Results 111 to 120 of about 16,148 (267)

N-Borane-Substituted Cyclic Phosphine Imides (BCPIs)

open access: yes, 2023
Phosphine imides are ubiquitous nucleophiles/Lewis bases in modern organic chemistry. The introduction of unexplored substituents on the phosphine imidoyl nitrogen and/or phosphorus atoms should facilitate the discovery of unprecedented utility for ...
Shun, Nagai   +3 more
core   +1 more source

Ammonia Borane Nanospheres for Hydrogen Storage

open access: yes, 2019
Nanosizing ammonia borane NH3BH3 (AB) is an attractive approach to make it suitable for chemical hydrogen storage. Herein is reported the successful direct preparation of ammonia borane nanospheres. No scaffold is used. The preparation is performed via a
Kondo-François Aguey-Zinsou (2041369)   +5 more
core   +1 more source

σ-Borane Complexes of Manganese and Rhenium

open access: yes, 2016
The late transition metal borane complexes (MeCp)Mn(CO)2(HBR2) (R = alkyl, alkoxy) and Cp*Re(CO)2(HBpin) (HBpin = pinacolborane, Cp* = pentamethylcyclopentadienyl) have been synthesized and isolated.
Sabine Schlecht (1487305)   +1 more
core   +1 more source

High‐performance tetrahedral palladium nanocatalyst for microwave‐assisted organic synthesis

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Tetrahedral palladium nanoparticles anchored on graphene sheets (T‐Pd/graphene) were synthesized through a solvent‐free process involving thermal decomposition in an environment rich in carbon monoxide at elevated temperatures and have high catalytic activity for organic chemistry reactions. Abstract Palladium is widely recognized for its effectiveness
Dicky Annas   +9 more
wiley   +1 more source

Hydrolysis of ammonia borane and hydrazine borane by poly($N$-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage

open access: yes, 2017
For the first time the synthesis of poly(N-vinyl-2-pyrrolidone)-stabilized cobalt-palladium nanoparticles by an easy method, their characterization, and their use as active catalysts for hydrogen release from hydrolysis of ammonia borane and hydrazine ...
Bayram ABAY   +5 more
core   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Solvent‐Driven Conformational Landscapes of a Tetradentate Schiff Base Ligand and Its Metal Complexes: A Genetic Algorithm–Guided VCD Investigation

open access: yesChemistry – A European Journal, EarlyView.
Solvent effects: vibrational circular dichroism (VCD) revealed pronounced solvent‐induced conformational shifts for a tetradentate salen ligand in CDCl3, a solvent generally considered benign. Contrary to the DFT prediction of a single dominant conformer family, quantum cluster growth together with the genetic algorithm guided VCD analysis uncovered ...
Amanda Nhi Tran   +9 more
wiley   +1 more source

Ammonia borane-D6

open access: yes, 2012
Inelastic Neutron Scattering spectrum of Ammonia borane-D6, ND₃BH₃, measured on the TOSCA instrument.
W.I.F. David, ISIS
core   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

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