Results 151 to 160 of about 20,491 (284)
Small boranes, carboranes, and heterocarboranes [PDF]
Walter Siebert +6 more
openalex +1 more source
Selective Scrambling of Phenyl‐Stannanes: Main Group Catalysis With Aromatic Phosphorus Heterocycles
Phosphinine–borane Lewis pairs catalyze the selective scrambling of phenylstannanes into SnPh4, H2, and elemental Sn. The reaction proceeds via transient SnH4 formation through reversible hydride and phenyl transfer steps within three interconnected cycles and enabled by an intrinsically weak P→B bond.
Samantha Frank +7 more
wiley +1 more source
Rigid Ligand Environments at Beryllium, From Spectroscopic Probes to Small Molecule Activation
Due to the high rigidity and definition of beryllium scorpionate complexes, they can be used to study metal‐pseudohalide and ‐carbon bonds in detail. Furthermore, these compounds can be used to activate small molecules and exhibit unprecedented transmetalation reactions. In beryllium scorpionate complexes, three of the four available coordination sites
Magnus R. Buchner, Chantsalmaa Berthold
wiley +1 more source
FeCl3‐Catalyzed Synthesis of Ynones from Silylated Alkynes and Acetic Anhydride
The synthesis of alkynones from silylated alkynes and acid chlorides, first reported by Birkhofer in 1963, remains a valuable transformation. However, its reliance on stoichiometric AlCl3 and corrosive reagents raises environmental and practical concerns. To address this, a greener protocol using catalytic FeCl3 and acetic anhydride is developed.
Paul Charki +2 more
wiley +1 more source
Crystal structure and photophysical properties of (κ2‐(N,O)‐5,7‐dichloro‐2‐methyl‐8‐quinolinolate)di(pentafluorophenyl)borane: Experiment and density functional theory calculations [PDF]
Nguyen Minh Phuong +9 more
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The pictorial illustration of the applications of polymers of intrinsic microporosity extraordinary porous organic polymers with high surface areas, pore radii, pore volumes, high permeability, high diffusivity, high selectivity, and high thermal stability, as suitable filters or purifiers for water contaminated with pharmaceutical and organic dyes ...
Martins O. Omorogie
wiley +1 more source
Tris(pentafluorophenyl)borane‐Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis—A Computational and Experimental Study [PDF]
Ayan Dasgupta +7 more
openalex +1 more source

