Results 101 to 110 of about 16,148 (267)

Stoichiometric and Catalytic Synthesis of Alkynylphosphines

open access: yesMolecules, 2012
Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont   +3 more
doaj   +1 more source

Borane transfer reactions [PDF]

open access: yes, 2016
Lewis base borane adducts (LB·BH3) constitute a well-known class of molecules with a number of diverse applications, including use as protected phosphines.
Taylor, Nicholas
core  

boranes

open access: yes, 2014
Citation: 'boranes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.B00709 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial usage
openaire   +1 more source

Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes [PDF]

open access: yes, 2010
Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability.
Safronov, Alexander V.   +9 more
core   +1 more source

Borane–Trimethylamine Complex: A Versatile Reagent in Organic Synthesis

open access: yesMolecules
Borane–trimethylamine complex (Me3N·BH3; BTM) is the most stable of the amine–borane complexes that are commercially available, and it is cost-effective.
Dario Perdicchia
doaj   +1 more source

Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

open access: yes, 2007
The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane ...
Xu, Jiaxi   +5 more
core   +1 more source

Late‐Stage Functionalization of Peptides on the Solid Phase

open access: yesAngewandte Chemie International Edition, EarlyView.
Peptide modifications are essential to control pharmacodynamic and pharmacokinetic properties of peptide drugs. Consequently, strategies that allow for efficient and rapid incorporation of non‐canonical modifications into peptides in parallel formats are highly sought after.
Marius Werner   +2 more
wiley   +1 more source

Silica embedded cobalt(0) nanoclusters: Efficient, stable and cost effective catalyst for hydrogen generation from the hydrolysis of ammonia borane

open access: yes, 2011
Cobalt(0) nanoclusters embedded in silica (Co@SiO2) were prepared by a facile two-step procedure. In the first step, the hydrogenphosphate anion (HPO42-) stabilized cobalt(0) nanoclusters were in situ generated from the reduction of cobalt(II) chloride ...
Metin, Onder   +3 more
core   +1 more source

Resolution and Stereochemistry of tert-Butylphenylphosphinous Acid−Borane

open access: yes, 2016
A combined use of ephedrine and cinchonine as resolving agents enabled facile resolution of racemic tert-butylphenylphosphinous acid−borane (1) into the two enantiomers in ca. 31−32% yield each.
K. Michał Pietrusiewicz (1676410)   +1 more
core   +2 more sources

Phosphido-Borane and Phosphido-Bis(Borane) Complexes of the Alkali Metals, a Comparative Study

open access: yes, 2016
Treatment of the secondary phosphine {(Me3Si)2CH}­(Ph)­PH with BH3·SMe2 yields the phosphine-borane {(Me3Si)2CH}­(Ph)­PH­(BH3) (12) as colorless crystals.
Keith Izod (1580347)   +3 more
core   +1 more source

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