Results 11 to 20 of about 7,978 (176)

Bis(silylene)-Mediated N═N Bond Scission of Diazo Compounds. [PDF]

Angew Chem Int Ed Engl
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Xiong Y, Yao S, Driess M.
europepmc   +3 more sources

Preparation and Characterization of Carborane Modified Liquid Fluoroelastomers and the investigation of their properties

Designed Monomers and Polymers, 2021
The preparation of liquid fluoroelastomers that are liquid with excellent mechanical properties remains a challenge. Here, we show a very straightforward method to produce liquid fluoroelastomers by introducing carborane.
Juan Li
doaj   +1 more source

Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)

Chemistry, 2023
This review is an attempt to bring together the data from the literature on the synthesis and properties of icosahedral carborane derivatives, in which exo-polyhedral three- and four-coordinated boron substituents are attached directly to the carborane ...
Igor B. Sivaev
doaj   +1 more source

Novel Self-Forming Nanosized DDS Particles for BNCT: Utilizing A Hydrophobic Boron Cluster and Its Molecular Glue Effect

Cells, 2022
BNCT is a non-invasive cancer therapy that allows for cancer cell death without harming adjacent cells. However, the application is limited, owing to the challenges of working with clinically approved boron (B) compounds and drug delivery systems (DDS ...
Abdul Basith Fithroni, Kazuko Kobayashi, Hirotaka Uji, Manabu Ishimoto, Masaru Akehi, Takashi Ohtsuki, Eiji Matsuura   +6 more
doaj   +1 more source

Tuning the Liquid Crystallinity of Cholesteryl-o-Carborane Dyads: Synthesis, Structure, Photoluminescence, and Mesomorphic Properties

Crystals, 2021
A set of mesomorphic materials in which the o-carborane cluster is covalently bonded to a cholesteryl benzoate moiety (mesogen group) through a suitably designed linker is described.
Albert Ferrer-Ugalde, Arántzazu González-Campo, José Giner Planas, Clara Viñas, Francesc Teixidor, Isabel M. Sáez, Rosario Núñez   +6 more
doaj   +1 more source

Molecular dynamics simulations of ortho-carborane nano-diamond storage within the nonpolar channel cavities of a right-handed coiled-coil tetrabrachion nanotube

Computational and Structural Biotechnology Journal, 2021
Molecular dynamics simulations have been performed on a complex in which clusters of boron in the form of molecules of the nanodiamond ortho-carborane (C2B10H12) have been inserted into the four large nonpolar cavities of a nanotube of the right-handed ...
C. Harder-Viddal, F. Heide, R.M. Roshko, J. Stetefeld   +3 more
doaj   +1 more source

1,2-Diphenyl-o-carborane and Its Chromium Derivatives: Synthesis, Characterization, X-ray Structural Studies, and Biological Evaluations

Molecules, 2023
The objective of this study is to design and synthesize substituted η6-chromium(0) tricarbonyl metal complexes carrying o-carborane units as potential boron neutron capture therapy (BNCT) agents.
Tae-Jin Ha, Dong-Kyung Im, Seung-Min Kim, Jong-Dae Lee   +3 more
doaj   +1 more source

Ultra-thin 3D silicon sensors for neutron detection [PDF]

, 2012
We present a novel neutron detector based on an ultra-thin 3D silicon sensor with a sensitive volume only 10 µm thick. This ultra-thin active volume allows a high gamma-ray rejection, a key requirement in order to discriminate the signal coming from the ...
Fleta, Celeste, Garcia, Francisco, Guardiola, Consuelo, Lozano, Manuel, Pellegrini, Giulio, Quirion, David, Rodriguez, Joaquin   +6 more
core   +1 more source

Homocoupling of CO and isocyanide mediated by a C,C′-bis(silylenyl)-substituted ortho-carborane [PDF]

, 2019
The unexpected reactivity of the o-carborane supported bis-silylene [(LSi:)C]2B10H101 {L= PhC(tBuN)2} towards carbon monoxide and 2,6-dimethylphenyl isocyanide is reported.
Drieß, Matthias, Ruzicka, Ales, Szilvási, Tibor, Xiong, Yun, Yao, Shenglai   +4 more
core   +1 more source

Carborane-containing copolyester fibers with unique neutron shielding properties

Materials & Design, 2019
Two series of carborane-containing copolyesters were prepared by copolymerization of the newly designed 5-(1-methoxy-o-carborane)dimethyl isophthalate (BDMI) and conventional polyester monomers.
Yuane Wu, Jianjing Hu, Chen Feng, Gong Chen, Jiping Yang   +4 more
doaj   +1 more source