Results 131 to 140 of about 16,148 (267)

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

open access: yesChemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew   +3 more
wiley   +1 more source

Dual‐Functional Sulfonated Nanocellulose for Proton Exchange Membranes With High Proton Conductivity at Low Humidity

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A scalable dual‐functional strategy yields simultaneously sulfonated and nanosized cellulose for proton exchange membranes with continuous hydrogen‐bond networks. These sustainable membranes exhibit low‐humidity proton conductivity twofold higher than Nafion 212, providing a robust solution for next‐generation fuel cells.
Nan Li   +6 more
wiley   +1 more source

Hydrogen Generation via Catalytic Ammonia Borane Hydrolysis: A Patent Overview

open access: yes
Hydrogen is one of the clean energies that will play an important role in energy selection for the coming low-carbon society. Ammonia borane (NH3BH3, abbreviated hereafter as AB) is considered as a promising hydrogen storage material due to its high ...
Koyo, Matsuda
core   +1 more source

Breaking the Temperature Barrier: Ultra‐Stable SiHfBCN Ceramic Coatings for High‐Temperature Pressure Sensing

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A 3D conductive net including HfC(N) conductive nanodomains and in‐situ carbon ribbons was generated within the amorphous SiHfBCN matrix by a new molecular‐level composition and microstructure design strategy, making a smooth and dense polymer‐derived SiHfBCN ceramic coatings exhibits excellent electrical conductivity, wide‐temperature sensing, cycling
Xichao Dong   +6 more
wiley   +1 more source

Conjugated organic and organoboron materials [PDF]

open access: yes, 2005
A series of compounds containing one or more dimesitylboryl groups (mesityl = 2,4,6-trimethylphenyl) has been synthesised. Triarylboranes were synthesised by reaction of dimesitylfluoroborane with an appropriate lithium reagent.
Entwistle, Christopher Donald
core  

Synergistic Modulation of Conductivity and Oxidation Stability in SiHfBCN Ceramics via UV‐Assisted Structural Evolution

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A quinary UV‐curable SiHfBCN ceramic photoresist with high ceramic yield enhanced is developed through sequential molecular design for high‐temperature sensing coatings. The elevated interconnected conductive network induced by chemically bonded carboxylated MWCNTs enables the pyrolyzed ceramics' enhanced conductivity and excellent oxidation stability.
Xiyue Zhu   +8 more
wiley   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair   +3 more
wiley   +1 more source

Hydrosilane Chemistry: From Historic First Steps to Modern Applications

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
This review covers the history of hydrosilanes, from their initial discovery to their modern applications. It highlights the pioneering work of chemists like Alfred Stock and Franz Fehér and discusses the modern ways of synthesis and use of hydrosilanes in printed electronics.
Uwe Böhme, Maik Gerwig
wiley   +1 more source

Main Group Metals in Redox Catalysis

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki   +2 more
wiley   +1 more source

Total Synthesis of Sacrolide A and Cytotoxic Evaluation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Isolated from the edible cyanobacterium Aphanothece sacrum, sacrolide A is a highly potent antimicrobial and cytotoxic metabolite. Its total synthesis via a convergent strategy enabled accurate assessment of its effects on liver and colon cells, offering new insights into its bioactivity and potential health risks.
Priyanka Kataria   +7 more
wiley   +1 more source

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