Results 1 to 10 of about 1,700 (179)

Hypergolic Copper Cluster‐Based Covalent Organic Frameworks [PDF]

Advanced Science
Rational design of hypergolic materials that integrate rapid ignition with high energy density is of great significance for advancing propulsion technologies. Herein, we achieve synergistic enhancement in hypergolic performance by incorporating catalytic
Yu‐Zhou Qiao, Cai Li, Wen‐Yang Jiao, Guoqiang Sun, Xiao‐Fei Liu, Shuang‐Quan Zang   +5 more
doaj   +3 more sources

Charge-Compensated Derivatives of Nido-Carborane

Inorganics, 2023
This review summarizes data on the main types of charge-compensated nido-carborane derivatives. Compared with organic analogs, onium derivatives of nido-carborane have increased stability due to the stabilizing electron-donor action of the boron cage ...
Marina Stogniy, Igor Sivaev, Sergey Anufriev   +2 more
exaly   +3 more sources

Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine

Molecules, 2017
The enhancement of aggregation-induced emission (AIE) is presented on the basis of the strategy for improving solid-state luminescence by employing multiple o-carborane substituents.
Kazuo Tanaka, Yoshiki Chujo, Masayuki Gon   +2 more
exaly   +3 more sources

Synthesis and Anti-Tumor Evaluation of Carboranyl BMS-202 Analogues—A Case of Carborane Not as Phenyl Ring Mimetic [PDF]

Molecules
Carborane is considered a three-dimensional mimetic of phenyl rings in medicinal chemistry. BMS-202 is a potent PD-L1 inhibitor that can block the PD-L1/PD-1 interaction and restore the immune response to cancer cells.
Changxian Yuan, Chaofan Li, Chenyang Ma, Yuzhe Lin, Linyuan Wang, Guanxiang Hao, Yirong Zhang, Hongjing Li, Yuan Li, Yu Zhao, Nan Sun, Tiezheng Chen, Zhiguang Zhang, Dengfeng Cheng, Sinan Wang   +14 more
doaj   +2 more sources

Carboranes as unique pharmacophores in antitumor medicinal chemistry

Molecular Therapy: Oncolytics, 2022
Carborane is a carbon-boron molecular cluster that can be viewed as a 3D analog of benzene. It features special physical and chemical properties, and thus has the potential to serve as a new type of pharmacophore for drug design and discovery.
Yu Chen, Fukuan Du, Liyao Tang, Jinrun Xu, Yueshui Zhao, Xu Wu, Mingxing Li, Jing Shen, Qinglian Wen, Chi Hin Cho, Zhangang Xiao   +10 more
doaj   +1 more source

Synthesis, Crystal Structure, and Some Transformations of 9,12-Dichloro-ortho-Carborane

Crystals, 2022
Reaction of ortho-carborane with anhydrous AlCl3 in chloroform results in a mixture of 9-chloro, 9,12-dichloro, and 8,9,12-trichloro derivatives with 9,12-dichloro-ortho-carborane being the main product. Molecular crystal structure of 9,12-dichloro-ortho-
Sergey A. Anufriev, Sergey V. Timofeev, Olga B. Zhidkova, Kyrill Yu. Suponitsky, Igor B. Sivaev   +4 more
doaj   +1 more source

Exploiting Blood Transport Proteins as Carborane Supramolecular Vehicles for Boron Neutron Capture Therapy

Nanomaterials, 2023
Carboranes are promising agents for applications in boron neutron capture therapy (BNCT), but their hydrophobicity prevents their use in physiological environments.
Tainah Dorina Marforio, Edoardo Jun Mattioli, Francesco Zerbetto, Matteo Calvaresi   +3 more
doaj   +1 more source

Conformation-Dependent Electron Donation of Nido-Carborane Substituents and Its Influence on Phosphorescence of Tris(2,2′-bipyridyl)ruthenium(II) Complex

Crystals, 2022
In this work, we report the synthesis of the nido-carborane-substituted ruthenium complexes and the substituent effects of nido-carboranes on the optical properties.
Kyoya Uemura, Kazuo Tanaka, Yoshiki Chujo   +2 more
doaj   +1 more source

Preparation and Characterization of Carborane Modified Liquid Fluoroelastomers and the investigation of their properties

Designed Monomers and Polymers, 2021
The preparation of liquid fluoroelastomers that are liquid with excellent mechanical properties remains a challenge. Here, we show a very straightforward method to produce liquid fluoroelastomers by introducing carborane.
Juan Li
doaj   +1 more source

Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)

Chemistry, 2023
This review is an attempt to bring together the data from the literature on the synthesis and properties of icosahedral carborane derivatives, in which exo-polyhedral three- and four-coordinated boron substituents are attached directly to the carborane ...
Igor B. Sivaev
doaj   +1 more source