Results 241 to 250 of about 46,823 (313)

Oxygen‐Tolerant Photo‐Induced Miniaturized Accelerated Atom Transfer Radical Polymerization (OPTIMA‐ATRP) for High‐Throughput Synthesis of Polymer Bioconjugates

open access: yesAngewandte Chemie, EarlyView.
Oxygen‐tolerant photo‐induced miniaturized accelerated atom transfer radical polymerization (OPTIMA‐ATRP) in water was developed for the polymerization of hydrophilic (meth)acrylate monomers under ambient or sub‐ambient (4°C) temperature and atmospheric conditions, without prior degassing, in less than 10 min, at an ultra‐small scale (< 50 µL) in ...
Arman Moini Jazani   +5 more
wiley   +1 more source

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

open access: yesAngewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang   +5 more
wiley   +1 more source

Mesoporous N,S‐Dual‐Doped Carbon Nanoreactors via Entropy‐Driven Interface Self‐Assembly for Efficient H2O2 Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An entropy‐driven interface self‐assembly strategy is proposed for the controllable synthesis of mesoporous N,S‐dual‐doped carbon nanoreactors. The N,S‐dual‐doping sites optimized the *OOH adsorption, boosting the 2e− selectivity, while the favorable mesostructure accelerated O2 enrichment.
Fei Liu   +6 more
wiley   +1 more source

Tuning the Mechanical Properties of Crosslinked Copolymers via Sequence and Solvent‐Selective Swelling for Vat Photopolymerization

open access: yesAngewandte Chemie, EarlyView.
Polymer sequence and solvent selectivity independently modulate pendant‐vinyl accessibility during photocuring, trapping different topologies in CLIP and controlling mechanical properties. ABSTRACT Block copolymers (BCPs) offer distinct advantages for vat photopolymerization by enabling mechanically programmable network structures through microphase ...
Chia‐Min Hsieh   +12 more
wiley   +1 more source

3D‐Printable Nanoporous Thermosets via Disulfide‐Based Polymerization‐Induced Microphase Separation

open access: yesAngewandte Chemie, EarlyView.
α‐Lipoic acid‐derived degradable macro‐chain transfer agents (macroCTAs) with tunable hydrophilicity drive polymerization‐induced microphase separation (PIMS) in photocurable resins. Selective etching via disulfide cleavage then generates interconnected nanoporous thermosets, and compatibility with liquid‐crystal display (LCD) 3D printing enables the ...
Xueheng Dai   +8 more
wiley   +1 more source

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