Results 161 to 170 of about 20,491 (284)

Organophosphide: Eine neue Klasse der Luminophorliganden für Kupfer(I)‐Carben‐basierte TADF‐Emitter und Photokatalysatoren

open access: yesAngewandte Chemie, Volume 138, Issue 13, 23 March 2026.
Der Einsatz von Dimesitylphosphid als höheres Homolog der etablierten Amidoliganden für Charge‐Transfer‐Kupfer(I)‐Komplexe führt zu einer Rotverschiebung der Emission um 3645 cm–1 in den rot‐orangen Spektralbereich im Festkörper sowie in den NIR‐Bereich in Lösung. Die thermisch‐aktivierte verzögerte Fluoreszenz weist hohe Dissymmetriefaktoren von glum =
Paul C. Ruer   +2 more
wiley   +1 more source

Organophosphides: A New Class of Luminophore Ligands for Copper(I) Carbene Based TADF Emitters and Photocatalysts

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 13, 23 March 2026.
Dimesitylphosphide as a heavier congener of established amide ligands for charge‐transfer copper(I) complexes leads to bathochromic shift of the emission by up to 3645 cm−1 into the orange‐red (solid, polymer films) and even NIR (solution). The thermally activated delayed fluorescence exhibits high dissymmetry factors of glum = 10−2 in polystyrene.
Paul C. Ruer   +2 more
wiley   +1 more source

Mild Generation of Highly Nucleophilic N‐Heterocyclic Carbene Boryl Anion From Neutral sp2–sp3 Diboron Reagents and Its Applications in Nucleophilic Borylation

open access: yesAngewandte Chemie, Volume 138, Issue 11, 9 March 2026.
A less hindered and highly nucleophilic N‐heterocyclic carbene (NHC) boryl anion is generated at room temperature by reacting sp2–sp3 diboron reagent (NHC)BH2Bpin with KOtBu. This highly reactive anion demonstrates broad reactivity with various electrophiles, including those traditionally considered inert, enabling their efficient borylation.
Weixuan Sun, Peiqi Zhang, Hairong Lyu
wiley   +1 more source

Merging Pyrrole with Boron into Versatile Di(2-pyrryl)borane Building Blocks: π-Extension, Polymerization, and Coordination. [PDF]

open access: yesAngew Chem Int Ed Engl
Göbel D   +6 more
europepmc   +1 more source

Dealkylation as a Strategy to Synthesize Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes. [PDF]

open access: yesInorg Chem
Kornokovich AD   +5 more
europepmc   +1 more source

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