Results 51 to 60 of about 1,050 (206)
Metal Complexes Containing Boron Based Ligands [PDF]
, 2019 Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional.
Owen, Gareth
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The Far Side of Carboranes: Anticancer Active Monocations and Ambiently Stable Dications
Angewandte Chemie, Volume 138, Issue 20, 11 May 2026.This work describes the synthesis of bench‐stable dicationic carboranes. Their enhanced electrophilicity is documented by opening the clusters with weak nucleophiles or dihydrogen. The surprising stability of positively charged carboranes in water enabled a study of their in vitro antiproliferative activity, which surpassed the effects of doxorubicin ...
Vlastimil Němec +10 more
wiley +2 more sources
Synthesis, biological and photophysical studies of novel compounds for cancer therapy [PDF]
, 2011 Cancer remains the second most common cause of death in the United States. It is therefore imperative that a lot of effort be put into finding a cure for this dreadful disease that shows no discrimination, and virtually anybody is at risk of developing ...
Amuhaya, Edith Khavwajira
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Syntheses and biological evaluation of water soluble carboranylporphyrins for application in boron neutron capture therapy [PDF]
, 2006 The goal of the research presented in this dissertation is to develop novel water soluble carboranylporphyrins that can deliver therapeutic dosage of boron specifically to tumors for application in boron neutron capture therapy.
Gottumukkala, Vijay
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Medicinal Chemistry of Boron-Bearing Compounds for BNCT- Glioma Treatment: Current Challenges and Perspectives [PDF]
, 2018 Since its first description, boron neutron capture therapy (BNCT) was a special type of radiotherapy for treatment of cancer and with focus mainly on glioma therapeutic.
Cerecetto, Hugo, Couto, Marcos
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Angewandte Chemie International Edition, EarlyView.A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi +9 more
wiley +1 more source
Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms [PDF]
, 2021 Monatomic zero-valent silicon and germanium complexes (silylones and germylones), stabilised by neutral donating ligands, emerged only recently as a new class of low-valent group 14 element compounds.
Drieß, Matthias +3 more
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Bulletin of the Korean Chemical Society, EarlyView.Structure‐oriented design of NHC‐based tetradentate Pt(II) complexes offers narrowband deep‐blue emission for OLEDs. This review highlights how steric shielding and electronic modulation regulate intermolecular interactions, excited‐state dynamics, and device performance, outlining design principles and outlines toward efficient and durable blue ...
Mingi Kim, Chan Hee Ryu, Kang Mun Lee
wiley +1 more source
Trigonal Phosphine Umpolung: Electrophilicity Driven by a Redox‐Active Boron Cluster
Chemistry – A European Journal, EarlyView.Coupling of a phosphine to a redox‐active cluster enables polarity reversal, or umpolung, at phosphorus. Phosphines are classically known for their nucleophilicity, and while electrophilic reactivity has been observed in geometrically constrained, non‐trigonal systems, similar behavior in ordinary trigonal phosphines is rare.
Bryce C. Nussbaum +2 more
wiley +1 more source
NITRILIUM DERIVATES OF NIDO-CARBORANE IN SYNTHESIS OF TRANSITIONAL METAL COMPLEXES [PDF]
, 2023 This work was supported by Russian Science Foundation, project № 21-73 ...
Anufriev, S. A. +3 more
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