Results 31 to 40 of about 16,649 (384)

Synthesis of 4-hydroxy and 6-hydroxyindoles: a renaissance of the Bischler reaction

open access: yesChimica Techno Acta, 2022
In the present work we studied a modified Bischler-Möhlau reaction – synthesis of indoles from benzoin and aniline. Our proposed modification of this method differs from that described earlier in that the reaction is carried out at a lower temperature ...
A. D. Sharapov   +3 more
doaj   +1 more source

(±) Methanodibenzodiazocine tethered [C-H]δ+ functional site: Study towards benzoin condensation and Baylis-Hillman reactions [PDF]

open access: yes, 2015
New heterocyclic ring systems consisting of (±) methanodibenzodiazocine and imidazolium/ benzimidazolium salts were synthesized in very good yield. Subsequently, these halide salts were subjected to the anion exchange reaction with KPF6 to yield ...
Arruri, S, G, Prabusankar
core   +5 more sources

Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin‐Derived Enol Carbonates

open access: bronzeAdvanced Synthesis and Catalysis, 2019
The enantioselective palladium-catalyzed decarboxylative allylic alkylation of fully substituted α-hydroxy acyclic enol carbonates providing tetrasubstituted benzoin derivatives is reported. Investigation into the transformation revealed that preparation
Rémi Lavernhe   +3 more
openalex   +3 more sources

Minimization of Amounts of Catalyst and Solvent in NHC-Catalyzed Benzoin Reactions of Solid Aldehydes: Mechanistic Consideration of Solid-to-Solid Conversion and Total Synthesis of Isodarparvinol B

open access: yesACS Omega, 2020
Attempts were made to minimize the amounts of catalyst and solvent in the NHC-catalyzed benzoin reactions of solid aldehydes. In some case, solid-to-solid conversions proceeded in the solvent-free NHC-catalyzed benzoin reactions. Even if a mixture of the
Kentaro Iwai   +3 more
semanticscholar   +1 more source

Benzoin thiosemicarbazone

open access: yesActa Crystallographica Section E Structure Reports Online, 2005
In the title compound, C15H15N3OS, the thio­semicarbazone moiety is planar, with a maximum deviation of 0.0369 (11) A, and has an E configuration. The planar phenyl rings make dihedral angles of 26.56 (9) and 81.20 (5)° with the plane of the thio­semicarbazone moiety. In the mol­ecule, there are two intramolecular interactions of types N—H⋯O and N—H⋯N.
Dincer, M   +3 more
openaire   +3 more sources

Facile O-atom insertion into C-C and C-H bonds by a trinuclear copper complex designed to harness a singlet oxene [PDF]

open access: yes, 2007
Two trinuclear copper [CuICuICuI(L)]1+ complexes have been prepared with the multidentate ligands (L) 3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(dimethylamino)ethyl)(methyl)amino)propan-2-ol) (7-Me) and (3,3'-(1,4-diazepane-1,4-diyl)bis(1-((2-(diethylamino)
Chan   +13 more
core   +4 more sources

The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one

open access: yesIUCrData, 2019
The title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the ...
Martin J. Di Grandi   +2 more
doaj   +1 more source

First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature [PDF]

open access: yes, 2017
Cyclic voltammetry provides the first direct evidence of N-­heterocyclic carbene (NHC) presence in neat 1-‐butyl-­3-­methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was
Chiarotto, I., Feroci, M., Inesi, A.
core   +1 more source

An investigation of the catalytic potential of potassium cyanide and imidazolium salts for ultrasound-assisted synthesis of benzoin derivatives

open access: yesJournal of Saudi Chemical Society, 2015
A rapid, highly efficient and mild green synthesis of benzoin was performed using substituted benzaldehyde catalyzed by KCN and imidazolium salts in EtOH/H2O under ultrasonic activation.
Javad Safari   +3 more
doaj   +1 more source

Increasing the stability of incense gum extract (Styrax benzoin) with a mixture of surfactants

open access: yesJournal of Advanced Pharmaceutical Technology & Research, 2023
Styrax benzoin is a type of incense produced in North Tapanuli, Indonesia. The content of metabolite compounds provides wide use in pharmaceuticals.
Nora Susanti   +2 more
doaj   +1 more source

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