Results 31 to 40 of about 11,273 (151)

Synthesis and Delayed Fluorescent Properties of p-Nido-Carborane-Triarylborane Conjugates with a Methyl-Substituted Phenylene Linker [PDF]

, 2021
A series of p?nido?carborane?triarylborane conjugates (nido?1?3) in which a methyl group is introduced at the ortho?position to the carborane cage in the phenylene linker was prepared and characterized. All compounds exhibit broad low?energy absorptions (
쿠투마타라 수렌드란 수지트, 이민형   +1 more
core   +1 more source

Boron Neutron Capture Therapy at a Crossroads: Translational Gap and Emerging Delivery Agents. [PDF]

Chemistry
This review surveys recent advances in boron delivery agents for BNCT, emphasizing the shift from classical small molecules to multifunctional nanocarriers and theranostic systems. By integrating targeting, imaging, and therapy, next‐generation boron compounds aim to bridge the gap between (bio)chemical innovation and clinical translation.
Selg C, Hey-Hawkins E.
europepmc   +2 more sources

Emerging agents for boron neutron capture therapy: Biomolecular carriers paving the way for precision radiotherapy [PDF]

Precis Radiat Oncol
Boron neutron capture therapy (BNCT) requires key non‐negotiable technical criteria: megadose administration, precise tumor‐specific targeting, favorable biocompatibility, and sustained tumor retention. Overcoming these interconnected challenges fundamentally depends on biomolecular carriers, which are critical for translating the therapeutic potential
Chen C, Yang M, Wang J, Zhang L, Huang S, Xu X, Liu Y.   +6 more
europepmc   +2 more sources

New Aspects of Ruthenium-Mediated Polyhedral Contraction of Monocarbollides

Inorganics, 2022
It has been shown that the interaction of tris(triphenylphosphine)ruthenium dichloride RuCl2(PPh3)3 (1) with 10-vertex monocarborane [6-Ph-nido-6-CB9H11]−[Et4N]+ (2) under mild thermolysis conditions is not selective due to the undesired coordination of ...
Dmitry A. Loginov, Fedor M. Dolgushin, Vitalii E. Konoplev, Maxim V. Tachaev   +3 more
doaj   +1 more source

Palladium-Catalyzed Amination of 2-Iodo-para-carborane [PDF]

, 2007
The palladium-catalyzed Buchwald−Hartwig amination of B-iodocarborane by various azoles and amines is described for the first time. The reactions of 2-iodo-p-carborane with indole, imidazole, benzimidazole, or carbazole in the system Pd(dba)2−BINAP ...
Vladimir I. Bregadze (1978285), Kuanysh Z. Kabytaev (1616482), Pavel V. Petrovskii (1989103), Galina G. Zhigareva (2407459), Irina P. Beletskaya (1684774), Ivan V. Glukhov (2354689), Zoya A. Starikova (1701826)   +6 more
core   +7 more sources

Cyclic Voltammetry Study of Closo-Ruthenacarboranes

Physchem, 2023
Electrochemical properties of transition metal complexes are important parameters that should be considered for the successful application of these compounds in catalytic reactions.
Ivan D. Grishin, Anastasia M. Zimina, Alexander A. Kaltenberg   +2 more
doaj   +1 more source

Zwitterionic nido-Carborane-Fused Phospholes [PDF]

, 2019
Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key ...
Guanyu Tao (4788930), Francois Mathey (1450816), Zheng Duan (1450807)   +2 more
core   +1 more source

Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH₂NH(O)C(CH₂)_n-1,2-C₂B₁₀H₁₁)₂ (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)

Molecules, 2021
Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa, Aleksandra V. Arsent’eva, Sergey A. Anufriev, Alexei A. Anisimov, Kyrill Yu. Suponitsky, Oleg A. Filippov, Hiroyuki Nakamura, Igor B. Sivaev   +7 more
doaj   +1 more source

Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane) [PDF]

, 2015
Examples of singly-metallated derivatives of 1,1′-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1′-1′,2′-closo-C2B10H11)-7,8-nido-C2B9H10]2- with a {Ru(p-cymene)}2+ fragment affords both the ...
Ellis, David; id_orcid, Rosair, Georgina M., Welch, Alan J., Man, Wing Y., Palmero Palos, Cesar, McKay, David, Chan, Antony P. Y., Jourdan, Laure, Leube, Bernhard T, Palmero, Cesar, Macgregor, Stuart A., Leube, Bernhard T., Ellis, David, Thiripuranathar, Gobika, Chan, Antony P Y   +14 more
core   +1 more source

Coordination Ability of 10-EtC(NHPr)=HN-7,8-C₂B₉H₁₁ in the Reactions with Nickel(II) Phosphine Complexes

Crystals, 2021
The complexation reactions of nido-carboranyl amidine 10-PrNHC(Et)=HN-7,8-C2B9H11 with different nickel(II) phosphine complexes such as [(PR2R’)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph) were investigated.
Marina Yu. Stogniy, Svetlana A. Erokhina, Kyrill Yu. Suponitsky, Igor B. Sivaev, Vladimir I. Bregadze   +4 more
doaj   +1 more source