Results 221 to 230 of about 67,378 (273)
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Carbene-Stabilized Beryllium Borohydride
Journal of the American Chemical Society, 2012The reaction of N-heterocyclic carbene, L:, with BeCl(2) quantitatively yields L:BeCl(2)1 (L: = :C{N(2,6-Pr(i)(2)C(6)H(3))CH}(2)). The carbene-stabilized beryllium borohydride monomer L:Be(BH(4))(2)2 is prepared by the reaction of 1 with LiBH(4). Compound 3, prepared by the reaction of 2 with Na(2)[Fe(CO)(4)]·dioxane, represents an unusual "dual ...
Robert J, Gilliard +8 more
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Radical reactions of borohydrides
Org. Biomol. Chem., 2014This review article focuses on state-of-the-art borohydride based radical reactions, also covering earlier work, kinetics and some DFT calculations with respect to the hydrogen transfer mechanism.
Takuji, Kawamoto, Ilhyong, Ryu
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Borohydride as Magnetic Superexchange Pathway in Late Lanthanide Borohydrides
European Journal of Inorganic Chemistry, 2019The magnetic characteristics of a series of borohydride‐based systems, including binary α‐/β‐Ln(BH4)3 phases (Ln = Gd, Tb, Dy, Ho, Er, and Tm) with direct Ln–HBH–Ln bridges and selected mixed‐metal systems, LiYb(BH4)4, NaYb(BH4)4, KHo(BH4)4, RbTm(BH4)4, with isolated Ln3+ ions embedded in [Ln(BH4)4]– anions are described for the first time using SQUID ...
Wojciech Wegner +4 more
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Reductions with sulfurated borohydrides. I. Preparation of sulfurated borohydrides
Canadian Journal of Chemistry, 1968Sodium borohydride reacts with sulfur at room temperature in the presence of appropriate organic solvents to give a sulfurated borohydride: NaBH2S3. The formulation of this hydride has been established by infrared, nuclear magnetic resonance, and elementary analysis. Thermal decomposition and hydrolysis are reported.
J. M. Lalancette, A. Frêche, R. Monteux
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Metallo Borohydrides. I. Aluminum Borohydride
Journal of the American Chemical Society, 1940H. I. Schlesinger +2 more
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Metallo Borohydrides. III. Lithium Borohydride
Journal of the American Chemical Society, 1940H. I. Schlesinger, Herbert C. Brown
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Tetrabutylammonium borohydride. Borohydride reductions in dichloromethane
The Journal of Organic Chemistry, 1976Douglas J. Raber, Wayne C. Guida
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Metallo Borohydrides. II. Beryllium Borohydride
Journal of the American Chemical Society, 1940Anton B. Burg, H. I. Schlesinger
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