Results 41 to 50 of about 4,674 (215)

Carborane-Containing Liquid Crystals:  Synthesis and Structural, Conformational, Thermal, and Spectroscopic Characterization of Diheptyl and Diheptynyl Derivatives of p-Carboranes

open access: yes, 2016
Molecular and electronic structures for four p-carborane derivatives were studied in the context of their liquid crystalline properties. Thus molecular and crystal structures of diheptyl and diheptynyl derivatives of 10- and 12-vertex bi-p-carboranes ...
Victor G. Young (1405513)   +3 more
core   +2 more sources

Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane)

open access: yes, 2015
Examples of singly-metallated derivatives of 1,1′-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1′-1′,2′-closo-C2B10H11)-7,8-nido-C2B9H10]2- with a {Ru(p-cymene)}2+ fragment affords both the ...
Ellis, David; id_orcid   +14 more
core   +1 more source

Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane

open access: yesMolbank, 2022
Synthesis, NMR spectral data and crystal structure of 9,12-dibromo derivative of ortho-carborane are reported.
Olga B. Zhidkova   +5 more
doaj   +1 more source

Crystal structure of 1-butyl-2,3-dimethylimidazolium dicarba-7,8-nido-undecaborate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title molecular salt, C9H17N2+·C2H12B9−, the carborane cage has a bridging B—H—B bond on the open B3C2 face. The butyl side chain of the cation adopts an extended conformation [C—C—C—C = 179.6 (1)°].
M. J. Klemes   +3 more
doaj   +1 more source

Zwitterionic nido-Carborane-Fused Phospholes

open access: yes, 2019
Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key ...
Guanyu Tao (4788930)   +2 more
core   +1 more source

Carborane-Based Lewis Base Catalysts for Aromatic Halogenation

open access: yes, 2023
Haloarenes have been an important class of chemicals in modern organic chemistry field because the halide functionality offers numerous possible transformations.
Shotaro, Nakamura   +5 more
core   +1 more source

Boosting Circularly Polarized Luminescence of Organic Conjugated Systems via Twisted Intramolecular Charge Transfer

open access: yesResearch, 2020
Realizing a high luminescence dissymmetry factor (glum) is a paramount yet challenging issue in the research field of circularly polarized luminescence (CPL).
Junfeng Li   +7 more
doaj   +1 more source

Boron‐10 carriers and their applications in boron neutron capture therapy [PDF]

open access: yesPrecis Radiat Oncol
Summary of different types of boron drugs. Abstract Boron neutron capture therapy (BNCT) has emerged as a promising therapeutic modality in cancer treatment, demonstrating the ability to selectively eliminate cancer cells through the 10B(n,α)7Li nuclear reaction with minimal side effects on normal tissues.
Tang D   +7 more
europepmc   +2 more sources

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands

open access: yes, 2016
We report the development of a new class of phosphorescent zwitterionic bis(heteroleptic) Ir­(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl substituents.
Peter I. Djurovich (1494643)   +8 more
core   +2 more sources

Palladium-Catalyzed Heck Reactions of Styrene Derivatives and 2-Iodo-p-carborane

open access: yes, 2016
p-Carborane has been vinylated on the 2-B-atom in high yields using the Heck reaction. Thus, the reaction between 2-iodo-p-carborane and various styrenes [4-H-, 4-C6H4-, 4-Cl-, 4-Br-, 4-NO2-, 4-CH3O-, and 4-CH3-] resulted in the production of the ...
Rodrigo Tascon Claro (3033471)   +3 more
core   +1 more source

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