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Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
He huaxue yu fangshe huaxue, 2023 Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers
JING Yi +4 more
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Tuning the Solid-State Hydrogen Release of Ammonia Borane by Entrapping the Intermediates: The Role of High-Boiling-Point Amines [PDF]
MoleculesAmmonia borane is a promising hydrogen storage material due to its high hydrogen content, but its use as hydrogen carrier under thermal stimuli involves the production of several byproducts, such as borazine, reducing hydrogen purity and the overall ...
Mattia Bartoli +5 more
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Isolable Diaminophosphide Boranes [PDF]
Chemistry – A European Journal, 2020 AbstractMetalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and selective access route to a range of metal diaminophosphide boranes M[(R2N)2P(BH3)] (M=Li, Na, K; R=alkyl, aryl) with acyclic or heterocyclic molecular backbones, whereas reduction of a chlorodiaminophosphine borane gave less satisfactory results.
Markus Blum +5 more
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Dehydroborylation of Terminal Alkynes Using Lithium Aminoborohydrides
Molecules, 2023 Dehydrogenative borylation of terminal alkynes has recently emerged as an atom-economical one-step alternative to traditional alkyne borylation methodologies.
P. Veeraraghavan Ramachandran +1 more
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The Hydrogen-Storage Challenge: Nanoparticles for Metal-Catalyzed Ammonia Borane Dehydrogenation.
Small, 2021 Dihydrogen is one of the sustainable energy vectors envisioned for the future. However, the rapidly reversible and secure storage of large quantities of hydrogen is still a technological and scientific challenge.
Clève D. Mboyi +5 more
semanticscholar +1 more source
Preparation of the 1-Methylimidazole Borane/Tetrazole System for Hypergolic Fuels
Molecules, 2022 Based on the acid–base neutralization, the (1-methylimidazolium)(tetrazol-1-yl)borane was successfully synthesized by taking advantage of the acidity of the tetrazole and the basicity of the 1-methylimidazole borane complex. Through HRMS, NMR, and FT−IR,
Xue Li +6 more
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Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid
Angewandte Chemie, 2022 The synthesis of tris(ortho‐carboranyl)borane (BoCb3), a single site neutral Lewis superacid, in one pot from commercially available materials is achieved.
Manjur O Akram +3 more
semanticscholar +1 more source
Acta Crystallographica Section E Structure Reports Online, 2009 The title compound, C3H12BN, was solved using data collected from a multiple crystal (note incomplete data shell). The cell packing is dominated by bifurcated attractive N—Hδ+...δ−H—B interactions.
Gainsford, Graeme J., Bowden, Mark E.
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Molecules, 2023 The cobalt bis(dicarbollide)(1−) anion (1−), [(1,2-C2B9H11)2-3,3′-Co(III)](1−), plays an increasingly important role in material science and medicine due to its high chemical stability, 3D shape, aromaticity, diamagnetic character, ability to penetrate ...
Lucia Pazderová +5 more
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“Activated Borane” – A Porous Borane Cluster Network [PDF]
, 2022 The unprecedented co-thermolysis of nido-decaborane (B10H14) and toluene results in a novel porous material (that we have named “Activated Borane”) containing micropores of 1.0 and 1.5 nm in diameter and a specific surface area of 774 m2 g-1 (Ar, 87 K) that is thermally stable up to 1000 oC.
Daniel Bůžek +9 more
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