Results 111 to 120 of about 20,491 (284)

Extended Synthetic Pathways Towards Dialkyl-Substituted Phosphanylboranes

Inorganics
Phosphine–boranes have garnered growing interest for their potential in catalysis and as building blocks for inorganic polymers. While various synthetic methods exist, flexibility to introduce diverse substituents on the P centers remains limited.
Mehdi Elsayed Moussa, Oliver Hegen, Christoph Riesinger, Manfred Scheer   +3 more
doaj   +1 more source

Reduction of Cyclopropanecarboxylic Acids by Borane, a Chemoselective Reduction Sensitive to Steric Interactions and Reaction Conditions [PDF]

, 2001
Leiv K. Sydnes, Paula F. F. Pereira, Marcel Sandberg, Hans H. Øvrebø   +3 more
openalex   +1 more source

EDA Complex–Mediated C(sp3)–H Cross‐Dehydrogenative Coupling Enables Synthesis of Noncanonical α,β‐Diamino Acids

European Journal of Organic Chemistry, EarlyView.
Access to nonproteinogenic α,β‐diamino acids from simple feedstock precursors is of great interest to generate medicinal small molecule libraries. We report a regioselective photoinduced C(sp3)–C(sp3) cross‐dehydrogenative coupling (CDC) of N‐arylglycine derivatives with amides.
Krishnakumar Sachidanandan, Cole Stenftenagel, Athul Joshy, Alexander M. Cluff, Sébastien Laulhé   +4 more
wiley   +1 more source

Alkali Metal Dihydropyridinates: From Hidden Intermediates to Promising Well-defined Catalysts?

CHIMIA
Often the synthesis of catalysts can be time-consuming, multistep tasks, but sometimes they can turn up fortuitously, hidden treasure finds in essence. The alkali metal dihydropyridinate complexes discussed here fit the latter scenario.
Thomas M. Horsley Downie, Robert E. Mulvey   +1 more
doaj   +1 more source

Proton transfer reactions of hydrazine-boranes

, 2015
International audienceHydrazine-borane and hydrazine-diborane contain respectively 15.4 and 16.9 wt% of hydrogen and are potential materials for hydrogen storage.
Adamson, Aiko, Burk, Peeter, Guillemin, Jean-Claude   +2 more
core   +3 more sources

ADDITIONS OF BORANE PROMOTED BY WILKINSON'S CATALYST [PDF]

, 1994
Donna A. Chen, Kevin W. Gillman, Pingyun Feng, Terence C. Morrill   +3 more
openalex   +1 more source

Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways

European Journal of Organic Chemistry, EarlyView.
Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian, Andrea Serafino, Luc Neuville, Géraldine Masson   +3 more
wiley   +1 more source

Reaktionen der Natrium-Komplexe aromatischer Ether mit Dichlor(diorganylamino)boranen/Reactions of Sodium Complexes of Aromatic Ethers with Dichloro(diorganylamino)boranes [PDF]

, 1989
W. MARINGGELE, Anton Meller
openalex   +1 more source

Synthetic Implications of Spin States in the Reactivity of Ni Intermediate Complexes in Coupling Reactions

European Journal of Organic Chemistry, EarlyView.
The formation of triplet Ni(II) complexes by activation of bromoalkenes with alkyl‐ or boryl Ni(I) is key to control the outcome of the reductive cross‐coupling of bromoalkanes precluding the formation of alkylboronates. We present a mechanistic study on the Ni‐catalyzed cross‐coupling reaction of bromoalkanes with diboron compounds as reductants.
Diego J. Cárdenas
wiley   +1 more source

Is Li$_2$Pd$_3$B a self-doped hole superconductor ?

, 2004
We propose that the electrons responsible for superconductivity in Li2Pd3B come from the palladium 4d-electrons. So, its electronic properties are likely to be dominated by strong electronic correlations.
Affleck, Anderson, Baskaran, Baskaran, Baskaran, Buzea, Debanand Sa, Eibenstein, Eltsev, He, Iye, Kiessling, Kivelson, Kotliar, Mackenzie, Manas Sardar, Muetterties, Nagamatsu, Paramekanti, Singh, Sorella   +20 more
core   +1 more source