Results 21 to 30 of about 4,682 (219)

Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane) [PDF]

open access: yes, 2015
Examples of singly-metallated derivatives of 1,1′-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1′-1′,2′-closo-C2B10H11)-7,8-nido-C2B9H10]2- with a {Ru(p-cymene)}2+ fragment affords both the ...
Ellis, David; id_orcid   +14 more
core   +1 more source

Zwitterionic nido-Carborane-Fused Phospholes [PDF]

open access: yes, 2019
Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key ...
Guanyu Tao (4788930)   +2 more
core   +1 more source

Carborane-Based Lewis Base Catalysts for Aromatic Halogenation [PDF]

open access: yes, 2023
Haloarenes have been an important class of chemicals in modern organic chemistry field because the halide functionality offers numerous possible transformations.
Shotaro, Nakamura   +5 more
core   +1 more source

Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine

open access: yesMolecules, 2017
The enhancement of aggregation-induced emission (AIE) is presented on the basis of the strategy for improving solid-state luminescence by employing multiple o-carborane substituents.
Kenta Nishino   +4 more
doaj   +1 more source

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands [PDF]

open access: yes, 2016
We report the development of a new class of phosphorescent zwitterionic bis(heteroleptic) Ir­(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl substituents.
Peter I. Djurovich (1494643)   +8 more
core   +3 more sources

Palladium-Catalyzed Heck Reactions of Styrene Derivatives and 2-Iodo-p-carborane [PDF]

open access: yes, 2016
p-Carborane has been vinylated on the 2-B-atom in high yields using the Heck reaction. Thus, the reaction between 2-iodo-p-carborane and various styrenes [4-H-, 4-C6H4-, 4-Cl-, 4-Br-, 4-NO2-, 4-CH3O-, and 4-CH3-] resulted in the production of the ...
Rodrigo Tascon Claro (3033471)   +3 more
core   +1 more source

Molecular dynamics simulations of ortho-carborane nano-diamond storage within the nonpolar channel cavities of a right-handed coiled-coil tetrabrachion nanotube

open access: yesComputational and Structural Biotechnology Journal, 2021
Molecular dynamics simulations have been performed on a complex in which clusters of boron in the form of molecules of the nanodiamond ortho-carborane (C2B10H12) have been inserted into the four large nonpolar cavities of a nanotube of the right-handed ...
C. Harder-Viddal   +3 more
doaj   +1 more source

1,2-Diphenyl-o-carborane and Its Chromium Derivatives: Synthesis, Characterization, X-ray Structural Studies, and Biological Evaluations

open access: yesMolecules, 2023
The objective of this study is to design and synthesize substituted η6-chromium(0) tricarbonyl metal complexes carrying o-carborane units as potential boron neutron capture therapy (BNCT) agents.
Tae-Jin Ha   +3 more
doaj   +1 more source

Carborane-containing copolyester fibers with unique neutron shielding properties

open access: yesMaterials & Design, 2019
Two series of carborane-containing copolyesters were prepared by copolymerization of the newly designed 5-(1-methoxy-o-carborane)dimethyl isophthalate (BDMI) and conventional polyester monomers.
Yuane Wu   +4 more
doaj   +1 more source

Carborane Guests for Cucurbit[7]uril Facilitate Strong Binding and on Demand Removal [PDF]

open access: yes, 2020
High affinity guest have been reported for the macrocyclic host cucurbit[7]uril (CB[7]), enabling widespread applications, but preventing CB[7] materials from being returned to their guest-free state for reuse.
Anna, Kataki-Anastasakou   +7 more
core   +1 more source

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