Results 31 to 40 of about 16,649 (384)
Synthesis of 4-hydroxy and 6-hydroxyindoles: a renaissance of the Bischler reaction
In the present work we studied a modified Bischler-Möhlau reaction – synthesis of indoles from benzoin and aniline. Our proposed modification of this method differs from that described earlier in that the reaction is carried out at a lower temperature ...
A. D. Sharapov+3 more
doaj +1 more source
(±) Methanodibenzodiazocine tethered [C-H]δ+ functional site: Study towards benzoin condensation and Baylis-Hillman reactions [PDF]
New heterocyclic ring systems consisting of (±) methanodibenzodiazocine and imidazolium/ benzimidazolium salts were synthesized in very good yield. Subsequently, these halide salts were subjected to the anion exchange reaction with KPF6 to yield ...
Arruri, S, G, Prabusankar
core +5 more sources
The enantioselective palladium-catalyzed decarboxylative allylic alkylation of fully substituted α-hydroxy acyclic enol carbonates providing tetrasubstituted benzoin derivatives is reported. Investigation into the transformation revealed that preparation
Rémi Lavernhe+3 more
openalex +3 more sources
Attempts were made to minimize the amounts of catalyst and solvent in the NHC-catalyzed benzoin reactions of solid aldehydes. In some case, solid-to-solid conversions proceeded in the solvent-free NHC-catalyzed benzoin reactions. Even if a mixture of the
Kentaro Iwai+3 more
semanticscholar +1 more source
In the title compound, C15H15N3OS, the thiosemicarbazone moiety is planar, with a maximum deviation of 0.0369 (11) A, and has an E configuration. The planar phenyl rings make dihedral angles of 26.56 (9) and 81.20 (5)° with the plane of the thiosemicarbazone moiety. In the molecule, there are two intramolecular interactions of types N—H⋯O and N—H⋯N.
Dincer, M+3 more
openaire +3 more sources
Facile O-atom insertion into C-C and C-H bonds by a trinuclear copper complex designed to harness a singlet oxene [PDF]
Two trinuclear copper [CuICuICuI(L)]1+ complexes have been prepared with the multidentate ligands (L) 3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(dimethylamino)ethyl)(methyl)amino)propan-2-ol) (7-Me) and (3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(diethylamino)
Chan+13 more
core +4 more sources
The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one
The title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the ...
Martin J. Di Grandi+2 more
doaj +1 more source
First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature [PDF]
Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-‐butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was
Chiarotto, I., Feroci, M., Inesi, A.
core +1 more source
A rapid, highly efficient and mild green synthesis of benzoin was performed using substituted benzaldehyde catalyzed by KCN and imidazolium salts in EtOH/H2O under ultrasonic activation.
Javad Safari+3 more
doaj +1 more source
Increasing the stability of incense gum extract (Styrax benzoin) with a mixture of surfactants
Styrax benzoin is a type of incense produced in North Tapanuli, Indonesia. The content of metabolite compounds provides wide use in pharmaceuticals.
Nora Susanti+2 more
doaj +1 more source