Synthesis, structures and coordination chemistry of singly bridged phosphane-boranes with coordinately unsaturated platinum group metals [PDF]
A range of singly bridged phosphane-boranes (PBs) have been investigated as potential ligands for basic transition metals. The PBs Ph2PC(Ph)=C(R)BR2 (R = Bu 1, Ph 2, Et 3), based on a rigid cis-ethylene bridges, have been prepared, improving upon limited
Allen +75 more
core +1 more source
From Materials to Systems: Challenges and Solutions for Fast‐Charge/Discharge Na‐Ion Batteries
This review systematically analyzes the key characteristics limiting the fast‐charge/discharge capability of Na‐ion batteries (SIBs) from a multi‐scale perspective encompassing electrode materials, the electrode‐electrolyte interface, and the system. Furthermore, it presents practical solution strategies for the fundamental issues arising at each scale,
Bonyoung Ku +5 more
wiley +1 more source
Multifunctionality of silver closo-boranes
Silver compounds have long been known to possess exceptional solid-state conductivity. Here the authors present silvercloso-boranes in which facile Ag+migration occurs, leading to exceptionally high ion conductivities and potential utility in silver ...
Mark Paskevicius +4 more
doaj +1 more source
In situ Synchrotron X-ray Thermodiffraction of Boranes
Boranes of low molecular weight are crystalline materials that have been much investigated over the past decade in the field of chemical hydrogen storage.
Pascal G. Yot +2 more
doaj +1 more source
Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation-Borylation Methodology [PDF]
The synthesis of highly enantioenriched alpha-heterocyclic tertiary alcohols has been achieved via lithiation-borylation of a configurationally stable lithiated carbamate and heterocyclic pinacol boronic esters followed by oxidation. Protodeboronation of
Aggarwal V. K. +41 more
core +3 more sources
Quantitative proteomics identifies clusterin as a novel biomarker for atherosclerosis
This schematic illustrates the proposed mechanism. In advanced atherosclerotic lesions, upregulated CLU on the cell surface activates low‐density lipoprotein (LDL) receptor‐related protein 1 (LRP1). This interaction triggers the phosphorylation and activation of AKT.
Dengfeng Ding +10 more
wiley +1 more source
Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation [PDF]
Despite rapid advances in the field of metal-free, “frustrated Lewis pair” (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions has hampered wide-scale uptake of this methodology.
Ashley, Andrew E. +5 more
core +3 more sources
Phosphido-borane-supported stannates
While the reaction between three equivalents of the alkali metal phosphido-borane complexes [R2P(BH3)]M (M = Li, Na, K; R = Ph, iPr) with SnCl2gave the tris(phosphido-borane)stannates [M{R2P(BH3)}3Sn], similar reactions between [tBu2P(BH3)]M and SnCl2gave the known hydrido-stannate [M{tBu2P(BH3)}2Sn(H)].
Keith Izod +3 more
openaire +3 more sources
Isolation und Reaktivtät eines quadratisch‐planaren Trisamidosilans
Wir berichten über die Synthese und umfassende Charakterisierung eines quadratisch‐planaren Si(+IV)‐Hydrids, das von einem unsymmetrischen, trianionischen und dearomatisierten N,N,N‐Pincerliganden stabilisiert wird. Dieses System ermöglicht eine Element–Liganden‐kooperative Reaktivität als Alternative zur siliciumzentrierten Redoxchemie und erweitert ...
David M. J. Krengel +5 more
wiley +1 more source
Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances
Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen ...
Carlos A. Castilla-Martinez +3 more
doaj +1 more source

