Molecules, 2020 Closo-o-carboranyl compounds bearing the ortho-type perfectly distorted or planar terphenyl rings (closo-DT and closo-PT, respectively) and their nido-derivatives (nido-DT and nido-PT, respectively) were synthesized and fully characterized using ...
Hyunhee So +7 more
doaj +1 more source
Half-Sandwich Nickelacarboranes Derived from [7-(MeO(CH2)2S)-7,8-C2B9H11]−
Inorganics, 2023 New carboranyl thioethers 1-MeO(CH2)nS-1,2-C2B10H11 (n = 2, 3) were prepared by the alkylation of the trimethylammonium salt of 1-mercapto-ortho-carborane with 1-bromo- 2-methoxyethane and 1-bromo-3-methoxypropane, respectively.
Dmitriy K. Semyonov +3 more
doaj +1 more source
“Free of Base” Sulfa-Michael Addition for Novel o-Carboranyl-DL-Cysteine Synthesis
Crystals, 2020 The sulfa-Michael addition reaction was applied for the two-step synthesis of o-carboranyl cysteine 1-HOOCCH(NH2)CH2S-1,2-C2B10H11 from the trimethylammonium salt of 1-mercapto-o-carborane and methyl 2-acetamidoacrylate.
Julia Laskova +5 more
doaj +1 more source
Novel Isoniazid-Carborane Hybrids Active In Vitro against Mycobacterium tuberculosis
Pharmaceuticals, 2020 Tuberculosis (TB) is a severe infectious disease with high mortality and morbidity. The emergence of drug-resistant TB has increased the challenge to eliminate this disease.
Daria Różycka +9 more
doaj +1 more source
Nitrogen-Doped Borane Cluster Network for High-Performance Supercapacitors Under Universal pH Conditions. [PDF]
ChemSusChemNitrogen‐doped borane cluster network was prepared as a porous electrode material, featuring 1–2 nm micropores and specific surface area up to 626 m2 g−1. It delivers outstanding supercapacitor performance, reaching 607 F g−1 in a three‐electrode configuration and 354 F g−1 in an asymmetric supercapacitor device.
Udnoor A +8 more
europepmc +2 more sources
Carborane-Based Three-Dimensional Covalent Organic Frameworks [PDF]
, 2023 The predesignable porous structure and high structural flexibility of covalent organic frameworks (COFs) render this material desirable as a platform for addressing various cutting-edge issues.
Xiaoyi Xu (811021) +3 more
core +1 more source
Radioiodination of Two Carborane-Based Dual Cyclooxygenase-2/5-Lipoxygenase Inhibitors and Their In Vitro and In Vivo Evaluation. [PDF]
ChembiochemTwo dicarbadodecaborane(12)‐based dual cyclooxygenase‐2/5‐lipoxygenase (COX‐2/5‐LO) inhibitors were 123I‐labeled. Refinement of labeling and formulation conditions and extensive in vitro characterization are presented. Cell uptake studies in COX‐2‐ and 5‐LO‐overexpressing cell lines showed COX‐2‐independent and partly 5‐LO‐dependent uptake.
Schädlich J +11 more
europepmc +2 more sources
Studies on Novel Functionalized Nido-¬Carborane Derivatives : Synthesis and Their Thermally Activated Delayed Fluorescence(TADF) Properties [PDF]
, 2021 The thesis entitled " Novel Functionalized Nido-¬Carborane Derivatives. Synthesis, Photophysical Properties, and its Potential Application in Thermally Activated Delayed Fluorescence (TADF) Emitters” presents the results obtained from the research work ...
쿠투마타라 수렌드란 수지트
core
1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene
Angewandte Chemie International Edition, EarlyView.A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic +4 more
wiley +1 more source