Results 11 to 20 of about 4,674 (215)

Charge-Compensated Derivatives of Nido-Carborane

open access: yesInorganics, 2023
This review summarizes data on the main types of charge-compensated nido-carborane derivatives. Compared with organic analogs, onium derivatives of nido-carborane have increased stability due to the stabilizing electron-donor action of the boron cage ...
Marina Yu Stogniy   +2 more
exaly   +4 more sources

Carborane photochromism: a fatigue resistant carborane switch

open access: yesChemical Communications, 2021
A dithienylethene molecule involving carborane clusters shows remarkable fatigue resistance and high contrast visual colour changes when irradiated with alternating ultraviolet and visible light.
Chong Li   +6 more
openaire   +7 more sources

Synthesis and Anti-Tumor Evaluation of Carboranyl BMS-202 Analogues—A Case of Carborane Not as Phenyl Ring Mimetic [PDF]

open access: yesMolecules
Carborane is considered a three-dimensional mimetic of phenyl rings in medicinal chemistry. BMS-202 is a potent PD-L1 inhibitor that can block the PD-L1/PD-1 interaction and restore the immune response to cancer cells.
Changxian Yuan   +14 more
doaj   +2 more sources

Carborane Nanomembranes [PDF]

open access: yesACS Nano
We report on the fabrication of a boron-based two-dimensional (2D) material via electron irradiation-induced cross-linking of carborane self-assembled monolayers (SAMs) on crystalline silver substrates. The SAMs of 1,2-dicarba-closo-dodecarborane-9,12-dithiol (O9,12) were prepared on flat crystalline silver substrates and irradiated with low-energy ...
Martha Frey   +8 more
openaire   +4 more sources

Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine

open access: yesMolecules, 2017
The enhancement of aggregation-induced emission (AIE) is presented on the basis of the strategy for improving solid-state luminescence by employing multiple o-carborane substituents.
Kenta Nishino   +2 more
exaly   +3 more sources

Synthesis of B-Substituted Anthracenyl and Pyrenyl Derivatives of ortho-Carborane

open access: yesInorganics
Isomeric B-substituted anthracenyl and pyrenyl derivatives of ortho-carborane containing polycyclic aromatic substituents both in the position of the carborane cage most distant from the carbon atoms (position 9) and in the neighboring position (position
Akim V. Shmal’ko   +5 more
doaj   +2 more sources

Carborane-Containing Iron Oxide@Gold Nanoparticles for Potential Application in Neutron Capture Therapy [PDF]

open access: yesNanomaterials
Cancer remains one of the most pressing global health challenges, driving the need for innovative treatment strategies. Boron neutron capture therapy (BNCT) offers a highly selective approach to destroying cancer cells while sparing healthy tissues.
Zhangali A. Bekbol   +8 more
doaj   +2 more sources

Pd-Catalysed synthesis of carborane sulfides from carborane thiols

open access: yesChemical Communications
Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects.
Natsuki Minematsu   +2 more
openaire   +4 more sources

Carboranes as unique pharmacophores in antitumor medicinal chemistry

open access: yesMolecular Therapy: Oncolytics, 2022
Carborane is a carbon-boron molecular cluster that can be viewed as a 3D analog of benzene. It features special physical and chemical properties, and thus has the potential to serve as a new type of pharmacophore for drug design and discovery.
Yu Chen   +10 more
doaj   +1 more source

Synthesis, Crystal Structure, and Some Transformations of 9,12-Dichloro-ortho-Carborane

open access: yesCrystals, 2022
Reaction of ortho-carborane with anhydrous AlCl3 in chloroform results in a mixture of 9-chloro, 9,12-dichloro, and 8,9,12-trichloro derivatives with 9,12-dichloro-ortho-carborane being the main product. Molecular crystal structure of 9,12-dichloro-ortho-
Sergey A. Anufriev   +4 more
doaj   +1 more source

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