A bifunctional metal‐organic framework (MOF) catalyst with dual active sites is developed for enabling NH2OH electrosynthesis via NitRR with both high selectivity and activity. ABSTRACT Electrocatalytic nitrate reduction reaction (NitRR) offers a promising route for hydroxylamine (NH2OH) synthesis under ambient conditions.
Yingying Zou +9 more
wiley +2 more sources
New melatonin biphenyl-linked scaffold targeting colorectal cancer: design, synthesis, biological, and ADME-Tox modelling studies. [PDF]
Silva-García M +3 more
europepmc +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source
Newly Synthesized Telmisartan-Amino Acid Conjugates Exhibit Enhanced Cytotoxic Effects in Malignant Melanoma Cells. [PDF]
Vukadinović D +5 more
europepmc +1 more source
Diselenide‐Catalyzed Asymmetric Allenylation of Alkynes
An asymmetric allenylation of alkynes is described using chiral lactamides‐based diselenides under oxidative conditions. This led to the corresponding allenylamides with enantiomeric excesses up to 72%, and uncovers an interesting stereodivergency feature related to the β‐H‐syn‐elimination of transient Se(IV) intermediates.
Rongyu Sun +5 more
wiley +1 more source
Structural Tuning of Vidofludimus for High-Efficacy NR4A Agonism. [PDF]
Vietor J +6 more
europepmc +1 more source
<i>In situ</i> interrogation of microorganisms mediating hydrocarbon degradation. [PDF]
Ren X-Y +8 more
europepmc +1 more source
<i>L</i>-region-selective annulative π-extension through dearomative activation of polycyclic aromatic hydrocarbons. [PDF]
Nakata K, Matsuoka W, Ito H, Itami K.
europepmc +1 more source
Pyridinium-Fused 1,3-Selenazoles via Cyclizations of 2-Pyridylselenyl Chloride with Alkynes: Synthesis, Structures, and Antifungal Properties. [PDF]
Dukhnovsky EA +9 more
europepmc +1 more source
Guest-induced emission enhancement in the permanent porous conjugated carboracycle crystal. [PDF]
Yuhara K +5 more
europepmc +1 more source

