1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Automated Nanocrystalline Sponge Workflow Enabled by 3D Electron Diffraction. [PDF]
Butonova S +5 more
europepmc +1 more source
Synergistic Cu-OH and zeolite confinement in Cu/MCM-22 for benzaldehyde-mediated Mukaiyama epoxidation of long-chain α-olefins. [PDF]
Chang H +12 more
europepmc +1 more source
Coordination Polymers Assembled from Flexible Tricarboxylate Linkers: Hydrothermal Synthesis, Structural Diversity, and Catalytic Features. [PDF]
Dou W +5 more
europepmc +1 more source
This review analyzes deep eutectic solvents (DESs) as efficient media for both organic and inorganic electrosynthesis. The improvements in terms of synthetic opportunities and sustainability are discussed, by exploring the multiple roles of DESs as solvents, electrolytes, and promoters, enabling effective and selective electrosynthesis under mild and ...
Cristiana Margarita +6 more
wiley +1 more source
Bio-inspired asymmetric Zn-N<sub>2</sub>O<sub>2</sub> single-atom catalysts via natural skeleton for efficient N-alkylation of nitroarenes with alcohols. [PDF]
Huang Y +9 more
europepmc +1 more source
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
<i>Caenorhabditis inopinata</i> shows reduced attraction and increased head-swinging compared with <i>C. elegans</i> in plate chemotaxis. [PDF]
Sukmawinata E +4 more
europepmc +1 more source
The selective oxidation of primary amines to generate nitriles provides a cost‐effective and atom‐economical synthetic approach that avoids the formation of harmful byproducts. However, achieving high yields under mild conditions remains challenging, due to the difficulty in efficiently activating the α‐CH bonds of amines and the multiple competing ...
Tsukino Ishizaki +2 more
wiley +1 more source
Green and mild retro-aldol synthesis of natural benzaldehyde from cinnamaldehyde over Li-doped MgO catalysts. [PDF]
Phan NQ +5 more
europepmc +1 more source

