Results 41 to 50 of about 67,378 (273)

STABILIZATION OF UNUSUAL SUBSTRATE COORDINATION MODES IN DINUCLEAR MACROCYCLIC COMPLEXES [PDF]

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2010
The steric protection offered by the macrobinucleating hexaazaditiophenolate ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a ...
Vasile Lozan
doaj  

Adding to the Family of Copper Complexes Featuring Borohydride Ligands Based on 2-Mercaptopyridyl Units

open access: yesInorganics, 2019
Borohydride ligands featuring multiple pendant donor functionalities have been prevalent in the chemical literature for many decades now. More recent times has seen their development into new families of so-called soft scorpionates, for example, those ...
Joseph Goldsworthy   +4 more
doaj   +1 more source

Synthesis and application of zeolite and glass fiber supported zero valent iron nanoparticles as membrane component for removal nitrate and Cr (+6) ions [PDF]

open access: yes, 2017
In the present paper the synthesis and characterization of zeolite and glass fiber supported zero valent iron nanoparticles (Ze-ZVI, GF-ZVI NPs) are reported.ZVI, Ze-ZVI and GF-ZVI NPs size, composition and morphology were characterized by Scanning ...
Allahverdiyeva, Gunel R.   +4 more
core   +1 more source

Natural Products Inspired Scaffold Diversification Leads to Unnatural Molecular Warhead and Covalent Strategy to Modulating Protein Function through Electrophilic Bromine Transfer

open access: yesAdvanced Science, EarlyView.
We report a new thiolate‐reactive α,α‐gem‐dibromo lactam warhead that activates transcription factor Nrf2 and demonstrates anti‐inflammatory activities, which have implications in cancer, neurodegeneration, and cardiovascular diseases. RNA‐seq illuminated detailed transcriptional profiles, and chemical reactions with cysteine‐containing compounds ...
Beau R. Brummel   +16 more
wiley   +1 more source

Preparation of black-titanium dioxide nanotubes by thermal decomposition of sodium borohydride

open access: yesJournal of Advanced Research in Natural and Applied Sciences, 2021
Titanium dioxide is a very attractive material in catalysis. Although the titanium dioxide exhibits superior proper-ties in ultra violet radiation, activity of the catalyst can be improved by some modifications specially for daylight radiation.
Murat Efgan Kibar
doaj   +1 more source

Low Shrinkage Bleaching of Unbleached Neutral Sulphite Semichemical Pulp [PDF]

open access: yes, 1959
The main objective of this research project was the investigation of the most feasible method for the bleaching of a soft-cooked unbleached neutral sulphite semichemical aspen pulp cooked to a 70 percent yield.
Morrison, Jobe B.
core   +1 more source

Development of polymeric hollow fiber membranes containing catalytic metal nanoparticules. [PDF]

open access: yes, 2010
Metal nanoparticles (MNPs) have unique physico-chemical properties advantageous for catalytic applications which differ from bulk material. However, the main drawback of MNPs is their insufficient stability due to a high trend for aggregation.
Bruening, Merlin L.   +5 more
core   +4 more sources

Timing Mechanotransduction: Mechanically Dynamic Biomaterials Reveal the Temporal Hierarchy of YAP/TAZ Control Nodes

open access: yesAdvanced Science, EarlyView.
This work develops dynamically softening polyacrylamide hydrogels for time‐resolved imaging during continuous mechanical transitions. The study revealed that mechanotransduction is biphasic; YAP/TAZ inactivation is driven by early loss of the nucleocytoskeletal continuum connecting subnuclear adhesions, F‐actin, and the nuclear envelope, coupled with ...
Alessandro Gandin   +12 more
wiley   +1 more source

Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor

open access: yesAngewandte Chemie, EarlyView.
Plastic waste is transformed into functional amines via solar‐driven transfer hydrogenation. Soluble monomers from acid hydrolysis of waste polymers serve as a hydrogen (electron/proton)donors in the selective reduction of nitroarenes using a visible light active photocatalyst consisting of cobalt promoted molybdenum disulfide integrated in cyanamide ...
Papa K. Kwarteng   +2 more
wiley   +2 more sources

Electroless Nickel-Based Catalyst for Diffusion Limited Hydrogen Generation through Hydrolysis of Borohydride

open access: yesCrystals, 2013
Catalysts based on electroless nickel and bi-metallic nickel-molybdenum nanoparticles were synthesized for the hydrolysis of sodium borohydride for hydrogen generation. The catalysts were synthesized by polymer-stabilized Pd nanoparticle-catalyzation and
Shannon P. Anderson, Egwu E. Kalu
doaj   +1 more source

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