Boric Acid Post‐Modified [Al]ZSM‐5 Zeolites: Properties, Acidity, and Ethanol/Ethene Conversion
The modification of MFI zeolites with boric acid leads to the formation of framework boron, unstable surface species, and unbound deposits. Relevant BAS for catalysis and access to pores are strongly reduced. The boric acid is removed upon converting C1 or C2 alcohols and ethene. ABSTRACT The effect of boric acid post‐modification on [Al]ZSM‐5 zeolites
Zheng Li +3 more
wiley +1 more source
Boron Neutron Capture Therapy at a Crossroads: Translational Gap and Emerging Delivery Agents
This review surveys recent advances in boron delivery agents for BNCT, emphasizing the shift from classical small molecules to multifunctional nanocarriers and theranostic systems. By integrating targeting, imaging, and therapy, next‐generation boron compounds aim to bridge the gap between (bio)chemical innovation and clinical translation.
Christoph Selg, Evamarie Hey‐Hawkins
wiley +1 more source
Merging Pyrrole with Boron into Versatile Di(2-pyrryl)borane Building Blocks: π-Extension, Polymerization, and Coordination. [PDF]
Göbel D +6 more
europepmc +1 more source
Dealkylation as a Strategy to Synthesize Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes. [PDF]
Kornokovich AD +5 more
europepmc +1 more source
Lipid drug carriers to which ultra‐small gold nanoparticles were added enabled more efficient radiotherapy of cultured pancreatic cancer tumors. These nanoparticles boosted radiation‐induced damage to tumors by generating more reactive molecules, though higher gold levels are needed for strong benefits.
Nazareth Milagros Carigga Gutierrez +17 more
wiley +1 more source
Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley +2 more sources
Direct Access to Acylboranes via Formal Condensation of Carboxylic Acids with Ligated Boranes. [PDF]
Cai CY +5 more
europepmc +1 more source
Wafer‐Scale Single‐Crystal Boron Nitride: Synthesis and Integration in 2D Electronics
This Review highlights recent breakthroughs in wafer‐scale hBN synthesis and its integration into next‐generation 2D electronics. We analyze growth kinetics, epitaxial strategies, and stacking‐sequence control while correlating material quality with device performance.
Jaewon Wang, Soon‐Yong Kwon
wiley +1 more source
Catalytic Asymmetric 1,2-Migration/Allylation of Alkynyl Boronate Complexes: A Modular Route to Enantioenriched Skipped 1,4-Dienes. [PDF]
Wei L, Guo Z, Tyler JL, Aggarwal VK.
europepmc +1 more source
Systematic pnictogen variation (P, As, Sb, Bi) in PnMes3–B(C6F5)3 Frustrated Lewis Pairs (FLPs) reveals how both the energy and intensity of charge–transfer excitation can be tuned. Increasing pnictogen–boron orbital overlap and dispersion enhances oscillator strength and encounters complex stability, enabling higher radical ion pair concentrations ...
Lars J. C. van der Zee +8 more
wiley +1 more source

