Results 141 to 150 of about 16,148 (267)

"Rhodium catalysed borylation reactions via direct and indirect c-h activation" [PDF]

open access: yes, 2002
This thesis describes both direct and indirect C-H activation borylation processes, catalysed by several Rh-based catalyst precursors. Chapter One presents an overview of the processes investigated, namely diboration, dehydrogenative borylation, and ...
Coapes, Richard Benjamin
core  

The Synthesis Use of a Difluorinated Amino‐Benzo‐Cinnoline Dyes (ABCDyes) Enables Fine Tuning of Emission Through Double SNAr Late‐Stage Functionalization

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
An efficient synthesis of difluorinated amino‐benzo‐cinnoline dyes (ABCDyes) is reported. Their use for the late‐stage introduction of internal dinucleophilic species through a double SNAr reaction enables straightforward access to previously unexplored ABCDye analogs displaying tunable emission ranging from green to red.
Mélina Fabe   +3 more
wiley   +1 more source

Constructing better electrode–electrolyte interphases in sodium‐ion battery cathodes

open access: yesInfoMat, EarlyView.
Recent work on the engineering of electrode–electrolyte interphases (EEIs) in sodium‐ion batteries (SIBs) cathode materials has been summarized. The classifications and corresponding problems are presented, followed by electrolyte, auxiliary, and electrode engineering methods.
Junpeng Xie   +4 more
wiley   +1 more source

Catechol‐Containing Poly(2‐isopropyl‐2‐oxazoline): Synthesis and Thermoresponsive Behavior in Aqueous Salt Solutions

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj   +4 more
wiley   +1 more source

Quantification of 10B and 11B in Biological Samples in Translational Science and Clinical Applications for Boron Neutron Capture Therapy (BNCT)

open access: yesMedicinal Research Reviews, EarlyView.
ABSTRACT Boron neutron capture therapy (BNCT) is a targeted radiotherapy that exploits the selective accumulation of the 10B isotope within tumors, followed by irradiation with low‐energy neutrons to induce high linear energy transfer particles with short path lengths, resulting in localized tumor cell destruction while sparing surrounding healthy ...
Christoph Selg   +2 more
wiley   +1 more source

Corrosion and Passivation: An Intimate Struggle for Durable Non‐Aqueous Multivalent Metal Batteries

open access: yesNational Materials, EarlyView.
In multivalent metal batteries, corrosion and passivation are intrinsically coupled. Anodes and current collectors pose conflicting interfacial demands: ion‐ versus electron‐conductivity. This review deciphers their intricate interplay and discusses current strategies to balance these mechanisms for achieving durable battery performance.
Hongfeng Chen   +5 more
wiley   +1 more source

Unsaturated biobased polyesters from bicyclic α‐pinene‐based diols

open access: yesPolymer International, EarlyView.
We present the synthesis of four biosourced unsaturated polyesters made from chiral terpene‐based diols and esters of renewable diacids. The resulting materials harbor a bicyclic pinene ring in their backbones which leads to enhanced thermal properties while still conferring susceptibility to enzyme hydrolysis for chains having a cis alkene.
Ganapathy Ranjani   +4 more
wiley   +1 more source

Synthesis of Amorphous‐Crystalline Mixture Boron Nitride for Balanced Resistive Switching Operation

open access: yesSmall, EarlyView.
An amorphous–crystalline mixture BN (acm‐BN) is synthesized through low‐pressure chemical vapor deposition, achieving balanced resistive switching with low SET voltage and stable RESET. High‐resolution transmission electron microscopy reveals that BN films are fully amorphous at 930 °C, a mixed amorphous–crystalline phase is achieved at 990 °C.
Kyung Jin Ahn   +8 more
wiley   +1 more source

Dual Functionality of a Plasmonic Gold Photocatalyst in the Reversible Dehydrogenation / Hydrogenation of N‐Heterocycles

open access: yesSmall, EarlyView.
A new hybrid plasmonic material, Au@COF, serves as a recyclable photocatalyst for the light‐mediated dehydrogenation and hydrogenation of N‐Heterocycles, where simply adjusting the reaction conditions allows control over the reaction mechanism, marking a notable breakthrough for hydrogen storage.
Alba Sorroche   +4 more
wiley   +1 more source

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