Results 41 to 50 of about 38,047 (279)

Hydrogen Sorption in Erbium Borohydride Composite Mixtures with LiBH4 and/or LiH

open access: yesInorganics, 2017
Rare earth (RE) metal borohydrides have recently been receiving attention as possible hydrogen storage materials and solid-state Li-ion conductors. In this paper, the decomposition and reabsorption of Er(BH4)3 in composite mixtures with LiBH4 and/or LiH ...
Michael Heere   +7 more
doaj   +1 more source

Device for Controlled Production of Hydrogen

open access: yesHydrogen, 2023
In this work, the production of hydrogen from the sodium borohydride (NaBH4) reaction was studied using an experimental bench test in a passive device operating with or without minimal external energy input.
Alfonso Pozio
doaj   +1 more source

Synthesis and characterization of poly(N-vinyl-2-pyrrolidone)-stabilized water-soluble nickel(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohydride

open access: yes, 2008
Water-soluble PVP-stabilized nickel(0) nanclusters in particle size of 3.6 +/- 1.6 nm were synthesized by using a modified version Of alcohol reduction method and characterized by TEM, XPS and FT-IR. PVP polymer is coordinated to the nanoclusters surface
Metin, Onder, Özkar, Saim
core   +1 more source

Shaping Matter with Acoustic Waves: From Particles to Functional Structures

open access: yesAdvanced Functional Materials, EarlyView.
Acoustic‐directed assembly is reviewed as a materials‐oriented strategy for organizing particles, polymers, metals, and biological systems into functional structures. The review distinguishes reversible manipulation from permanent structure formation through medium fixation, particle fixation, and in situ material generation, highlighting routes toward
Avraham Kenigsberg   +5 more
wiley   +1 more source

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

open access: yesAdvanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang   +4 more
wiley   +1 more source

STABILIZATION OF UNUSUAL SUBSTRATE COORDINATION MODES IN DINUCLEAR MACROCYCLIC COMPLEXES [PDF]

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2010
The steric protection offered by the macrobinucleating hexaazaditiophenolate ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a ...
Vasile Lozan
doaj  

Adding to the Family of Copper Complexes Featuring Borohydride Ligands Based on 2-Mercaptopyridyl Units

open access: yesInorganics, 2019
Borohydride ligands featuring multiple pendant donor functionalities have been prevalent in the chemical literature for many decades now. More recent times has seen their development into new families of so-called soft scorpionates, for example, those ...
Joseph Goldsworthy   +4 more
doaj   +1 more source

Calcium Borohydride Ca(BH4)2: Fundamentals, Prediction and Probing for High-Capacity Energy Storage Applications, Organic Synthesis and Catalysis

open access: yesEnergies, 2023
Calcium borohydride (Ca(BH4)2) is a complex hydride that has been less investigated compared to its lighter counterpart, magnesium borohydride. While offering slightly lower hydrogen storage capacity (11.5 wt% theoretical maximum, 9.6 wt% under actual ...
Cezar Comanescu
doaj   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

open access: yesAdvanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami   +3 more
wiley   +1 more source

Structure and Hydrogen Storage Properties of Calcium Borohydride Diammoniate

open access: yes, 2010
A new type of hydrogen storage material namely, calcium borohydride diammoniate (Ca(BH4)(2)center dot 2NH(3)), is synthesized by reacting calcium borohydride and 2 equiv of ammonia. Structural analyses show that this complex has an orthorhombic structure
Guotao Wu   +12 more
core   +1 more source

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