Results 121 to 130 of about 38,047 (279)

Kinetics of Sodium Borohydride Hydrolysis Reaction for Hydrogen Generation

open access: yes, 2011
In this work, a ruthenium catalyst was prepared for hydrogen generation from the hydrolysis reaction of an alkaline sodium borohydride solution. The reactions were carried out in a batch reactor at temperatures of 10, 30, 40 and 60 °C for at least 70 ...
Hung, Ai-jen; Tsai, Shing-fen; Hsu, Ya-yi; Ju, Jie-ren; Chen, Yih-hang; Yu, Cheng-ching
core   +1 more source

Synthesis of Oligonucleotide Conjugates Employing a Diselenide Linker

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT In this study, we report the synthesis of an alkylene linker containing a terminal 2‐cyanoethyl protected selenium functionality for coupling at the 5'‐end of an oligonucleotide by solid phase synthesis for the preparation of oligonucleotide conjugates.
Shivam Tikoo   +2 more
wiley   +1 more source

Tuning the Growth Pattern of Triangular Silver Nanoplates from Lateral to Vertical by Secondary Metal Addition

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
What happens, if in the synthesis of flat silver platelets, the slow deposition of silver along twinning faults is disturbed by the addition of a nobler metal? We have looked into it and found a way to fine‐tune the metal deposition in lateral and vertical direction.
Jonas Kluitmann   +3 more
wiley   +1 more source

Hydrogen production from sodium borohydride

open access: yes, 2007
The rapid development of the proton exchange membrane fuel cell technology in recent years has stimulated research in the low cost hydrogen production and high efficient hydrogen storage.
Xu Dongyan, Zhang Huamin, Ye Wei
core  

Bimetallic Synergy in Cocatalyst Alloy Nanoparticles for Efficient Photocatalytic Hydrogen Production

open access: yesEcoEnergy, EarlyView.
A bimetallic NiAg alloy is assembled on the surface of Zn3In2S6 to construct a NiAg‐Zn3In2S6 composite using a chemical reduction method. By adjusting the different alloy ratios, the hydrogen evolution activity of the optimum Ni0.25Ag0.75‐Zn3In2S6 photocatalyst achieves 21.32 mmol·g−1·h−1. ABSTRACT A bimetallic NiAg alloy is assembled on the surface of
Zhihui Yang   +4 more
wiley   +1 more source

A high-spin nickel(II) borohydride complex in dehalogenation

open access: yes, 2016
A nickel(II)-borohydride complex bearing a macrocyclic tridentate N-donor ligand, [Ni(Me-3-TACN)(BH4)-(CH3CN)](+) (Me-3-TACN = 1,4,7-trimethyl-1,4,7-triazacyclononane), was prepared, isolated, and characterized by various physicochemical methods ...
Kang, Joongoo   +3 more
core   +1 more source

Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi2Te3/TiO2‐X Heterostructures for Highly Efficient Photothermal‐Driven CO2 Photoreduction

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Integrating the topological insulator Bi2Te3 with oxygen‐deficient TiO2‐X creates a synergistic platform for full‐spectrum CO2 reduction, achieving high‐selectivity C2+ production via enhanced photothermal catalysis and tailored charge dynamics.
Bingke Zhang   +11 more
wiley   +1 more source

Chemoselective reduction of aldehydes with zinc borohydride in tetrahydrofuran

open access: yes, 1990
A variety of structurally different aldehydes undergo chemoselectire reduction over ketones with zinc borohydride in tetrahydrofuran at -10°C to the corresponding alcohols.
Ranu, Brindaban C.   +3 more
core   +1 more source

Activating and Stabilizing Lattice Oxygen in Spinel NiCo2O4 through F, Mn Dual Doping for Rechargeable Zinc–Air Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study exploited the substitution doping of Mn and F in NiCo2O4 to activate and stabilize lattice oxygen, achieving a stable synergistic effect between AEM and LOM to enhance the intrinsic activity of the catalyst. The outstanding bifunctional properties enable its application as an anode catalyst in zinc–air batteries.
Jitong Li   +8 more
wiley   +1 more source

Electro-Oxidation of Borohydride on Rhodium, Iridium, and Rhodium–Iridium Bimetallic Nanoparticles with Implications to Direct Borohydride Fuel Cells

open access: yes, 2010
Electrochemical oxidation of borohydride is studied on nanosized rhodium, iridium, and bimetallic rhodium–iridium catalysts supported onto Vulcan XC72R carbon.
Kalyanasundaram, N.T.   +19 more
core   +1 more source

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