Results 71 to 80 of about 10,808 (271)
CO2 reduction with protons and electrons at a boron-based reaction center. [PDF]
, 2019 Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparation of
Essex, Laura A +3 more
core
Nature Communications, 2019 Polymers featuring p-block elements other than carbon are of interest for a range of applications, but access to highly-substituted examples remains challenging.
Nicola L. Oldroyd +5 more
doaj +1 more source
Aluminum Borate Nanowires from the Pyrolysis of Polyaminoborane Precursors [PDF]
, 2016 Polyaminoboranes [N(R)H-BH2]n (1: R = H, 2: R = Me) were pyrolyzed on a range of substrates: silicon, metal foils (stainless steel, nickel, and rhodium), and sapphire wafers, as well as on Al2O3 and AlN powders.
Du, Van A +3 more
core +2 more sources
Lithium dihydropyridine dehydrogenation catalysis : a group 1 approach to cyclisation of diamine-boranes [PDF]
, 2017 In reactions restricted previously to a ruthenium catalyst, a 1-lithium-2-alkyl-1,2-dihydropyridine complex is shown to be a competitive alternative dehydrogenation catalyst for the transformation of diamine boranes to cyclic 1,3,2-diazaborolidines ...
Kennedy, Alan R. +4 more
core +1 more source
Role of Li_2B_(12)H_(12) for the Formation and Decomposition of LiBH_4 [PDF]
, 2010 By in situ X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) spectroscopy, the role of Li_2B_(12)H_(12) for the sorption of LiBH_4 is analyzed.
Friedrichs, O. +3 more
core
, 2014 Citation: 'boranes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.B00709 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial usage
openaire +1 more source
Isolation and Reactivity of a Square‐Planar Trisamido Silane
Angewandte Chemie International Edition, EarlyView.We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel +5 more
wiley +1 more source
Unsymmetrical Diboron Reagents: Application in Borylation Reactions of Unsaturated Bonds
Molecules, 2019 In the past decades, borylation reactions have received extensive research interest and have developed into effective tools in the synthesis of versatile organoboron compounds. Boranes and symmetrical diboron compounds are commonly utilized as borylating
Siyi Ding, Liang Xu, Zongcheng Miao
doaj +1 more source
Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(II), Shimoi-type, η1-BH complex [PDF]
, 2016 The platinum complex [Pt(IBu′)(IBu)][BAr] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines.
Conejero, Salvador +3 more
core +1 more source
The propargyl rearrangement to functionalised allyl-boron and borocation compounds [PDF]
, 2016 A diverse range of Lewis acidic alkyl, vinyl and aryl boranes and borenium compounds that are capable of new carbon–carbon bond formation through selective migratory group transfer have been synthesised.
Hansmann, Max M. +6 more
core +1 more source