Der Einsatz von Dimesitylphosphid als höheres Homolog der etablierten Amidoliganden für Charge‐Transfer‐Kupfer(I)‐Komplexe führt zu einer Rotverschiebung der Emission um 3645 cm–1 in den rot‐orangen Spektralbereich im Festkörper sowie in den NIR‐Bereich in Lösung. Die thermisch‐aktivierte verzögerte Fluoreszenz weist hohe Dissymmetriefaktoren von glum =
Paul C. Ruer +2 more
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Dimesitylphosphide as a heavier congener of established amide ligands for charge‐transfer copper(I) complexes leads to bathochromic shift of the emission by up to 3645 cm−1 into the orange‐red (solid, polymer films) and even NIR (solution). The thermally activated delayed fluorescence exhibits high dissymmetry factors of glum = 10−2 in polystyrene.
Paul C. Ruer +2 more
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Bimetallic NiCo Nanoparticles Embedded in Organic Group Functionalized Mesoporous Silica for Efficient Hydrogen Production from Ammonia Borane Hydrolysis [PDF]
Juti Rani Deka +5 more
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Continuous synthesis of TiO2-supported noble metal NPs and their application in ammonia borane hydrolysis [PDF]
Lamei Luo, Mei Yang, Guangwen Chen
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A less hindered and highly nucleophilic N‐heterocyclic carbene (NHC) boryl anion is generated at room temperature by reacting sp2–sp3 diboron reagent (NHC)BH2Bpin with KOtBu. This highly reactive anion demonstrates broad reactivity with various electrophiles, including those traditionally considered inert, enabling their efficient borylation.
Weixuan Sun, Peiqi Zhang, Hairong Lyu
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Merging Pyrrole with Boron into Versatile Di(2-pyrryl)borane Building Blocks: π-Extension, Polymerization, and Coordination. [PDF]
Göbel D +6 more
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Facile Fabrication of Rhodium/Nanodiamond Hybrid as Advanced Catalyst toward Hydrogen Production from Ammonia–Borane [PDF]
Zhaoyu Wen, Jie Wu, Guangyin Fan
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Dealkylation as a Strategy to Synthesize Unconventional Lithium Salts from ortho-Phenyl-phosphonate-boranes. [PDF]
Kornokovich AD +5 more
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Ultrafine Ni−MoOx Nanoparticles Anchored on Nitrogen‐Doped Carbon Nanosheets: A Highly Efficient Noble‐Metal‐Free Catalyst for Ammonia Borane Hydrolysis [PDF]
Weihong Liu +7 more
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