Results 41 to 50 of about 47,782 (256)

Hydroboration-Oxidation of (±)-(1α,3α,3aβ,6aβ) -1,2,3,3a,4,6a-Hexahydro-1,3-pentalenedimethanol and Its O-Protected Derivatives: Synthesis of New Compounds Useful for Obtaining (iso)Carbacyclin Analogues and X-ray Analysis of the Products

Molecules, 2017
Hydroboration-oxidation of 2α,4α-dimethanol-1β,5β-bicyclo[3.3.0]oct-6-en dibenzoate (1) gave alcohols 2 (symmetric) and 3 (unsymmetric) in ~60% yield, together with the monobenzoate diol 4a (37%), resulting from the reduction of the closer benzoate by ...
Constantin I. Tănase, Florea G. Cocu, Miron Teodor Căproiu, Constantin Drăghici, Sergiu Shova   +4 more
doaj   +1 more source

Nanostructured Carbon-Doped BN for CO₂ Capture Applications

Nanomaterials, 2023
Carbon-doped boron nitride (denoted by BN/C) was prepared through the pyrolysis at 1100 °C of a nanostructured mixture of an alkyl amine borane adduct and ammonia borane. The alkyl amine borane adduct acts as a soft template to obtain nanospheres.
Rimeh Mighri, Kevin Turani-I-Belloto, Umit B. Demirci, Johan G. Alauzun   +3 more
doaj   +1 more source

The effect of the amido substituent on polymer molecular weight in propene homopolymerisation by titanium cyclopentadienyl-amide catalysts [PDF]

, 2000
In the homopolymerisation of propene by the cyclopentadienyl-amide titanium catalyst systems [η5,η1-C5H4(CH2)2NR]TiCl2/MAO and [η5,η1-C5H4(CH2)2NR]Ti(CH2Ph)2/B(C6F5)3 (R = tBu, iPr, Me), the catalyst with the smallest substituent (Me) on the amido moiety
Hessen, Bart,, Sinnema, Piet-Jan,, Teuben, Jan H.,   +2 more
core   +1 more source

Spontaneous dehydrocoupling in peri-substituted phosphine-borane adducts [PDF]

, 2016
This work was financially supported by the EPSRC and COST action CM1302 SIPs.Bis(borane) adducts Acenap(PiPr2·BH3)(PRH·BH3) (Acenap = acenaphthene-5,6-diyl; 4a, R = Ph; 4b, R = ferrocenyl, Fc; 4c, R = H) were synthesised by the reaction of excess H3B ...
Cordes, David Bradford, Kilian, Petr, Ray, Matthew James, Slawin, Alexandra Martha Zoya, Surgenor, Brian Andrew, Taylor, Laurence John, Wawrzyniak, Piotr   +6 more
core   +2 more sources

In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen

Nanomaterials, 2018
The development of highly-efficient heterogeneous supported catalysts for catalytic hydrolysis of ammonia borane to yield hydrogen is of significant importance considering the versatile usages of hydrogen.
Qi Wang, Caili Xu, Mei Ming, Yingchun Yang, Bin Xu, Yi Wang, Yun Zhang, Jie Wu, Guangyin Fan   +8 more
doaj   +1 more source

Hydrazine Borane and Hydrazinidoboranes as Chemical Hydrogen Storage Materials

Energies, 2015
Hydrazine borane N2H4BH3 and alkali derivatives (i.e., lithium, sodium and potassium hydrazinidoboranes MN2H3BH3 with M = Li, Na and K) have been considered as potential chemical hydrogen storage materials.
Romain Moury, Umit B. Demirci
doaj   +1 more source

Chiral Aminoalcohols and Squaric Acid Amides as Ligands for Asymmetric Borane Reduction of Ketones: Insight to In Situ Formed Catalytic System by DOSY and Multinuclear NMR Experiments

Molecules, 2021
A series of squaric acid amides (synthesized in 66–99% isolated yields) and a set of chiral aminoalcohols were comparatively studied as ligands in a model reaction of reduction of α-chloroacetophenone with BH3•SMe2.
Yana Nikolova, Georgi M. Dobrikov, Zhanina Petkova, Pavletta Shestakova   +3 more
doaj   +1 more source

(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. [PDF]

, 2017
Although BH3 simply coordinates the endocyclic P of (phospholidino)phosphaketene 1Dipp , the bulkier B(C6F5)3 gives rise to a zwitterionic diphosphirenium, which is a novel type of 2π-electron aromatic system as shown by the calculated NICS values. While
Bertrand, Guy, Hansmann, Max M, Jazzar, Rodolphe, Liu, Liu Leo, Ruiz, David A   +4 more
core   +2 more sources

Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B₁₂H₁₁NH₃]⁻

Molecules, 2018
The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications.
Yuanbin Zhang, Yuji Sun, Tao Wang, Jiyong Liu, Bernhard Spingler, Simon Duttwyler   +5 more
doaj   +1 more source

Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane

Catalysis Communications, 2021
The development of highly active and stable catalysts is desirable for hydrogen generation from ammonia borane (AB). In this study, Ni0.25Co0.75O nanowire array supported on Cu@CuO foam (Ni0.25Co0.75O/Cu@CuO) has been successfully fabricated.
Yufa Feng, Fei Lv, Huize Wang, Xiaodong Chen, Hang Li, Zhiyu Chen, Guangyu Lin, Jinyun Liao, Mingyang He, Quanbing Liu   +9 more
doaj   +1 more source