Results 101 to 110 of about 38,047 (279)

The Oxidation Mechanisms of Saturated Fatty Acids: Formation of Hydroperoxide Isomers and Production of 2‐Alkanones and Lactones

Journal of the American Oil Chemists' Society, EarlyView.
ABSTRACT Saturated fatty acids (SFAs) are generally regarded simply as being resistant to oxidation compared with unsaturated fatty acids. However, it has long been reported that SFAs can undergo oxidation when heated at high temperatures, leading to the formation of unique degradation products such as 2‐alkanones and lactones.
Kanji Aoyagi, Shunji Kato, Kiyotaka Nakagawa   +2 more
wiley   +1 more source

Überraschende Umlagerungen eines 1,2,5,7-Benzothiatriazonins

CHIMIA, 1984
Sodium borohydride reduction of 1,2,5,7-benzothiatriazonine 3 yields two isomeric products 4 and 5 (Scheme 1) whereas a third isomer 7 has been obtained after heating 3 in methanol and subsequent reduction of the intermediate 6 with sodium borohydride ...
Marlise Schläpfer-Dähler, Jost H. Bieri, Heinz Heimgartner   +2 more
doaj   +1 more source

Integrating agro‐residue valorization and clean hydrogen production: coconut fiber‐based catalysts for NaBH4 hydrolysis

Biofuels, Bioproducts and Biorefining, EarlyView.
Abstract A novel phosphoric acid‐treated green coconut fiber (GCF‐C) was developed as a catalyst for hydrogen production from the hydrolysis of sodium borohydride (NaBH4). Characterization techniques confirmed structural modifications, including X‐ray diffraction, scanning electron microscopy, X‐ray fluorescence, Fourier transform infrared, and ...
Isabelly Silveira Freitas, Francisco Izaias da Silva Aires, Dayana Nascimento Dari, Jacob Tchiyeke António Kandjila, Maurício Quintas Salamba, Diego Lomonaco, Monalisa Moura de Oliveira, Pierre Basílio Almeida Fechine, Rafael Leandro Fernandes Melo, Alan Silva de Menezes, Marcos Carlos de Mattos, Leonardo Farias Serafim, Maria Cristiane Martins de Souza, Ada Amelia Sanders Lopes, John Herbert da Silva Felix, Eveline de Abreu Menezes, José Cleiton Sousa dos Santos   +16 more
wiley   +1 more source

Alkene Isomerization Catalyzed by a Mn(I) Bisphosphine Borohydride Complex

An additive-free manganese-catalyzed isomerization of terminal alkenes to internal alkenes is described. This reaction is atom economic, implementing an inexpensive, non-precious metal catalyst. The most efficient catalyst is the borohydride complex cis-[
Karl, Kirchner, Stefan, Weber, Robin, Dülger, Ines, Blaha, Luis, Veiros   +4 more
core   +1 more source

Glycosylated dendrimer nanoamplifiers hijack DNA damage‐immune crosstalk for enhanced dual‐track therapy of orthotopic glioblastoma

BMEMat, EarlyView.
A glycosylated dendrimer nanoamplifier hijacks DNA damage‐immune crosstalk for enhanced radio‐immunotherapy of glioblastoma. The responsive release of demethylcantharidin simultaneously blocks repair‐mediated resistance by inhibiting DNA repair and overcomes adaptive immune resistance.
Cong Song, Binghan Liu, Junjie Liu, Ce Li, Wenqing Man, Xurui Sun, Chang Yuan, Yanjun Wang, Hong Pan, Shuanglian Wang, Zhiming Zheng   +10 more
wiley   +1 more source

Magnesium borohydride beta

, 2010
Inelastic Neutron Scattering spectrum of Magnesium borohydride beta, Mg(BH₄)₂, measured on the TOSCA instrument. Beta Phase. Natural abundance B. Backscattering detectors only.
D. Colognesi, CNR Florence, Italy
core   +1 more source

Micro method for determination of borohydride with NAD+ [PDF]

, 1972
A spectrophotometric method for the determination of borohydride is described. It involves the reduction of NAD+ to a number of isomeric forms of NADH by borohydride.
Huang, Chin C., Werner, D. A., David Aminoffl, D. A. Werner, Aminoff, David, Chin C. Huang   +5 more
core   +1 more source

Multifunctional Design of Solid Polymer Electrolytes: Paving the Way for High‐Performance All‐Solid‐State Batteries

Carbon Energy, EarlyView.
This review provides a comprehensive and systematic overview of the multifunctional design strategies for solid polymer electrolytes (SPEs), a pivotal component for enabling high‐performance all‐solid‐state batteries (ASSBs). It begins with a detailed classification of SPE systems and elaborates on their respective molecular design principles. The work
Bin Man, Yuzhen Zhao, Bo Fu, Yulong Zeng, Yinwen Chen, Qingrui Liu, Wenjing Luo, Xin Li, Xuewei Li, Zikang Zhang, Yun Zheng, Sijie Liu   +11 more
wiley   +1 more source

Locking Ni Atoms in Ordered PtNi for Durable Hydrogen Production: From Electrocatalyst Design to Practical AEMWE Stack Validation

Carbon Energy, EarlyView.
DFT‐guided atomic ordering of PtNi intermetallic catalysts enhances HER activity and durability by optimizing hydrogen adsorption and increasing dissolution potential. Experimental validation from half‐cell to practical AEMWE stack demonstrates outstanding performance with less than 2% degradation over 3,000 h.
Song Jin, Minseon Park, Jae‐Yeop Jeong, Shin‐Woo Myeong, Seung Min Woo, Junyoung Park, Jaehun Lee, Nam In Kim, Jun Seok Ha, Yoo Sei Park, Chiho Kim, Jooyoung Lee, Won Bae Kim, Min Ho Seo, Sung Mook Choi   +14 more
wiley   +1 more source

Fe Atoms Accelerator Coupled With Oxygen Vacancies Channel Synergistically Boost OER Performance of Fe‐CoMoO4‐Ov Nanosheets

Carbon Energy, EarlyView.
Fe‐CoMoO4‐Ov/NF demonstrates significantly improved OER catalytic performance compared to CoMoO4. Specifically, the introduced Fe atoms act as a promoter for surface reconstruction, significantly reducing the energy required for surface reconstruction to generate FeCoOOH. The oxygen vacancies serve as electron channels between the core Fe‐CoMoO4‐Ov and
Chaojie Lyu, Jiarun Cheng, Yanhui Yu, Xinlong Tian, Yiming Liu   +4 more
wiley   +1 more source