Results 11 to 20 of about 3,734 (241)

Tunable NaBH4 Nanostructures Revealing Structure‐Dependent Hydrogen Release

Advanced Energy & Sustainability Research, 2021
Borohydrides are promising candidates for hydrogen storage and generation assuming these can be tuned to reversibly deliver hydrogen under practical conditions.
Muhammad Saad Salman, Aditya Rawal, Kondo-Francois Aguey-Zinsou   +2 more
doaj   +1 more source

Recent Development of Lithium Borohydride‐Based Materials for Hydrogen Storage

Advanced Energy & Sustainability Research, 2021
Lithium borohydride (LiBH4) has been attracting extensive attention as an exemplary high‐capacity complex hydride for solid‐state hydrogen storage applications because of its high hydrogen capacities (18.5 wt% and 121 kg H2 m−3).
Wenxuan Zhang, Xin Zhang, Zhenguo Huang, Hai-Wen Li, Mingxia Gao, Hongge Pan, Yongfeng Liu   +6 more
doaj   +1 more source

Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes

Molecules, 2020
Thermodynamic hydricity (HDAMeCN) determined as Gibbs free energy (ΔG°[H]−) of the H− detachment reaction in acetonitrile (MeCN) was assessed for 144 small borane clusters (up to 5 boron atoms), polyhedral closo-boranes dianions [BnHn]2−, and their ...
Igor E. Golub, Oleg A. Filippov, Vasilisa A. Kulikova, Natalia V. Belkova, Lina M. Epstein, Elena S. Shubina   +5 more
doaj   +1 more source

Nucleophilic Substitution Reactions in the [B₃H₈]⁻ Anion in the Presence of Lewis Acids

Molecules, 2022
As a result of our study on the interaction between the octahydrotriborate anion with nucleophiles (Nu = THF, Ph3P, Ph2P-(CH2)2-PPh2 (dppe), Ph3As, Et3N, PhNH2, C5H5N, CH3CN, Ph2CHCN)) in the presence of a wide range of Lewis acids (Ti(IV), Hf(IV), Zr(IV)
Alexandra T. Shulyak, Evgeniy O. Bortnikov, Nikita A. Selivanov, Mikhail S. Grigoriev, Alexey S. Kubasov, Andrey P. Zhdanov, Alexander Y. Bykov, Konstantin Y. Zhizhin, Nikolai T. Kuznetsov   +8 more
doaj   +1 more source

Rare Earth Borohydrides—Crystal Structures and Thermal Properties

Energies, 2017
Rare earth (RE) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high gravimetric hydrogen density. This review illustrates the rich chemistry, structural diversity
Christoph Frommen, Magnus H. Sørby, Michael Heere, Terry D. Humphries, Jørn E. Olsen, Bjørn C. Hauback   +5 more
doaj   +1 more source

Hydrogen Sorption and Reversibility of the LiBH₄-KBH₄ Eutectic System Confined in a CMK-3 Type Carbon via Melt Infiltration

C, 2020
Metal borohydrides have very high hydrogen densities but their poor thermodynamic and kinetic properties hinder their use as solid hydrogen stores.
Filippo Peru, SeyedHosein Payandeh, Georgia Charalambopoulou, Torben R. Jensen, Theodore Steriotis   +4 more
doaj   +1 more source

Thermal Decomposition of Anhydrous Alkali Metal Dodecaborates M2B12H12 (M = Li, Na, K)

Energies, 2015
Metal dodecaborates M2/nB12H12 are regarded as the dehydrogenation intermediates of metal borohydrides M(BH4)n that are expected to be high density hydrogen storage materials.
Liqing He, Hai-Wen Li, Etsuo Akiba
doaj   +1 more source

Synergized Tricomponent All‐Inorganics Solid Electrolyte for Highly Stable Solid‐State Li‐Ion Batteries

Advanced Science, 2023
Garnet‐type oxide Li6.4La3Zr1.4Ta0.6O12 (LLZTO) features superior ionic conductivity and good stability toward lithium (Li) metal, but requires high‐temperature sintering (≈1200 °C) that induces high fabrication cost, poor mechanical processability, and ...
Guixiang Xu, Xin Zhang, Shuyang Sun, Yangfan Zhou, Yongfeng Liu, Hangwang Yang, Zhenguo Huang, Fang Fang, Wenping Sun, Zijiang Hong, Mingxia Gao, Hongge Pan   +11 more
doaj   +1 more source

Stability and Reversibility of Lithium Borohydrides Doped by Metal Halides and Hydrides [PDF]

, 2008
In an effort to develop reversible metal borohydrides with high hydrogen storage capacities and low dehydriding temperature, doping LiBH4 with various metal halides and hydrides has been conducted.
Anton, Donald L., Au, Ming, Bowman, Robert C., Jr., Hwang, Son-Jong, Jurgensen, Arthur R., Kim, Chul, Pinkerton, Frederick E., Spencer, William A.   +7 more
core   +1 more source

A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity

Inorganics, 2020
Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel, sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen
Efi Hadjixenophontos, Erika Michela Dematteis, Nicola Berti, Anna Roza Wołczyk, Priscilla Huen, Matteo Brighi, Thi Thu Le, Antonio Santoru, SeyedHosein Payandeh, Filippo Peru, Anh Ha Dao, Yinzhe Liu, Michael Heere   +12 more
doaj   +1 more source