Results 121 to 130 of about 103,633 (342)

Molecular‐Scale Tuning of Low‐Molecular‐Weight Gelators Controls Supramolecular Assembly and Directs Human Mesenchymal Stem Cell Growth

open access: yesAngewandte Chemie, EarlyView.
Chemistry in charge of biology! Simple low‐molecular‐weight gelators, with minor modifications in molecular structure, self‐assemble differently and can also co‐assemble when simultaneously triggered. This creates a family of gels with different properties that direct the growth of stem cells in different ways.
Chayanan Tangsombun   +5 more
wiley   +2 more sources

Electrochemical Nitrate Reduction Reaction to Ammonia at Industrial‐Level Current Densities

open access: yesAdvanced Science, EarlyView.
This review starts from the mechanism and theoretical basis of electrochemical nitrate reduction reaction (NO3−RR), and systematically summarizes and discusses the design strategies of industrial‐level current density catalysts. In addition, the progress of industrial‐level NO3−RR‐based electrolyzers, including flow reactor and membrane electrode ...
Zhijie Cui   +4 more
wiley   +1 more source

Mild Generation of Highly Nucleophilic N‐Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation

open access: yesAngewandte Chemie, EarlyView.
A less hindered and highly nucleophilic N‐heterocyclic carbene (NHC) boryl anion is generated at room temperature by reacting sp2–sp3 diboron reagent (NHC)BH2Bpin with KOtBu. This highly reactive anion demonstrates broad reactivity with various electrophiles, including those traditionally considered inert, enabling their efficient borylation.
Weixuan Sun, Peiqi Zhang, Hairong Lyu
wiley   +2 more sources

Comparative metabolome and transcriptome revealed the CpODO1 transcription factor controlling the varied floral scent traits of three wintersweet cultivars

open access: yesHorticultural Plant Journal
Wintersweet (Chimonanthus praecox), a well-known fragrant flowering shrub, is extensively planted for ornamental purpose and production of floral essential oil.
Yubing Yong   +6 more
doaj   +1 more source

Enantioselective Reductive Alkenylation of α‐CF2H (‐CF3) Amino Halides: Rapid Access to Chiral α‐CF2H (‐CF3) Allylamines

open access: yesAdvanced Science, EarlyView.
Difluoromethyl (CF2H) group, the bioisostere of hydroxyl thiol methyl or amide is privileged in medicinal chemistry due to hydrogen‐binding ability and lipophilic, metabolically stable, and chemical inert nature. However, enatioseleceive CF2H introduction remains challenging.
Peng Liu   +9 more
wiley   +1 more source

NUCLEAR MAGNETIC RESONANCE THE GELLED PRODUCT OF CANNIZZARO REACTION

open access: yesAvances en Ciencias e Ingeniería, 2015
The paper presents the nuclear magnetic resonance (NMR) of proton 1H, carbon 13C and two dimensional spectrums, product of a green organic synthesis of redox on the Cannizzaro reaction.
Lilia Fernández-Sánchez   +4 more
doaj  

Catalytic potential of titanium oxide and gold dopped titanium oxide nanoparticles in the selectivity benzyl alcohol oxidation

open access: diamond, 2022
Arthur Martins Gabriel   +3 more
openalex   +2 more sources

Strategies for Paired Electrolysis with Enhanced Efficiency

open access: yesAdvanced Energy and Sustainability Research, EarlyView.
This review summarizes the fundamentals, challenges, and strategies for paired electrolysis, with examples in the chlor‐alkali, hydrogen production, CO2 reduction, and ammonia synthesis industries. Future directions include the development of advanced membranes, computational studies, process integration, scale‐up, and techno‐economic analysis.
Yuanyuan Yao   +6 more
wiley   +1 more source

Efficient conversion of aromatic and phenylpropanoid alcohols to acids by the cascade biocatalysis of alcohol and aldehyde dehydrogenases

open access: yesSynthetic and Systems Biotechnology
Benzyl and phenylpropanoid acids are widely used in organic synthesis of fine chemicals, such as pharmaceuticals and condiments. However, biocatalysis of these acids has received less attention than chemical synthesis.
Zetian Qiu   +8 more
doaj   +1 more source

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