Results 51 to 60 of about 11,276 (152)

Carba‐closo‐dodecaborates as Superchaotropic Anions

Chemistry – A European Journal, EarlyView.
The singly charged boron cluster anion CB11H12– forms strong inclusion complexes with cyclodextrins, interacts strongly with nonionic polymers, and serves as an effective transmembrane carrier, positioning itself as the smallest superchaotropic anion known to date. .
Andrea Barba‐Bon, Guillermo E. Quintero, Maryam Ashjari, Ivana Nikšić‐Franjić, Kai‐Jen Tsung, Xiaojuan Wang, Margarita E. Aliaga, Bohumir Grüner, Werner M. Nau   +8 more
wiley   +1 more source

Exploring the Boundaries of Aromaticity in Complex Structures and Excited States Through Computational Analysis

Chemistry – A European Journal, EarlyView.
Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola, Miquel Solà, Albert Poater   +2 more
wiley   +1 more source

Carborane Guests for Cucurbit[7]uril Facilitate Strong Binding and on Demand Removal [PDF]

, 2020
High affinity guest have been reported for the macrocyclic host cucurbit[7]uril (CB[7]), enabling widespread applications, but preventing CB[7] materials from being returned to their guest-free state for reuse.
Anna, Kataki-Anastasakou, Alexander, Spokoyny, Arnold L., Rheingold, Gary J., Balaich, Selena, Hernandez, Jonathan C., Axtell, RafalM., Dziedzic, Ellen, Sletten   +7 more
core   +1 more source

Two New closo- or nido-Carborane Diphosphine Complexes: Synthesis, Characterization and Crystal Structures [PDF]

Bulletin of the Korean Chemical Society, 2011
Two new carborane complexes containing closo- or nido-carborane diphosphine ligands with the formula: complex (1) and (2) have been synthesized and characterized by elemental analysis, 1H and 13C NMR spectroscopy and X-ray structure determination. The X-ray structure analyses revealed that the carborane diphosphine ligand was degraded from closo-1,2 ...
Lingqian Kong, Daopeng Zhang, Fangfang Su, Dacheng Li, Jianmin Dou   +4 more
openaire   +1 more source

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane [PDF]

, 2020
The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the ...
Pisareva I.V., Lazareva A.I., Smolyakov A.F., Godovikov I.A., Chizhevsky I.T., Balagurova E.V., Dolgushin F.M.   +6 more
core   +3 more sources

Trigonal Phosphine Umpolung: Electrophilicity Driven by a Redox‐Active Boron Cluster

Chemistry – A European Journal, Volume 32, Issue 27, 17 July 2026.
Coupling of a phosphine to a redox‐active cluster enables polarity reversal, or umpolung, at phosphorus. Phosphines are classically known for their nucleophilicity, and while electrophilic reactivity has been observed in geometrically constrained, non‐trigonal systems, similar behavior in ordinary trigonal phosphines is rare.
Bryce C. Nussbaum, Mark D. Smith, Dmitry V. Peryshkov   +2 more
wiley   +1 more source

Organocatalytic B–H Functionalization of Carboranes via Photo‐Induced Hydrogen Atom Transfer

ChemistryEurope, Volume 4, Issue 7, July 2026.
Visible‐light organocatalytic hydrogen atom transfer enables direct carborane B─H bond functionalization. A photocatalytically generated cationic aminium radical selectively abstracts hydrogen from hydridic boron sites, forming boron‐centered radicals that couple with activated olefins or imines to deliver B‐functionalized carboranes under mild ...
Takaya Sakaue, Kana Yasuda, Tsukasa Tawatari, Akira Matsumoto, Keiichi Hirano, Kiyosei Takasu, Hiroshi Takikawa   +6 more
wiley   +1 more source

The Synthesis and Characterization of Carborane and Metallocarborane-Carbohydrate Conjugates [PDF]

, 2008
This thesis describes the synthesis and characterization of a series of carborane and metallocarborane-carbohydrate conjugates as model systems for developing a novel class of radiophannaceuticals.
Green, Andrew
core  

Palladium-Catalyzed Heck Reactions of Styrene Derivatives and 2-Iodo-p-carborane [PDF]

, 2016
p-Carborane has been vinylated on the 2-B-atom in high yields using the Heck reaction. Thus, the reaction between 2-iodo-p-carborane and various styrenes [4-H-, 4-C6H4-, 4-Cl-, 4-Br-, 4-NO2-, 4-CH3O-, and 4-CH3-] resulted in the production of the ...
Rodrigo Tascon Claro (3033471), Stefan Sjöberg (2978637), Ludvig Eriksson (3033477), Karl Johan Winberg (3033474)   +3 more
core   +1 more source

Stable exo-nido-Metallacarboranes (M = Os^IV) that Incorporate meta-Carborane-Based Dicarbollide Ligands [PDF]

, 2016
Reactions of the [K]+ salts of the [nido-7,9-C2B9H12]- anion (2) and its C-phenylated derivative [7-Ph-nido-7,9-C2B9H11]- (4) with [OsCl2(PPh3)3] (3) proceed in benzene at ambient temperature with the formation of 16-electron chlorohydrido-Os(IV) exo ...
Alexander I. Yanovsky (2499058), Galina D. Kolomnikova (2499055), Oleg L. Tok (2499052), Elena V. Balagurova (2499049), Fedor M. Dolgushin (1612729), Dmitri N. Cheredilin (2499046), Igor T. Chizhevsky (2046805)   +6 more
core   +5 more sources