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pH-differential design and operation of electrochemical and photoelectrochemical systems with bipolar membrane [PDF]
© 2020 Elsevier Ltd Electrochemical and photoelectrochemical systems for hydrogen production and CO2 reduction are regarded as prospective technologies to achieve carbon-free energy vision.
Hao Zhang, Kui Jiao, Jin Xuan
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Reactive and Functional Polymers, 1996
Abstract Bipolar membranes are composed of two distinct layers which are selective to ions of opposite charges. Because of this unique characteristics, bipolar membranes are able to electrically separate water into hydrogen and hydroxyl ions. These membranes in conjunction with conventional cation- and anion-exchange membranes in a cell stack, have ...
G.S. Trivedi +4 more
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Abstract Bipolar membranes are composed of two distinct layers which are selective to ions of opposite charges. Because of this unique characteristics, bipolar membranes are able to electrically separate water into hydrogen and hydroxyl ions. These membranes in conjunction with conventional cation- and anion-exchange membranes in a cell stack, have ...
G.S. Trivedi +4 more
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Development of bipolar membranes
Desalination, 1988Abstract The large-scale industrial use of bipolar membrane for the production of acids and bases from the corresponding salts is limited by the properties of the commercially available bipolar membranes. Today's membranes are unsatisfactory in terms of their selectivity and chemical stability at high pH values.
B. Bauer, F.J. Gerner, H. Strathmann
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Bipolar Faradaic Interfaces in Bipolar Membranes
ECS Meeting AbstractsIn this work, we demonstrated that a pinhole-free, solid-state and electron-conductive membrane can function as an ion exchange membrane or a solid electrolyte through bipolarized Faradaic interfacial reactions. The bipolar Faradaic interface membrane (BFIM) is an insulator to ionic conduction in the bulk phase.
Dawei Xi, Michael J. Aziz
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Journal of Membrane Science, 2010
Abstract A hybrid bipolar membrane was developed for high-temperature applications. In particular, the cation-exchange layer was prepared by hybridizing sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) (SPPO) with (3-aminopropyl) triethoxysilane (A1100) while the anion-exchange layer was prepared from a hybrid anion-exchange material—poly(VBC-co-γ ...
Anlei Wang +4 more
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Abstract A hybrid bipolar membrane was developed for high-temperature applications. In particular, the cation-exchange layer was prepared by hybridizing sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) (SPPO) with (3-aminopropyl) triethoxysilane (A1100) while the anion-exchange layer was prepared from a hybrid anion-exchange material—poly(VBC-co-γ ...
Anlei Wang +4 more
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ECS Meeting Abstracts, 2011
Abstract not Available.
Nathan P. Craig, John Newman
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Abstract not Available.
Nathan P. Craig, John Newman
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Physical Chemistry Chemical Physics, 2013
A reaction kinetic model of the bipolar membrane interface in the bipolar membrane fuel cell (BPMFC) was proposed based on the p-n junction theory and chemical reaction kinetics. It verified the self-humidification feasibility of the BPMFC successfully.
Sikan, Peng +4 more
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A reaction kinetic model of the bipolar membrane interface in the bipolar membrane fuel cell (BPMFC) was proposed based on the p-n junction theory and chemical reaction kinetics. It verified the self-humidification feasibility of the BPMFC successfully.
Sikan, Peng +4 more
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Current-voltage curves of bipolar membranes
Journal of Applied Physics, 1992Bipolar membranes consist of a layered ion-exchange structure composed of a cation selective membrane joined to an anion selective membrane. They are analogous to semiconductor p-n devices as both of them present current-voltage curves exhibiting similar rectification properties.
P. Ramírez +4 more
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Bipolar Patterning of Polymer Membranes by Pyroelectrification
Advanced Materials, 2015Polymer freestanding membranes with permanent bipolar patterns are fabricated by "pyroelectrification". The thermal stimulation of periodically poled lithium niobate (PPLN) crystals simultaneously generates the pyroelectric effect, the glass transition of the polymer, and therefore the periodic electric poling of the polymer.
Rega R +5 more
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Electrodialysis with Bipolar Membranes for Sustainable Development
Environmental Science & Technology, 2006Electrodialysis with bipolar membranes (EDBM) is a kind of technology that integrates solvent and salt dissociation. It can realize salt conversion without second salt pollution or provide H+ and OH-/alkoxide ions in situ without salt introduction. Thus, it inherently possesses economical and environmental benefits.
Chuanhui, Huang, Tongwen, Xu
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