Results 191 to 200 of about 43,948 (300)
An enantioselective rhodium‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of axially chiral diaryl ethers. Carbonyl coordination ensures high reactivity and regioselectivity, affording products bearing up to four stereogenic axes with good enantio‐ and diastereoselectivity.
Yu Sato +3 more
wiley +2 more sources
Efficient aerobic oxidation of benzyl alcohols using a magnetically recoverable Ni/nitrogen-containing carbon nanocomposite. [PDF]
Arumugam DB, Santhakumar K.
europepmc +1 more source
A straightforward one‐step protocol enables the synthesis of bio‐based and biologically active isochromans through the Oxa‐Pictet cyclization involving diverse aldehydes, including vanillin in combination with lignin‐derivable homovanillyl alcohol, a prominent aromatic platform chemical obtainable via diol‐assisted fractionation of lignocellulose ...
Anjali Kottayi +6 more
wiley +1 more source
Machine learning-based QSAR modeling assay for the nitrification inhibition of 2,4,5-trichloroaniline-derived eco-friendly Schiff bases. [PDF]
Mondal T +11 more
europepmc +1 more source
Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel +5 more
wiley +1 more source
Room temperature synthesis of α,β-unsaturated nitriles by manganese-catalysed base-free coupling of α-saturated nitriles with aldehydes. [PDF]
Thiyagarajan S +5 more
europepmc +1 more source
Flipping the Card With Enantiodivergent Organocatalysis
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre +3 more
wiley +1 more source
Decoding and reconstructing yeast protein flavor based on an integrated sensory-omics approach. [PDF]
Chen J +7 more
europepmc +1 more source
Rhodium‐Catalyzed Carbene Transfer to Isocyanides Using Zinc Carbenoids
A diazo‐free rhodium‐catalyzed carbene transfer to isocyanides using zinc carbenoids generated from α‐acyloxy halides is reported. This mild protocol furnishes ketenimines that can either be hydrolyzed to amides or intercepted with trimethylsilyl azide or carboxylic acids to give tetrazoles and imides, respectively.
Thomas R. Roose +5 more
wiley +1 more source

