Results 41 to 50 of about 11,276 (152)

Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane) [PDF]

, 2015
Examples of singly-metallated derivatives of 1,1′-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1′-1′,2′-closo-C2B10H11)-7,8-nido-C2B9H10]2- with a {Ru(p-cymene)}2+ fragment affords both the ...
Ellis, David; id_orcid, Rosair, Georgina M., Welch, Alan J., Man, Wing Y., Palmero Palos, Cesar, McKay, David, Chan, Antony P. Y., Jourdan, Laure, Leube, Bernhard T, Palmero, Cesar, Macgregor, Stuart A., Leube, Bernhard T., Ellis, David, Thiripuranathar, Gobika, Chan, Antony P Y   +14 more
core   +1 more source

Coordination Ability of 10-EtC(NHPr)=HN-7,8-C₂B₉H₁₁ in the Reactions with Nickel(II) Phosphine Complexes

Crystals, 2021
The complexation reactions of nido-carboranyl amidine 10-PrNHC(Et)=HN-7,8-C2B9H11 with different nickel(II) phosphine complexes such as [(PR2R’)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph) were investigated.
Marina Yu. Stogniy, Svetlana A. Erokhina, Kyrill Yu. Suponitsky, Igor B. Sivaev, Vladimir I. Bregadze   +4 more
doaj   +1 more source

Deboronation-Induced Ratiometric Emission Variations of Terphenyl-Based Closo-o-Carboranyl Compounds: Applications to Fluoride-Sensing

Molecules, 2020
Closo-o-carboranyl compounds bearing the ortho-type perfectly distorted or planar terphenyl rings (closo-DT and closo-PT, respectively) and their nido-derivatives (nido-DT and nido-PT, respectively) were synthesized and fully characterized using ...
Hyunhee So, Min Sik Mun, Mingi Kim, Jea Ho Kim, Ji Hye Lee, Hyonseok Hwang, Duk Keun An, Kang Mun Lee   +7 more
doaj   +1 more source

Half-Sandwich Nickelacarboranes Derived from [7-(MeO(CH₂)₂S)-7,8-C₂B₉H₁₁]⁻

Inorganics, 2023
New carboranyl thioethers 1-MeO(CH2)nS-1,2-C2B10H11 (n = 2, 3) were prepared by the alkylation of the trimethylammonium salt of 1-mercapto-ortho-carborane with 1-bromo- 2-methoxyethane and 1-bromo-3-methoxypropane, respectively.
Dmitriy K. Semyonov, Marina Yu. Stogniy, Kyrill Yu. Suponitsky, Igor B. Sivaev   +3 more
doaj   +1 more source

“Free of Base” Sulfa-Michael Addition for Novel o-Carboranyl-DL-Cysteine Synthesis

Crystals, 2020
The sulfa-Michael addition reaction was applied for the two-step synthesis of o-carboranyl cysteine 1-HOOCCH(NH2)CH2S-1,2-C2B10H11 from the trimethylammonium salt of 1-mercapto-o-carborane and methyl 2-acetamidoacrylate.
Julia Laskova, Irina Kosenko, Ivan Ananyev, Marina Stogniy, Igor Sivaev, Vladimir Bregadze   +5 more
doaj   +1 more source

Novel Isoniazid-Carborane Hybrids Active In Vitro against Mycobacterium tuberculosis

Pharmaceuticals, 2020
Tuberculosis (TB) is a severe infectious disease with high mortality and morbidity. The emergence of drug-resistant TB has increased the challenge to eliminate this disease.
Daria Różycka, Małgorzata Korycka-Machała, Anna Żaczek, Jarosław Dziadek, Dorota Gurda, Marta Orlicka-Płocka, Eliza Wyszko, Katarzyna Biniek-Antosiak, Wojciech Rypniewski, Agnieszka B. Olejniczak   +9 more
doaj   +1 more source

Carborane-Based Three-Dimensional Covalent Organic Frameworks [PDF]

, 2023
The predesignable porous structure and high structural flexibility of covalent organic frameworks (COFs) render this material desirable as a platform for addressing various cutting-edge issues.
Xiaoyi Xu (811021), Hongzheng Chen (1649647), Qirui Cui (10155771), Ning Huang (623370)   +3 more
core   +1 more source

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, Volume 138, Issue 33, 10 August 2026.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +2 more sources

Studies on Novel Functionalized Nido-¬Carborane Derivatives : Synthesis and Their Thermally Activated Delayed Fluorescence(TADF) Properties [PDF]

, 2021
The thesis entitled " Novel Functionalized Nido-¬Carborane Derivatives. Synthesis, Photophysical Properties, and its Potential Application in Thermally Activated Delayed Fluorescence (TADF) Emitters” presents the results obtained from the research work ...
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