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Propane oxidation at 653-673 K and benzyl alcohol oxidation at 393 K over phase-pure MoV(TeNb) M1 oxide catalysts were studied to gain insight into the multiple catalytic functions of the surface of the M1 structure.
Yury V Kolen´Ko +2 more
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The anodic oxidation of benzyl alcohol to benzaldehyde
Journal of Electroanalytical Chemistry, 1972Summary The anodic oxidation of benzyl alcohol in acetonitrile has been investigated by preparative electrolysis at a rotating Pt disc with and without a PTFE scraper blade. The kinetics of the process have been investigated by potentiostatic pulse measurements.
O.R. Brown, S. Chandra, J.A. Harrison
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Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes with oxone
Tetrahedron, 2012Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes to their corresponding oxidation products has been shown to be accomplished directly with oxone. The methodology that involves mere stirring/heating of the reactants and oxone in acetonitrile/water (1:1, v/v) is simple and practical, but is limited to substrates that do not contain ...
Keshaba Nanda Parida +3 more
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Oxidation of benzyl alcohol and benzaldehyde with xenon trioxide
Journal of Pharmaceutical Sciences, 1967Benzyl alcohol is oxidized by xenon trioxide in acidic or neutral solution to benzaldehyde and benzoic acid. The course of the reaction was followed by gas chromatography. Thin-layer chromatography was used to identify the products of oxidation.
H J, Rhodes, R, Kluza, M I, Blake
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Electrochemically Mediated Oxidation of Sensitive Propargylic Benzylic Alcohols
Organic Letters, 2022The electrochemical oxidation of sensitive propargylic benzylic alcohols having varying substituents is reported. We describe the preparation and characterization of N-hydroxytetrafluorophthalimide (TFNHPI) and pseudo-high-throughput development of a green electrochemical oxidation protocol for sensitive propargylic benzylic alcohols that employs ...
Chad E. Hatch +8 more
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Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation
Journal of the American Chemical Society, 2012Four distinct intermediates, Ru(IV)═O(2+), Ru(IV)(OH)(3+), Ru(V)═O(3+), and Ru(V)(OO)(3+), formed by oxidation of the catalyst [Ru(Mebimpy)(4,4'-((HO)(2)OPCH(2))(2)bpy)(OH(2))](2+) [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl) and 4,4'-((HO)(2)OPCH(2))(2)bpy = 4,4'-bismethylenephosphonato-2,2'-bipyridine] on nanoITO (1-PO(3)H(2)) have been identified ...
Aaron K, Vannucci +5 more
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Photochemical Selective Oxidation of Benzyl Alcohols to Aldehydes or Ketones
The Journal of Organic Chemistry, 2023Using Eosin Y as a metal-free photocatalyst and O2 as an oxidant, the present study reports a new photochemical protocol that enables efficient aerobic oxidation of various benzyl alcohols to the corresponding aldehydes or ketones in excellent yields under mild reaction conditions.
Zhen-Xiang He +6 more
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A DFT investigation of the catalytic oxidation of benzyl alcohol using graphene oxide
Journal of Molecular Modeling, 2023Metal-free heterogeneous materials have attracted great interest due to their potential to facilitate various organic transformations in line with circular economy and green chemistry principles. Among various 2D materials, graphene oxide (GO) is considered an attractive material for numerous applications in physics, chemistry, biology, material ...
Hassan, Chataoui +5 more
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