Results 51 to 60 of about 4,682 (219)
Metal‐anode batteries using Li, Na, Mg, and Ca offer exceptionally high energy density, but dendrites, unstable interphases, cracking, and pore formation hinder durability and safety. This review shows how careful electrolyte and interphase design can stabilize these reactive metals.
Jian Pan +3 more
wiley +1 more source
Unraveling aromaticity: the dual worlds of pyrazole, pyrazoline, and 3D carborane
A new series of o-carborane-fused pyrazoles has been recently successfully synthesized. This fusion was expected to create a hybrid 3D/2D aromatic system, combining the 3D aromaticity of o-carborane with the 2D aromaticity of pyrazole. However, while the
Zahra Noori +4 more
doaj +1 more source
The dynamic disulfide bonds facilitated the development of high‐performance aerospace ablation‐resistant materials. At moderate temperature, the dissociation and recombination of disulfide bonds ensured excellent processability, mechanical properties, and recycling ability of phenolic resin; at high temperature, cleavage of disulfide bonds produced ...
Yu Li +9 more
wiley +1 more source
Icosahedral symmetry super-carborane and beyond [PDF]
© 2014 Elsevier B.V. All rights reserved. Nano-structures are often sought to be constructed from some especially stable multifunctional unit which can be manipulated into different desired forms.
Griffin, L.L. +5 more
core +1 more source
1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic +4 more
wiley +2 more sources
Preparation and Evaluation of Carborane Analogues of Tamoxifen [PDF]
A stereoselective synthesis of closo carborane analogues of tamoxifen was developed where the products represent a new approach to developing metabolically robust SERMs.
Jennifer Lemon (2248609) +2 more
core +5 more sources
The emergence of antibiotic resistance in opportunistic pathogens represents a huge problem, the solution for which may be a treatment with a combination of multiple antimicrobial agents.
Eva Vaňková +7 more
doaj +1 more source
Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands [PDF]
We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(o-carborane) (bc). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex ...
Alexander, Spokoyny +5 more
core +1 more source
In this study, we investigated a novel anti-cancer drug design approach by revisiting diclofenac-based carborane-substituted prodrugs. The redesigned compounds combine the robust carborane scaffold with the oxindole framework, resulting in four carborane-
Christoph Selg +13 more
doaj +1 more source
Fluorescent carborane-vinylstilbene functionalised octasilsesquioxanes: Synthesis, structural, thermal and photophysical properties [PDF]
A new set of four different fluorescent boron-rich hybrids based on an octasilsesquioxane core (T8) are presented herein. The syntheses have been carried out starting from styrene-containing ortho- and meta-carboranes and an adequately substituted ...
Cabrera González, Justo Enrique
core +1 more source

