Results 41 to 50 of about 20,772 (274)

Synthesis of Biaryls via Benzylic C–C Bond Cleavage of Styrenes and Benzyl Alcohols

, 2015
A metal-free oxidative coupling of styrenes and benzyl alcohols with arenes has been developed for the synthesis of biaryls. The reaction features a conspicuous benzylic C–C bond cleavage of styrenes and benzyl alcohols. The reaction with both substrates
Arvind Kumar (227201), Bhahwal Ali Shah (1490659)   +1 more
core   +1 more source

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

Advanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang, Avirup Sardar, Weijie Ji, Zhongyu Liu, Rongchao Jin   +4 more
wiley   +1 more source

Catalytic Selective Oxidation of Benzyl Alcohols to Aldehydes with Rhenium Complexes

, 2005
The system (nBu4N)ReO4 5/PhIO/CH 2Cl2, T = 298 K catalyses effectively and with total selectivity the anaerobic oxidation of a range of primary substituted benzyl alcohols (o-, m-, p-X-C6H4-CH2OH, X = H, Me, MeO, Cl, NO2, CF3) to the corresponding ...
Mertis, Konstantinos, Koinis, Spyros, Paraskevopoulou, Patrina, Stavropoulos, Pericles, Psaroudakis, Nikos   +4 more
core   +2 more sources

Modulus‐Switchable Miniature Robots for Biomedical Applications: A Review

Advanced Robotics Research, EarlyView.
Materials, robot designs, proof‐of‐concept functions, and biomedical applications of modulus‐switchable miniature robots. Miniature soft robots have shown great potential in biomedical applications due to their excellent controllability and suitable mechanical properties in biological environments.
Chunyun Wei, Yibin Wang, Jiangfan Yu
wiley   +1 more source

3D Printing of Soft Robotic Systems: Advances in Fabrication Strategies and Future Trends

Advanced Robotics Research, EarlyView.
Collectively, this review systematically examines 3D‐printed soft robotics, encompassing material selections, function integration, and manufacturing methodologies. Meanwhile, fabrication strategies are analyzed in order of increasing complexity, highlighting persistent challenges with proposed solutions.
Changjiang Liu, Bin Cui, Xumin Huang, Xiaoyu (Rayne) Zheng, T. Thang Vo‐Doan, Ruirui Qiao   +5 more
wiley   +1 more source

Polyvinylpyrrolidone-bromine complex: An efficient polymeric reagent for selective preparation of benzyl bromides in the presence of hexamethyldisilane

Bulletin of the Chemical Society of Ethiopia, 2012
Benzylic bromides were conveniently obtained in high yields via the reaction of the corresponding alcohols with crosslinked polyvinylpyrrolidone-bromine complex (PVPP-Br2)/hexamethyldisilane in chloroform at reflux condition.
Moslem M. Lakouraj, Masoud Mokhtary
doaj  

Green Synthesis of Diphenyl‐Substituted Alcohols Via Radical Coupling of Aromatic Alcohols Under Transition‐Metal‐Free Conditions

ChemistryOpen
Alcohols are common alkylating agents and starting materials alternative to harmful alkyl halides. In this study, a simple, benign and efficient pathway was developed to synthesize 1,3‐diphenylpropan‐1‐ols via the β‐alkylation of 1‐phenylethanol with ...
Dr. Ha V. Le, M. Sc. Vy T. B. Nguyen, M. Sc. Huy X. Le, Dr. Tung T. Nguyen, Dr. Khoa D. Nguyen, Dr. Phuoc H. Ho, Thuong T. H. Nguyen   +6 more
doaj   +1 more source

Zinc Exposure Causes Disulfidptosis to Induce Miscarriage by Up‐Regulating GATA1/METTL1/SLC7A11 Axis

Advanced Science, EarlyView.
Zn exposure up‐regulates GATA1, promoting GATA1‐mediated METTL1 and SLC7A11 transcription. It also enhances METTL1‐mediated m7G modification on SLC7A11 mRNA, increasing SLC7A11 mRNA stability. Ultimately, Zn exposure up‐regulates SLC7A11 at both transcriptional and post‐transcriptional levels, causing disulfidptosis. Knockdown of murine Slc7a11, Gata1,
Wenxin Huang, Yi Sun, Yanxin Wang, Haijun Yan, Xiaoping Yue, Weidong Wu, Xueyu Chen, Jinfang Zhang, Yanbing Lin, Qiong Lei, Nan Ji, Shuaishuai Xing, Liqin Zeng, Qingzheng Kang, Depeng Zhao, Geng Guo, Huidong Zhang   +16 more
wiley   +1 more source

Palladacarboxamide Capping Reagents for Carbon Isotope Labeling and Pharmaceutical Diversification

Angewandte Chemie, EarlyView.
Herein, we present a method for carbon isotope labeling of arylamides via the coupling of air‐stable palladium carboxamide complexes and boronic ester/acids. A wide variety of functionalized boronic esters and acids have been coupled with simple palladium carboxamides complexes.
Daniel V. Hoffmann, Anika Schick, Lasse Kjær, Vitus J. Enemærke, Clemens Kaussler, Jens Torp, Pablo Martínez‐Pardo, Charles S. Elmore, Troels Skrydstrup   +8 more
wiley   +2 more sources

FELT CARBON ELECTRODES MODIFIED WITH RUTHENIUM DIMERIC FILM: APPLICATION IN ALCOHOL ELECTROCHEMICAL OXIDATIONS

Eclética Química, 2018
Modified films were prepared by deposition of poli-[(H2O)(L)2Ru-O-Ru(L)2(OH2)]4+ (L=4-methyl- 4´-pyrrol-1-yl-buthyl-2,2´-bipyridine) (poly-dim.), on felt carbon electrodes, by direct anodic electropolymerization of the monomer.
Claudemir Batalini, Wagner Ferraresi De Giovani   +1 more
doaj   +1 more source