Results 81 to 90 of about 47,782 (256)

Metal-Free Dihydrogen Oxidation by a Borenium Cation:A Combined Electrochemical/Frustrated Lewis Pair Approach [PDF]

, 2014
In order to use H2 as a clean source of electricity, prohibitively rare and expensive precious metal electrocatalysts, such as Pt, are often used to overcome the large oxidative voltage required to convert H2 into 2 H+ and 2 e−. Herein, we report a metal-
Bard, Chiu, Clark, Clark, Eisenberger, Erker, Farrell, Jutzi, Lawrence, Lawrence, Matsumoto, Matsumoto, Rablen, Stephan, Ueng, Welch   +15 more
core   +1 more source

Tris(pentafluorophenyl)borane and Beyond: Modern Advances in Borylation Chemistry.

Inorganic Chemistry, 2017
As main-group chemistry, in particular boron chemistry, has expanded and developed over the past 20 years, one reagent has risen to prominence as well.
J. R. Lawson, Rebecca L. Melen
semanticscholar   +1 more source

Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes

Molecules, 2019
The utility of an electron-deficient, air stable, and commercially available Lewis acid tris(pentafluorophenyl)borane has recently been comprehensively explored.
Taylor Hackel, Nicholas A. McGrath
doaj   +1 more source

Palladium-Borane Cooperation: Evidence for an Anionic Pathway and its Application to Catalytic Hydro- / Deutero-dechlorination.

Angewandte Chemie, 2019
Metal-Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium-borane cooperation involving anionic Pd(0) species.
H. Kameo, Jun Yamamoto, Ayaka Asada, H. Nakazawa, H. Matsuzaka, D. Bourissou   +5 more
semanticscholar   +1 more source

From betaines to anionic N-heterocyclic carbenes. Borane, gold, rhodium, and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer

Beilstein Journal of Organic Chemistry, 2016
The mesomeric betaine imidazolium-1-ylphenolate forms a borane adduct with tris(pentafluorophenyl)borane by coordination with the phenolate oxygen, whereas its NHC tautomer 1-(2-phenol)imidazol-2-ylidene reacts with (triphenylphosphine)gold(I) chloride ...
Ming Liu, Jan C. Namyslo, Martin Nieger, Mika Polamo, Andreas Schmidt   +4 more
doaj   +1 more source

Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHMe)(2)}] [PDF]

, 2004
Addition of PMe2Ph to fused-cluster syn-[(η5-C5Me5)IrB18H20] 1 to give [(η5-C5Me5)HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido ...
Jelinek, T., Kennedy, J.D., Perera, S.D., Shea, S.L., Stibr, B., Thornton-Pett, M.   +5 more
core   +1 more source

Design, Synthesis, and Evaluation of B-(Trifluoromethyl)phenyl Phosphine–Borane Derivatives as Novel Progesterone Receptor Antagonists

Molecules
We previously revealed that phosphine–boranes can function as molecular frameworks for biofunctional molecules. In the present study, we exploited the diversity of available phosphines to design and synthesize a series of B-(trifluoromethyl)phenyl ...
Yu Miyajima, Kotaro Ochiai, Shinya Fujii
doaj   +1 more source

In situ Synchrotron X-ray Thermodiffraction of Boranes

Crystals, 2016
Boranes of low molecular weight are crystalline materials that have been much investigated over the past decade in the field of chemical hydrogen storage.
Pascal G. Yot, Philippe Miele, Umit B. Demirci   +2 more
doaj   +1 more source

An Improved Synthesis of 3b-Acetoxy-lanost-8-en-24-one (24-Ketolanosteryl Acetate)

Molecules, 2000
The oxidation of a borane intermediate by PFC provides a convenient synthesis of 24-ketolanosteryl acetate.
Terrence L. Boos, Stephen Kizito, Hang Sun, Edward J. Parish   +3 more
doaj   +1 more source

Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation.

Chemical Communications, 2019
The catalytic activity of tris(3,4,5-trifluorophenyl)borane has been explored in the 1,2-hydroboration reactions of unsaturated substrates. Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and
J. Carden, Lukas Gierlichs, D. Wass, D. Browne, Rebecca L. Melen   +4 more
semanticscholar   +1 more source