Results 41 to 50 of about 1,700 (179)

Exploring the Boundaries of Aromaticity in Complex Structures and Excited States Through Computational Analysis

Chemistry – A European Journal, EarlyView.
Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola, Miquel Solà, Albert Poater   +2 more
wiley   +1 more source

Organocatalytic B–H Functionalization of Carboranes via Photo‐Induced Hydrogen Atom Transfer

ChemistryEurope
Boron‐centered radicals of the parent icosahedral carborane (C2B10H12) have become increasingly accessible from prefunctionalized carborane derivatives.
Takaya Sakaue, Kana Yasuda, Tsukasa Tawatari, Akira Matsumoto, Keiichi Hirano, Kiyosei Takasu, Hiroshi Takikawa   +6 more
doaj   +1 more source

Carborane-based BODIPY dyes: synthesis, structural analysis, photophysics and applications

Frontiers in Chemistry
Icosahedral boron clusters-based BODIPY dyes represent a cutting-edge class of compounds that merge the unique properties of boron clusters with the exceptional fluorescence characteristics of BODIPY dyes.
Javier Ordóñez-Hernández, José Giner Planas, Rosario Núñez   +2 more
doaj   +1 more source

Hydride Materials for Advanced Electrochemical Energy Storage: Progress and Perspectives

EcoEnergy, EarlyView.
Hydrides are emerging as functional materials for low‐carbon electrochemical energy storage. Complex hydrides provide polyanionic electrolyte frameworks for all‐solid‐state, Li–S, and multivalent batteries; hydride ion conductors enable H− transport for emerging hydride‐based cells; and metal hydrides offer established electrode chemistries for Ni–MH ...
Taehyun Kim, Taegyoung Lee, Huijeong Oh, Shin‐ichi Orimo, Sangryun Kim   +4 more
wiley   +1 more source

o‐Carborane‐based multi‐resonance thermally activated delayed fluorescence emitter exhibits highly efficient and multifunctional electroluminescence

FlexMat, EarlyView.
By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang, Denghui Liu, Mengke Li, Tong Wang, Yuanyuan Meng, Deli Li, Shi‐Jian Su, Wei Li, Ziyi Ge   +8 more
wiley   +1 more source

Recent Advances in Carborane-Based Crystalline Porous Materials

Molecules
The field of carborane research has witnessed continuous development, leading to the construction and development of a diverse range of crystalline porous materials for various applications. Moreover, innovative synthetic approaches are expanding in this
Yuxuan Meng, Xi Lin, Jinyi Huang, Liangliang Zhang   +3 more
doaj   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

Mass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

Ball-Type Dioxy-o-Carborane Bridged Cobaltphthalocyanine: Synthesis, Characterization and DFT Studies For Dye-Sensitized Solar Cells as Photosensitizer

Heterocyclic Communications, 2020
The synthesis and spectroscopic characterization of an innovative ball-type cobalt metallophthalocyanine 4, bridged by four 1,2-bis(2-hydroxymethyl)-O-carborane (HMOC) 1 units, has been achieved.
Şener Sevil
doaj   +1 more source

Synergistic Action of Ascorbic Acid and Readily Accessible NHC^N Ligands for the Oxidation of Gold(I) With Electron‐Rich Aryldiazonium Salts

Chemistry – A European Journal, Volume 32, Issue 35, 19 September 2026.
The synergic action of ascorbic acid and NHC^N ligands enables Au(I) oxidation with electron‐rich aryldiazonium salts. ABSTRACT The synergistic action of ascorbic acid and NHC^N ligands enables the challenging oxidation of Au(I) with electron‐rich aryldiazonium salts in the absence of a cocatalyst and/or irradiation. EPR, NMR, and x‐ray analyses reveal
Paula G. Cárdenas‐Cárdenas, Diego Dusso, Saúl Soto‐Zúñiga, Osvaldo F. López‐Saladino, Simón Hernández‐Ortega, Rubén A. Toscano, Virginia Gómez‐Vidales, Susana Porcel‐García   +7 more
wiley   +1 more source

Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid

Molecules
Amino acids with unusual types of chirality and their derivatives have recently attracted attention as precursors in the synthesis of chiral catalysts and peptide analogues with unique properties.
Dmitry A. Gruzdev, Angelina A. Telegina, Marina A. Ezhikova, Mikhail I. Kodess, Galina L. Levit, Victor P. Krasnov   +5 more
doaj   +1 more source