Results 121 to 130 of about 79,213 (337)

Novel oxidation of aromatic aldehydes catalyzed by Preyssler's anion, [NaP5W30O110]14-

open access: yesJournal of the Brazilian Chemical Society, 2006
Preyssler's anion, with formula [NaP5W30O110]14-, catalyzes the oxidation of aromatic aldehydes to related carboxylic acids by hydrogen peroxide as oxidizing agent, under microwave irradiation, or at 70 ºC.
Bamoharram F. F.   +4 more
doaj  

Crystal structure of 4-(4-methoxyphenoxy)benzaldehyde

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C14H12O3, was synthesized via the nucleophilic addition of 4-methoxyphenol to 4-fluorobenzaldehyde. The dihedral angle between the least-squares planes of the benzene rings is 71.52 (3)° and the C—O—C angle at the central O atom is ...
Andreas Schäfer   +5 more
doaj   +1 more source

An investigation of the roles furan versus thiophene π-bridges play in donor–π-acceptor porphyrin based DSSCs [PDF]

open access: yes, 2018
Dye-sensitized solar cells (DSSCs) continue to attract interest due to their lower cost production compared to silicon based solar cells and their improving power conversion efficiencies. Porphyrin-based sensitizers have become an important sub-class due
Abdalhadi, Saifaldeen M.   +7 more
core   +1 more source

C(sp3)─S Bond Formation via the Synergy of Oxidative With Reductive Photocatalysts Through Photoredox and Dual Hydrogen Atom Transfer Processes

open access: yesAdvanced Science, EarlyView.
The research reveals that polysulfide anions (K2Sx), which serve as reducing catalysts, can also effectively act as sulfur reagents, providing the formation of C(sp3)─S bonds through photoredox catalysis with an oxidative photocatalyst tetrabutylammonium decatungstate (TBADT) and dual hydrogen atom transfer (DHAT) process.
Chao Zhou   +8 more
wiley   +1 more source

Catalytic 1,2‐Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes

open access: yesAngewandte Chemie, EarlyView.
We report a multicomponent reaction involving an aryl halide, an aldehyde, and a silane derivative, facilitated by low‐valent bismuth redox catalysis under mild conditions. The protocol represents an unprecedented example of four elementary organometallic steps at a Bi center within the catalytic cycle.
Xiangrong Liu   +4 more
wiley   +2 more sources

Sustainable Electrochemical Strategy for Selective Double Bond Oxidation in the Presence of Aldehyde Groups with Mo─N─O Catalysts

open access: yesAdvanced Science, EarlyView.
In this work, an electrochemical strategy employing hydroperoxyl radicals and a molybdenum‐based catalyst (Mo─N─O) enables selective double‐bond oxidation in cinnamaldehyde, preserving aldehyde integrity. Under mild, energy‐efficient conditions (−200 mA), this approach converts cinnamaldehyde to benzaldehyde with complete conversion (100%) and >99 ...
Zhirong Li   +12 more
wiley   +1 more source

Oxidation of benzaldehyde in some single phase betaine-benzaldehyde-water systems

open access: yesJournal of Pharmacy and Pharmacology, 1964
AbstractThe oxidation rates of increasing concentrations of benzaldehyde in ternary systems of the L1 type have been measured in aqueous solutions of four betaine homologues. On applying corrections for extra-micellar material, the rate becomes independent of the betaine concentration and is related to the micellar ratio of benzaldehyde to betaine when
J, SWARBRICK, J E, CARLESS
openaire   +2 more sources

High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator. [PDF]

open access: yes, 2017
Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated ...
Berben, Louise A   +3 more
core   +1 more source

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