Results 31 to 40 of about 1,050 (206)

New Aspects of Ruthenium-Mediated Polyhedral Contraction of Monocarbollides

open access: yesInorganics, 2022
It has been shown that the interaction of tris(triphenylphosphine)ruthenium dichloride RuCl2(PPh3)3 (1) with 10-vertex monocarborane [6-Ph-nido-6-CB9H11]−[Et4N]+ (2) under mild thermolysis conditions is not selective due to the undesired coordination of ...
Dmitry A. Loginov   +3 more
doaj   +1 more source

Nitrogen-Doped Borane Cluster Network for High-Performance Supercapacitors Under Universal pH Conditions. [PDF]

open access: yesChemSusChem
Nitrogen‐doped borane cluster network was prepared as a porous electrode material, featuring 1–2 nm micropores and specific surface area up to 626 m2 g−1. It delivers outstanding supercapacitor performance, reaching 607 F g−1 in a three‐electrode configuration and 354 F g−1 in an asymmetric supercapacitor device.
Udnoor A   +8 more
europepmc   +2 more sources

Carborane: Dedicated to the Work of Professor Alan Welch [PDF]

open access: yes, 2022
This Special Issue on carboranes is dedicated to Prof. Alan Welch on the occasion of his retirement and his outstanding contributions to the field of carborane chemistry. Polyhedral carboranes lie at the interface of organic and inorganic chemistry. One

core   +1 more source

Cyclic Voltammetry Study of Closo-Ruthenacarboranes

open access: yesPhyschem, 2023
Electrochemical properties of transition metal complexes are important parameters that should be considered for the successful application of these compounds in catalytic reactions.
Ivan D. Grishin   +2 more
doaj   +1 more source

Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)

open access: yesMolecules, 2021
Bis(carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) were prepared by the reactions of the corresponding carboranyl acyl chlorides with ethylenediamine.
Yasunobu Asawa   +7 more
doaj   +1 more source

Radioiodination of Two Carborane-Based Dual Cyclooxygenase-2/5-Lipoxygenase Inhibitors and Their In Vitro and In Vivo Evaluation. [PDF]

open access: yesChembiochem
Two dicarbadodecaborane(12)‐based dual cyclooxygenase‐2/5‐lipoxygenase (COX‐2/5‐LO) inhibitors were 123I‐labeled. Refinement of labeling and formulation conditions and extensive in vitro characterization are presented. Cell uptake studies in COX‐2‐ and 5‐LO‐overexpressing cell lines showed COX‐2‐independent and partly 5‐LO‐dependent uptake.
Schädlich J   +11 more
europepmc   +2 more sources

Pharmacological development of target-specific delocalized lipophilic cation-functionalized carboranes for cancer therapy [PDF]

open access: yes, 2016
PURPOSE: Tumor cell heterogeneity and microenvironment represent major hindering factors in the clinical setting toward achieving the desired selectivity and specificity to malignant tissues for molecularly targeted cancer therapeutics. In this study,
A Kreso   +52 more
core   +1 more source

Coordination Ability of 10-EtC(NHPr)=HN-7,8-C2B9H11 in the Reactions with Nickel(II) Phosphine Complexes

open access: yesCrystals, 2021
The complexation reactions of nido-carboranyl amidine 10-PrNHC(Et)=HN-7,8-C2B9H11 with different nickel(II) phosphine complexes such as [(PR2R’)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph) were investigated.
Marina Yu. Stogniy   +4 more
doaj   +1 more source

Carborane confined nanoparticles for boron neutron capture therapy: Improved stability, blood circulation time and tumor accumulation [PDF]

open access: yes, 2011
Carborane confined nanoparticles based on the core cross-linked and boron-containing micelles (CL micelles) were prepared using the radical polymerization of poly(ethylene glycol)-block-poly(lactide) copolymer (PEG-b-PLA), which contained an acetal group
Nagasaki Yukio   +5 more
core   +1 more source

Deboronation-Induced Ratiometric Emission Variations of Terphenyl-Based Closo-o-Carboranyl Compounds: Applications to Fluoride-Sensing

open access: yesMolecules, 2020
Closo-o-carboranyl compounds bearing the ortho-type perfectly distorted or planar terphenyl rings (closo-DT and closo-PT, respectively) and their nido-derivatives (nido-DT and nido-PT, respectively) were synthesized and fully characterized using ...
Hyunhee So   +7 more
doaj   +1 more source

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