Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers
Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
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Comprehensive spatiotemporal dataset of shared bicycle operations in Xiamen China. [PDF]
Cai J +5 more
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Bond and Antibond Resonances: A Unified Framework for Singlet Biradical Character
The electronic structure of a variety of singlet biradicaloids may be described in the Lewis picture using single antibonds as the central bonding motif. In conjunction with a consistent set of biradical indicators, we can resolve some long‐standing disputes over the biradical character of molecules such as O3 and S2N2.
Daniel T. Gschwind, Jonas Bresien
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<i>NECTIN4</i> Amplification Is a Frequent Event in Central Nervous System Metastases of Urothelial Carcinoma. [PDF]
Weiten R +15 more
europepmc +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
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Effects of Bike-Fitting on Lower Back Pain in Cyclists: A Systematic Review. [PDF]
Barrajón C +4 more
europepmc +1 more source
Sustainable Synthesis of 4,7‐Dihydro‐4,7‐ethano‐2H‐isoindoles—Key Building Blocks to Benzoporphyrins
A facile and sustainable route to isoindole derivatives—key benzoporphyrin precursors—brings high‐ and low‐symmetry benzoporphyrins closer to practical application. ABSTRACT Benzoporphyrins, π extended porphyrin analogues, exhibit remarkable potential for optoelectronic and theragnostic applications, yet have remained largely confined to fundamental ...
Lampros Pascal Gazetas +5 more
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Worth a Second Look: Report of a Rare Traumatic Pisiform Fracture Following a Bicycle Fall. [PDF]
Abulesz YT, Kralinger F.
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Total syntheses of agelamadin F and (±)‐tauroacidin A were achieved by sodium chlorite (NaClO2)‐mediated oxidative C─N coupling. Nine C15–N–amino acid‐substituted oroidin derivatives were successfully prepared to demonstrate the applicability and versatility of this oxidative coupling reaction.
Ryosuke Hirozumi +3 more
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The power of lifestyle intervention to induce glycaemic control in a patient with newly diagnosed type 2 diabetes and HbA1c >10. [PDF]
Ferreira A +3 more
europepmc +1 more source

