Results 21 to 30 of about 38,047 (279)
Thermal Decomposition of Anhydrous Alkali Metal Dodecaborates M2B12H12 (M = Li, Na, K)
Metal dodecaborates M2/nB12H12 are regarded as the dehydrogenation intermediates of metal borohydrides M(BH4)n that are expected to be high density hydrogen storage materials.
Liqing He, Hai-Wen Li, Etsuo Akiba
doaj +1 more source
The coordination chemistry of scorpionate ligands based on borates containing the 7-azaindole heterocycle is relatively unexplored. Thus, there is a requirement to further understand their coordination chemistry.
Miriam Jackson +4 more
doaj +1 more source
REACTIVITY OF CHLOROPHYLL a/b-PROTEINS AND MICELLAR TRITON X-100 COMPLEXES OF CHLOROPHYLLS a OR b WITH BOROHYDRIDE [PDF]
The reaction of several plant chlorophyll-protein complexes with NaBH4 has been studied by absorption spectroscopy. In all the complexes studied, chlorophyll b is more reactive than Chi a, due to preferential reaction of its formyl substituent at C-7 ...
Jan M. Anderson +6 more
core +1 more source
The Borohydride Ion in the Lithium Borohydride Lattice [PDF]
IN a recent communication in Nature, Dr. C. J. H. Schutte1 has suggested that the anomalous band occurring at about 1,250 cm.−1 in the paraffin-oil mull spectrum of lithium borohydride at room temperature2 may be assigned to the doubly degenerate frequency, ν2(E), of tne tetrahedral
openaire +3 more sources
Recent Development of Mg Ion Solid Electrolyte
Although the successful deployment of lithium-ion batteries (LIBs) in various fields such as consumer electronics, electric vehicles and electric grid, the efforts are still ongoing to pursue the next-generation battery systems with higher energy ...
Yi Zhan +4 more
doaj +1 more source
Crystallographic characterization of (C5H4SiMe3)3U(BH4)
New syntheses have been developed for the synthesis of (borohydrido-κ3H)tris[η5-(trimethylsilyl)cyclopentadienyl]uranium(IV), [U(BH4)(C8H13Si)3] or Cp′3U(BH4) (Cp′ = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography.
Cory J. Windorff +4 more
doaj +1 more source
Electrocatalyst Design for Direct Borohydride Oxidation Guided by First Principles [PDF]
© 2017 American Chemical Society. Density functional theory (DFT) calculations are used to propose a Au-Cu binary metal catalyst for the electrochemical borohydride oxidation reaction (BOR), which is evaluated experimentally and observed to show ...
Gholamreza Rostamikia +9 more
core +1 more source
Surface activation of catalysts is known to be an efficient process to enhance their activity in catalytic processes. The activation process includes the generation of oxygen vacancies, changing the nature of the catalyst surface from acidic to basic and
Jose-Luis Ortiz-Quiñonez (5938331) +3 more
core +2 more sources
{Bis[2-(diisopropylphosphanyl)ethyl]amine}carbonyl(tetrahydroborato)cobalt(I)
In the structure of title borohydride pincer complex, [Co(BH4)(C16H37NP2)(CO)], the cobalt(I) metal exhibits a distorted square-pyramidal coordination geometry with the basal positions occupied by the P and N atoms of the tridentate ligand and by the C ...
Kathrin Junge +3 more
doaj +1 more source
Recent Progress in Metal Borohydrides for Hydrogen Storage
The prerequisite for widespread use of hydrogen as an energy carrier is the development of new materials that can safely store it at high gravimetric and volumetric densities.
Craig M. Jensen +4 more
doaj +1 more source

