Results 91 to 100 of about 31,221 (252)

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

CO2 reduction with protons and electrons at a boron-based reaction center. [PDF]

open access: yes, 2019
Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparation of
Essex, Laura A   +3 more
core  

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Ammonia borane oxidation at gold microelectrodes in alkaline solutions [PDF]

open access: yes, 2017
Borane-based electroless plating baths are of interest in many microelectronics applications such as barrier and capping layers for copper integrated circuit interconnect.
Nagle, Lorraine C., Rohan, James F.
core   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

Electro-oxidation of Ethanol on PtPdSn/C-Sb2O5.SnO2 Electrocatalysts Prepared by Borohydride Reduction

open access: yesInternational Journal of Electrochemical Science, 2013
Pt/C-Sb2O5.SnO2, PtPd/C-Sb2O5.SnO2 and PtPdSn/C-Sb2O5.SnO2 electrocatalysts were prepared in a single step using H2PtCl6.6H2O, Pd(NO3)2.2H2O and SnCl2.2H2O as metal sources, sodium borohydride as reducing agent and a physical mixture of 85% Vulcan Carbon
R.M. Piasentin   +5 more
doaj   +1 more source

Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2'-Bipyridine Complexes [PDF]

open access: yes, 1978
The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′‐bipyridine. A prominent reaction product of the catalyzed reduction is 1,5‐hexadiene.
Anson, Fred C., Margel, Shlomo
core  

Morphological study of synthesized RGO/ Pt nanocomposites via facile chemical reduction method [PDF]

open access: yes, 2017
Reduced graphene oxide nanosheet (RGO)/Pt nanocomposite have been successfully prepared through a facile chemical reduction method. The reduction of Pt precursor was carried out using sodium borohydride as the efficient chemical reductant. The morphology
Ahmad Fauzi Ismail,   +10 more
core   +1 more source

Tuning the Growth Pattern of Triangular Silver Nanoplates from Lateral to Vertical by Secondary Metal Addition

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
What happens, if in the synthesis of flat silver platelets, the slow deposition of silver along twinning faults is disturbed by the addition of a nobler metal? We have looked into it and found a way to fine‐tune the metal deposition in lateral and vertical direction.
Jonas Kluitmann   +3 more
wiley   +1 more source

Theory of Solvation-Controlled Reactions in Stimuli-Responsive Nanoreactors [PDF]

open access: yes, 2015
Metallic nanoparticles embedded in stimuli-responsive polymers can be regarded as nanoreactors since their catalytic activity can be changed within wide limits: the physicochemical properties of the polymer network can be tuned and switched by external ...
Angioletti-Uberti, Stefano   +3 more
core   +4 more sources

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