Results 91 to 100 of about 16,148 (267)

Synthesis of Degradable Polyacetals via an Intramolecular Phosphonium Borane Lewis Pair Catalyzed Copolymerization of Epoxides with o-Phthaladehyde

open access: yes, 2023
An intramolecular phosphonium borane Lewis pair (PBB-Br) was used for the copolymerization of o-phthalaldehyde (OPA) with epoxides under mild conditions.
Minmin, Shi   +4 more
core   +1 more source

Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation

open access: yesMolecules, 2020
Aromatic heterocycles are ubiquitous building blocks in bioactive natural products, pharmaceutical and agrochemical industries. Accordingly, the carborane-fused heterocycles would be potential candidates in drug discovery, nanomaterials ...
Ke Cao   +7 more
doaj   +1 more source

Synthesis and Stereoselective Lithiation of Enantiopure 2‐(1‐Aminoalkyl)aziridine–Borane Complexes

open access: yes, 2004
This work shows that the enantiopure 2-(1-aminoalkyl)aziridine–borane complexes can easily be obtained by two alternative methodologies: either reaction with BF3·Et2O followed by reduction with LiAlH4 or by direct reaction with a solution of BH3 in THF.
José Ramón Suárez   +7 more
core   +1 more source

Borane-Protecting Strategy for Hydrosilylation of Phosphorus-Containing Olefins

open access: yes
Ir-catalyzed hydrosilylation of the alkenyl phosphine borane complex 1 was achieved to give the corresponding products 2. Because the phosphino group coordinates with metals and is unstable under aerobic conditions, the formation of the corresponding ...
Kazuhiko Sato (1628986)   +5 more
core   +1 more source

Synthesis and Molecular Structure of 2-(Diphenylphosphano)phenyl Benzoate Borane Adduct

open access: yesCrystals, 2014
The crystal and molecular structure of 2-(diphenylphosphano)phenyl benzoate borane adduct are reported. The title compound crystallizes from a petroleum ether/ethyl acetate mixture in the triclinic space group P
Constantin Mamat, Martin Köckerling
doaj   +1 more source

Transition metal σ-borane complexes

open access: yes, 2008
A variety of structural types of transition metal complexes containing σ-borane ligands are reviewed. Their structure and bonding are discussed. Compared with other types of σ-complexes, σ-borane complexes display quite different structural and bonding ...
Lin, Zhenyang
core   +1 more source

Ammonia borane

open access: yes, 2004
Inelastic Neutron Scattering spectrum of Ammonia borane, NH₃BH₃, measured on the TOSCA ...
B.S. Hudson, Syracuse Univ., USA
core   +1 more source

Design, Synthesis, and Evaluation of B-(Trifluoromethyl)phenyl Phosphine–Borane Derivatives as Novel Progesterone Receptor Antagonists

open access: yesMolecules
We previously revealed that phosphine–boranes can function as molecular frameworks for biofunctional molecules. In the present study, we exploited the diversity of available phosphines to design and synthesize a series of B-(trifluoromethyl)phenyl ...
Yu Miyajima, Kotaro Ochiai, Shinya Fujii
doaj   +1 more source

Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes

open access: yesMolecules, 2019
The utility of an electron-deficient, air stable, and commercially available Lewis acid tris(pentafluorophenyl)borane has recently been comprehensively explored.
Taylor Hackel, Nicholas A. McGrath
doaj   +1 more source

Borane-Catalyzed Reduction of Pyridines via a Hydroboration/Hydrogenation Cascade

open access: yes, 2021
We have developed a method for a B­(C6F5)3-catalyzed hydroboration/hydrogenation cascade reduction of pyridines. The method was particularly effective for 2,3-disubstituted pyridines, which generated piperidines in high yields with high cis selectivity ...
Xiao-Chen Wang   +7 more
core   +1 more source

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