Results 121 to 130 of about 20,491 (284)

Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications

open access: yesExploration, EarlyView.
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou   +5 more
wiley   +1 more source

Memory of Chirality in Radical Addition–Translocation–Cyclization Cascades

open access: yesHelvetica Chimica Acta, EarlyView.
Radical addition–translocation–cyclization cascades of chiral alkynes show striking memory of chirality (MoC), with strong retention of configuration when fast, polarity favored cyclization are involved. The most effective system employs a highly electron‐poor pentafluorobenzenesulfonyl group.
Christian Simon Gloor   +3 more
wiley   +1 more source

Catechol‐Containing Poly(2‐isopropyl‐2‐oxazoline): Synthesis and Thermoresponsive Behavior in Aqueous Salt Solutions

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj   +4 more
wiley   +1 more source

Living Coordination (Co)Polymerization of Norbornene Derivatives by Using Nickel Catalysts Derived From Bis(1,5‐Cyclooctadiene)nickel(0) and 2,6‐Dihydroxybenzoic Acid

open access: yesJournal of Polymer Science, EarlyView.
The living coordination polymerization of norbornene is achieved using a nickel catalyst derived from Ni(cod)2 and 2,6‐dihydroxybenzoic acid with trityl borate as cocatalyst to produce poly(norbornene) with controllable molecular weights and narrow polydispersity.
Taidong Yao   +5 more
wiley   +1 more source

Tuning the formal potential of ferrocyanide over a 2.1 V range [PDF]

open access: yes, 2019
We report the synthesis and characterization of homoleptic borane adducts of hexacyanoferrate(II). Borane coordination blueshifts d–d transitions and CN IR and Raman frequencies.
Despagnet-Ayoub, Emmanuelle   +4 more
core   +1 more source

Synthesis of Amorphous‐Crystalline Mixture Boron Nitride for Balanced Resistive Switching Operation

open access: yesSmall, EarlyView.
An amorphous–crystalline mixture BN (acm‐BN) is synthesized through low‐pressure chemical vapor deposition, achieving balanced resistive switching with low SET voltage and stable RESET. High‐resolution transmission electron microscopy reveals that BN films are fully amorphous at 930 °C, a mixed amorphous–crystalline phase is achieved at 990 °C.
Kyung Jin Ahn   +8 more
wiley   +1 more source

Exploring Stereogenic Phosphorus: The Search for New Chiral Diphosphines

open access: yesCHIMIA, 2001
The synthesis of P-stereogenic ligands bearing 2,6-disubstituted phenyl groups at the P atom is a challenging problem. The results reported herein help define the scope and limitations of the existing synthetic protocols, such as Jugé's ...
Francesca Maienza   +4 more
doaj  

Redox‐Active Frustrated Lewis Pair‐Mediated B─H Bond Activation: From Proton Transfer to THF Ring Opening

open access: yesChemistryEurope
The CAAC‐stabilized dithiolene (L0) zwitterion (1), an unusual redox‐active intramolecular frustrated Lewis pair (FLP), activates the B─H bond of boranes via hydride‐coupled reverse electron transfer processes.
Yuzhong Wang   +5 more
doaj   +1 more source

Combustion and Thermal Decomposition of Hydrazine Borane [PDF]

open access: bronze, 2015
W Berl   +6 more
openalex   +1 more source

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