Polymeric nanomaterials encapsulating fluorescent polyindole-nido- carborane: design, synthesis and biological evaluation [PDF]
Frontiers in ChemistryThe water-soluble nido-carborane was prepared by alkali treatment of o-carborane. A polymer PInd containing a polyindole structure was synthesized and employed to label the modified o-carborane. Subsequently, four polymeric nanomaterials were synthesized
Shihe Shao, Jin Tao, Feng Jin
exaly +9 more sources
Charge-Compensated Derivatives of Nido-Carborane [PDF]
Inorganics, 2023 This review summarizes data on the main types of charge-compensated nido-carborane derivatives. Compared with organic analogs, onium derivatives of nido-carborane have increased stability due to the stabilizing electron-donor action of the boron cage ...
Marina Yu Stogniy +2 more
exaly +5 more sources
Synthesis of Zwitter-Ionic Conjugate of Nido-Carborane with Cholesterol [PDF]
Molecules, 2021 9-HC≡CCH2Me2N-nido-7,8-C2B9H11, a previously described carboranyl terminal alkyne, was used for the copper(I)-catalyzed azide-alkyne cycloaddition with azido-3β-cholesterol to form a novel zwitter-ionic conjugate of nido-carborane with cholesterol ...
Anna A. Druzina +6 more
doaj +7 more sources
Preparation and cell imaging of a nido-carborane fluorescent complex based on multi-component polymerization. [PDF]
PLoS ONEThe biocompatibility of carborane was a difficult problem that had drawn a lot of study interest. Using multi-ion inlay binding, water-soluble polymers were created by encapsulating nido-carborane in diazaspirodecaniums such as para-poly-nido ...
Hezhong Ouyang, Zhou Wang, Min Liu
doaj +6 more sources
Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid [PDF]
MoleculesAmino acids with unusual types of chirality and their derivatives have recently attracted attention as precursors in the synthesis of chiral catalysts and peptide analogues with unique properties.
Dmitry A. Gruzdev +5 more
doaj +4 more sources
Strategies based on nido-carborane embedded indole fluorescent polymers: their synthesis, spectral properties and cell imaging studies [PDF]
Frontiers in ChemistryThe continuous preparation scheme EPO-Poly-indol-nido-carborane (E-P-INDOLCAB), L100-55-Poly-indol-nido-carborane (L-P-INDOLCAB), RS-Poly-indol-nido-carborane (S-P-INDOLCAB), and RL-Poly-indol-nido-carborane (R-P-INDOLCAB) were used to prepare the four ...
Guofan Jin
exaly +4 more sources
Conformation-Dependent Electron Donation of Nido-Carborane Substituents and Its Influence on Phosphorescence of Tris(2,2′-bipyridyl)ruthenium(II) Complex [PDF]
Crystals, 2022 In this work, we report the synthesis of the nido-carborane-substituted ruthenium complexes and the substituent effects of nido-carboranes on the optical properties.
Kyoya Uemura +2 more
doaj +2 more sources
Synthesis and Reactivity of Cyclic Oxonium Derivatives of nido-Carborane: A Review [PDF]
Reactions, 2022 Nucleophilic ring-opening reactions of cyclic oxonium derivatives of anionic boron hydrides are a convenient method of their modification which opens practically unlimited prospects for their incorporation into various macro- and biomolecules.
Marina Yu. Stogniy, Igor B. Sivaev
doaj +2 more sources
Synthesis of a novel planar-chiral nido-carborane amino acid [PDF]
Russian Chemical Bulletin, 2021 The deboronation of enantiomers of planar-chiral benzyl (3-formamido-1,2-dicarba-closo-dodecaboran-1-yl)acetate gave the individual (RP)- and (SP)-enantiomers (ee > 98%) of a new amino acid containing a nido-carborane fragment, (3-ammonio-7,8-dicarba-nido-undecaboran-7-yl)acetic acid.
Telegina, A. A. +3 more
openaire +4 more sources
Synthesis and Structure of Nido-Carboranyl Azide and Its “Click” Reactions [PDF]
Molecules, 2021 Novel zwitter-ionic nido-carboranyl azide 9-N3(CH2)3Me2N-nido-7,8-C2B9H11 was prepared by the reaction of 9-Cl(CH2)3Me2N-nido-7,8-C2B9H11 with NaN3.
Anna A. Druzina +6 more
doaj +2 more sources