Results 91 to 100 of about 10,808 (271)
Chemistry – A European Journal, EarlyView.Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo +5 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2010 In situ formation of two cyclic (alkyl) (amino) carbenes (CAACs) followed by addition of BF3•Et2O provided the first two examples of CAAC–BF3 complexes: 1-(2,6-diisopropylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene trifluoroborane, and 2-(2,6 ...
Julien Monot +5 more
doaj +1 more source
Chemistry – A European Journal, EarlyView.A series of thirteen (N‐heterocyclic carbene) NHC‐stabilized borenium cations is synthesized from NHC→BH3 complexes via hydroboration and condensation with diols. The novel compounds are fully characterized. Eight crystal structures are presented. Kinetic and NMR data show how the structural features translate to catalytic activity in hydrosilylation ...
Michał Jakubczyk +4 more
wiley +1 more source
Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes
Chemistry – A European Journal, EarlyView.We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel +5 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.To expand the acid‐responsive behavior of diphenylpyridylmethyl stable luminescent radicals, additional pyridyl groups were introduced. Dual acid responsiveness was observed, involving both the newly incorporated pyridyl groups and the PyBTM moieties.
Yohei Hattori +3 more
wiley +1 more source
Dihydrogen Bond in the Aminoborane Complex of a Nicergoline Intermediate
Molecules, 2019 An aminoborane side product from the nicergoline manufacture process was identified by single-crystal X-ray diffraction. As boranes of pharmaceutical molecules are quite rare, the binding potential of the BH3 group was investigated and compared with ...
Jan Čejka +4 more
doaj +1 more source
Nonaerospace uses of chemical rocket technology [PDF]
Nonaerospace uses of chemical rocket ...
Olson, W. T.
core +1 more source
Heteroatom‐Doped Graphdiynes and Their Applications in Photo‐/Electro‐Catalytic CO2 Conversion
Carbon Innovation, EarlyView.This review highlights the versatile role of doped graphdiyne (GDY) in boosting CO2 conversion, where metal and non‐metal doping simultaneously tune the electronic structure, create abundant active sites, and improve charge separation, light harvesting, and CO2 adsorption.
Fangzhou Yang +3 more
wiley +1 more source
Boranes in Organic Chemistry 2. ОІ-Aminoalkyl- and ОІ-Sulfanylalkylboranes in Organic Synthesis
Eurasian Chemico-Technological Journal, 2002 Problems on using of ОІ-aminoalkyl- and ОІ-sulfanylalkylboranes in organic synthesis are considered in this review. The synthesis of boron containing a-aminoacids by Curtius rearrangement draws attention.
V.M. Dembitsky +2 more
doaj +1 more source