Results 61 to 70 of about 16,148 (267)

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +2 more sources

Practical Enantioselective Reduction of Ketones Using Oxazaborolidine Catalysts Generated In Situ from Chiral Lactam Alcohols

Molecules, 2018
Oxazaborolidine catalyst (CBS catalyst) has been extensively used for catalytic borane reduction with a predictable absolute stereochemistry and high enantioselectivity.
Yasuhiro Kawanami, Ryo C. Yanagita
doaj   +1 more source

Phosphido-borane-supported stannates [PDF]

, 2022
\ua9 2023 The Royal Society of Chemistry. The reactions between SnCl2 and three equivalents of the alkali metal phosphido-borane complexes [R2P(BH3)]M yield the corresponding tris(phosphido-borane)stannate complexes [LnM{R2P(BH3)}3Sn] [R2 = iPr2, LnM ...
Craig A, Waddell PG, Izod K, Madlool AM
core  

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

Advanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang, Avirup Sardar, Weijie Ji, Zhongyu Liu, Rongchao Jin   +4 more
wiley   +1 more source

Copper(II/III) Redox Couple Enables C─H Methylation via a Radical Mechanism Analogous to SAM Enzymes

Angewandte Chemie, EarlyView.
Biological C–H methylation proceeds through radical pathways mediated by one‐electron redox cofactors, yet no synthetic model has reproduced this reactivity. Here, we report the first isolable Cu(II/III)–methyl complexes that mediate C–H methylation through hydrogen atom transfer and methyl radical rebound.
Emily N. Doss, Curtis E. Moore, Shiyu Zhang   +2 more
wiley   +2 more sources

Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B₁₂H₁₁NH₃]⁻

Molecules, 2018
The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications.
Yuanbin Zhang, Yuji Sun, Tao Wang, Jiyong Liu, Bernhard Spingler, Simon Duttwyler   +5 more
doaj   +1 more source

Zeolite framework stabilized rhodium(0) nanoclusters catalyst for the hydrolysis of ammonia-borane in air: Outstanding catalytic activity, reusability and lifetime

, 2009
Zeolite framework stabilized rhodium(0) nanoclusters; were prepared by a two steps procedure: incorporation of Rh3+ ions into the Zeolite-Y by ion-exchange followed by in situ reduction of Rh3+ ions during the catalytic hydrolysis of ammonia-borane. They
Özkar, Saim, Zahmakiran, Mehmet
core   +1 more source

‐butylphenylphosphido‐borane: A kinetic insight

, 2022
International audienceThe racemization mechanism of tert-butyl-phenylphosphido-borane is investigated experimentally andtheoretically. Based on this converging approach, it is shown,first, that several phosphido-borane molecular speciescoexist at the ...
Giordano, Laurent, Jean‐Valère Naubron, Béal, Aurélie, Gatineau, David, Rémy Fortrie, Hérault, Damien, Laurent Giordano, Gérard Buono, Naubron, Jean‐valère, Damien Hérault, Aurélie Béal, Buono, Gérard, Fortrie, Rémy, David Gatineau   +13 more
core   +1 more source

Ultrathin Li Metal Anodes: Quantitative Design Principles and Manufacturability Across Liquid and Solid‐State Batteries

Advanced Materials, EarlyView.
Ultrathin lithium metal anodes (≤15 µm) offer a promising route to high‐energy‐density batteries due to their high capacity and low potential. This review presents design principles for ultrathin Li, evaluates fabrication strategies, and discusses challenges in liquid and solid‐state cells.
Cheng Wang, Caoyu Wang, Shuixin Xia, Jodie A. Yuwono, Mingnan Li, Yanqiu Lyu, Ruizhi Zhang, Jun Wang, Jianfeng Mao, Zaiping Guo   +9 more
wiley   +1 more source

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

Angewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai, Yalei Zhang, Yue Zhao, Shujun Li, Nana Ma, Qingchun Xia, Yiwei Liu, Rongji Liu, Shuxia Liu, Xuenian Chen, Carsten Streb   +10 more
wiley   +2 more sources