decarboxylative Alkynylation [PDF]

open access: yesAngewandte Chemie International Edition, 2017
AbstractThe development of a new decarboxylative cross‐coupling method that affords terminal and substituted alkynes from various carboxylic acids is described using both nickel‐ and iron‐based catalysts. The use of N‐hydroxytetrachlorophthalimide (TCNHPI) esters is crucial to the success of the transformation, and the reaction is amenable to in situ ...
Joel M. Smith   +10 more
openaire   +2 more sources

Light‐Driven Enzymatic Decarboxylation of Dicarboxylic Acids

open access: yesChemistryOpen, 2021
Photodecarboxylase from Chlorella variabillis (CvFAP) is one of the three known light‐activated enzymes that catalyzes the decarboxylation of fatty acids into the corresponding C1‐shortened alkanes.
Yong‐Yi Zeng   +3 more
doaj   +1 more source

Energy Conservation in Fermentations of Anaerobic Bacteria

open access: yesFrontiers in Microbiology, 2021
Anaerobic bacteria ferment carbohydrates and amino acids to obtain energy for growth. Due to the absence of oxygen and other inorganic electron acceptors, the substrate of a fermentation has to serve as electron donor as well as acceptor, which results ...
Wolfgang Buckel
doaj   +1 more source

Metabolism of Tryptophan in the Liver: Interference with Decarboxylation of Other Aromatic Amino Acids

open access: yesActa Medica, 2000
Decarboxylation of aromatic amino acid in mammalian tissues is catalyzed by aromatic amino acid decarboxylase (EC. 4.1.1.28, AAD). The enzyme differs in its affinity to individual aromatic amino acids, the best substrates being 3,4-dihydroxyphenylalanine
Jaroslav Dršata, Eliška Marklová
doaj   +1 more source

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